Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (07): 1382-1394.DOI: 10.6023/cjoc201301020 Previous Articles     Next Articles



杨艳, 王立颖, 罗君, 朱育林   

  1. 华南师范大学化学与环境学院 广州 510006
  • 收稿日期:2013-01-09 修回日期:2013-02-06 发布日期:2013-02-18
  • 通讯作者: 朱育林

Research and Progress in Chiral Binuclear Catalyst of First Row Transition Metal and Corresponding Nonlinear Effect

Yang Yan, Wang Liying, Luo Jun, Zhu Yulin   

  1. School of Chemistry and Enviroment, South China Normal University, Guangzhou 510006
  • Received:2013-01-09 Revised:2013-02-06 Published:2013-02-18

The study on chiral binuclear complexes of first row transition metal has been expended to correlated fields such as asymmetric catalysis, biomimetic, functional supramolecular material and medicine, and reaches a research hot point of vast attraction and potential. Contrasting with other traditional organic-metal catalysts, the chiral binuclear complexes which combine several chiral centers and cooperated binuclear often play preferable catalysis behavior in enantioselective reaction. This review covers the recent progress in chiral binuclear complexes of V, Ti, Mn, Fe, Co, Ni, Cu, Zn applied in asymmetric reactions involving asymmetric addition, kinetic resolution, selective oxidation, asymmetric polymerization, as well as the mechanistic investigations. Some studies on the nonlinear effect along with the dimer catalysts are also discussed. The challenges and perspectives are given at the end of this article.

Key words: chiral binuclear complexes, first row transition metal, asymmetric catalysis, nonlinear effect