有机化学 ›› 2001, Vol. 21 ›› Issue (6): 445-452. 上一篇    下一篇

研究论文

有机合成中的C=C键形成新方法: 原子经济的金属复 分解闭环反应

赵宝祥   

  1. 山东大学化学与环境科学学院
  • 发布日期:2001-06-25

New method for forming C=C bonds in organic synthesis: Atom economic ring-closing metathesis reactions

Zhao Baoxiang   

  • Published:2001-06-25

综述了金属复分解闭环反应最新进展。金属复分解闭环反应已成为有机合成中的非常重要的方法,广泛应用于碳环、杂环化合物及天然产物的合成。原子经济的、绿色化学的优点展示出更加诱人的前景。

关键词: 有机合成, 双键, 复分解, 闭环反应, 苯并吡喃, 氨基酸, 肽, 内酰胺, 磺酰胺, 磷杂环化合物

Recent important propress in iring-closing metathesis of olefin is reviewed. The ring-closing metathesis recently emerges as a powerful method for the synthesis of a variety of ring systems including carbo-, and heterocycles, and has found extensive applications in the synthesis of natural products. These reactions are atom economic and meet the requirementsof green chemistry.

Key words: ORGANIC SYNTHESIS, DOUBLE BONDS, DOUBLE DECOMPOSITION, RING CLOSURE REACTION, BENZOPYRAN, AMINO ACID, PEPTIDE, LACTAM, SULFONIC ACID AMIDE, PHOSPHOROUS HETEROCYCLIC COMPOUNDS

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