Synthesis and Characterization of New Asymmetrical Phthalocyanine Zinc

doi:10.6023/cjoc1109291

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (04): 770-775.DOI: 10.6023/cjoc1109291 Previous Articles Next Articles

Notes

新型不对称酞菁锌的合成和表征

俞孝伟^a,b, 詹传郎^b, 黄彦^a

a 南京工业大学化学化工学院材料化学工程国家重点实验室南京 210009;
b 中国科学院化学研究所北京分子科学国家实验室中国科学院光化学重点实验室北京 100190

收稿日期:2011-09-29 修回日期:2011-11-25 发布日期:2012-04-24
通讯作者: 黄彦 E-mail:huangy@njut.edu.cn
基金资助:
国家自然科学基金(No. 20973182)资助项目.

Synthesis and Characterization of New Asymmetrical Phthalocyanine Zinc

Yu Xiaowei^a,b, Zhan Chuanlang^b, Huang Yan^a

a State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009;
b Beijing National Laboratory for Molecular Sciences (BNLMS), Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190

Received:2011-09-29 Revised:2011-11-25 Published:2012-04-24
Supported by:
Project supported by the National Natural Science Foundation of China (No. 20973182).

Four kinds of symmetrical phthalocyanine zincs (PCZn) 2(3),9(10),16(17),23(24)-(tetraheptanylcarbonyl amino)-phthalocyanine zinc, 2(3),9(10),16(17),23(24)-tetramethoxy-phthalocyanine zinc, 2(3),9(10),16(17),23(24)-tetra-(4- tert-butylphenoxyl)-phthalocyanine zinc, and 2(3),9(10),16(17),23(24)-tetraphenoxyl-phthalocyanine zinc were synthesized from 4-nitro-phthalonitrile. Moreover, the 4-(4-tert-butylphenoxyl)phthalonitrile was employed as a precursor in the synthesis of two kinds of asymmetrical PCZn (A₃B) containing either amino- or carboxyl-group by probability method.

Key words: phthalocyanine zinc, asymmetrical phthalocyanine, synthesis, precursor, probability method

Cite this article

Yu Xiaowei, Zhan Chuanlang, Huang Yan. Synthesis and Characterization of New Asymmetrical Phthalocyanine Zinc[J]. Chin. J. Org. Chem., 2012, 32(04): 770-775.

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新型不对称酞菁锌的合成和表征

Synthesis and Characterization of New Asymmetrical Phthalocyanine Zinc

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