Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (04): 749-759.DOI: 10.6023/cjoc201301032 Previous Articles     Next Articles



李昆, 杨国强, 刘媛媛, 张万斌   

  1. 上海交通大学化学化工学院 上海 200240
  • 收稿日期:2013-01-14 修回日期:2013-02-14 发布日期:2013-02-22
  • 通讯作者: 张万斌
  • 基金资助:

    国家自然科学基金(Nos. 20972095, 21172143, 21232004)和上海市科学技术委员会(No. 09JC1407800)资助项目.

Chiral Polymetallic Catalysts and Their Applications in Asymmetric Catalysis

Li Kun, Yang Guoqiang, Liu Yuanyuan, Zhang Wanbin   

  1. School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240
  • Received:2013-01-14 Revised:2013-02-14 Published:2013-02-22
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 20972095, 21172143 and 21232004) and the Science and Technology Commission of Shanghai Municipality (No. 09JC1407800).

Polymetallic catalytic process is the main metabolic way of life, which is widely observed in nature. Compared to the mono-metal catalysts, the designs and applications of polymetallic catalysts with high reactivity and enantioselectivity have been a hot research topic in organic chemistry recently. This review covers the recent research process on representative types of bimetallic catalysts, including hetero-bimetallic catalysts and dinuclear homometal catalysts, their reaction mechanisms and developments. Moreover, potentially development of this area is also discussed.

Key words: asymmetric catalysis, polymetallic, dinuclear homometal catalyst, hetero-bimetallic catalyst