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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (08): 913-925. 上一篇    下一篇

综述与进展

基于杯芳烃主体的分子自组装研究进展

赵邦屯*，张衡益，刘育   

  1. (1洛阳师范学院化学系 洛阳 471022)
    (2南开大学化学系 天津 300071)
  • 收稿日期:2004-09-27 修回日期:2005-04-03 发布日期:2005-07-30
  • 通讯作者: 赵邦屯

Progress on Molecular Self-assembly Based on Calixarene Derivatives

ZHAO Bang-Tun*,ZHANG Heng-Yi,LIU Yu   

  1. (1 Department of Chemistry, Luoyang Teacher’s College, Luoyang 471022)
    (2 Department of Chemistry, Nankai University, Tianjin 300071)
  • Received:2004-09-27 Revised:2005-04-03 Published:2005-07-30
  • Contact: ZHAO Bang-Tun

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2379

被引次数

52

分子自组装是超分子化学最重要的研究内容之一. 杯芳烃作为继冠醚、环糊精之后的第三代人工合成受体分子已在分子自组装研究方面取得了重要进展并显示了广泛的应用前景. 主要综述杯芳烃衍生物通过氢键、金属诱导配位、π-π作用、疏水作用等非共价键弱相互作用力在溶液状态、固态和界面的分子自组装方面的研究进展.

关键词: 杯芳烃, 分子自组装, 综述, 超分子化学

Molecular self-assembly is a topic of current interest in supramolecular chemistry. Calixarenes taken as the third general artificial synthetic receptors, following crown ethers and cyclodextrins, have been well explored in molecular self-assembly. The central issue of this paper is to review the progress on molecular assembly based on calixarene derivatives, which covers the self-assembly of calixarenes in solution, solid as well as surface through hydrogen bonding, metal-induced force, π-π interactions, hydrophobic interactions as well as other non-covalently weaker forces.

Key words: calixarene, supramolecular chemistry, review, molecular self-assembly