有机化学 ›› 2014, Vol. 34 ›› Issue (11): 2195-2201.DOI: 10.6023/cjoc201406014 上一篇    下一篇

综述与进展

铁催化硅氢加成反应研究进展

徐大鹏, 肖文军, 彭家建, 厉嘉云, 白赢   

  1. 杭州师范大学有机硅化学及材料技术教育部重点实验室 杭州 311121
  • 收稿日期:2014-06-12 修回日期:2014-07-15 出版日期:2014-11-25 发布日期:2014-07-17
  • 通讯作者: 彭家建,jjpeng@hznu.edu.cn;肖文军,xiaowj2008@126.com E-mail:jjpeng@hznu.edu.cn;xiaowj2008@126.com
  • 基金资助:

    国家自然科学基金(No.21303035)、浙江省自然科学基金(No.LY14B030007)资助项目.

Progress in Hydrosilylation Catalyzed with Iron Catalyst

Xu Dapeng, Xiao Wenjun, Peng Jiajian, Li Jiayun, Bai Ying   

  1. Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education,Hangzhou Normal University, Hangzhou 311121
  • Received:2014-06-12 Revised:2014-07-15 Online:2014-11-25 Published:2014-07-17
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No.21303035) and the Natural Science Foundation of Zhejiang Province (No.LY14B030007).

铁催化剂应用于催化硅氢加成反应, 具有原料丰富度高、低成本、低毒性等优点, 在近几年得到迅速发展. 总结了铁催化剂在碳-碳双键、碳-氧双键及其他杂原子不饱和双键硅氢加成反应中的应用, 并展望了铁催化剂在有机硅化学领域的应用前景.

关键词: 铁配合物, 硅氢加成, 碳-碳双键, 杂原子双键, 进展

Iron catalysts gained great development in hydrosilylation of various types of unsaturated double bond compounds due to their advantages of high raw material abundance, low cost, low toxicity, etc. The applications of iron catalysts are summarized in the hydrosilylation of carbon-carbon double bond, carbon-oxygen double bond and other heteroatomic double bond. The application prospect of iron catalysts in the field of organic silicon chemistry is looked forward.

Key words: iron complex, hydrosilylation, carbon-carbon double bond, heteroatomic double bond, progress