Synthesis and Herbicidal Activity of Novel N-Acyl-7-methoxybenzo[4,5]thiazolo- [2,3-c][1,2,4]triazole-3(2H)-thione

doi:10.6023/cjoc201308001

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (2): 419-423.DOI: 10.6023/cjoc201308001 Previous Articles Next Articles

Notes

新型N-酰基-7-甲氧基-苯并[4,5]噻唑并[2,3-c][1,2,4]三唑-3(2H)-硫酮的合成及其除草活性

王海林, 阮铃莉, 陈勇, 刘幸海, 翁建全

浙江工业大学化学工程与材料学院杭州 310032

收稿日期:2013-08-01 修回日期:2013-10-03 发布日期:2013-10-11
通讯作者: 翁建全 E-mail:jqweng@zjut.edu.cn
基金资助:
国家自然科学基金（No.30900959）资助项目.

Synthesis and Herbicidal Activity of Novel N-Acyl-7-methoxybenzo[4,5]thiazolo- [2,3-c][1,2,4]triazole-3(2H)-thione

Wang Hailin, Ruan Lingli, Chen Yong, Liu Xinghai, Weng Jianquan

College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032

Received:2013-08-01 Revised:2013-10-03 Published:2013-10-11
Supported by:
Project supported by the National Natural Science Foundation of China (No. 30900959).

1. Synthesis and Herbicidal Activity of Novel N-Acyl-7-methoxybenzo[4,5]thiazolo- [2,3-c][1,2,4]triazole-3(2H)-thione.PDF(1919KB)

Abstract

In order to find the new fused heterocycle of benzothiazole lead compounds, fourteen novel N-acyl-7-methoxybenzo[4,5]thiazolo[2,3-c][1,2,4]triazole-3(2H)-thiones were synthesized by using 6-methoxybenzo[d]thiazol-2-amine as starting materials via hydrazine, cyclization and acylation. The structures of the target compounds were characterized by ¹H NMR, ESI-MS and elemental analysis. The synthesized target compounds were screened for the herbicidal activity. The results indicated that the inhibition effects of most target compounds on the root and stem of Cucumis sativus, Triticum aestivum, Sorghum vulgare, Raphanus sativus, Brassica campestris and Echinochloa crusgalli were more than 85% at 200 mg/L.

Key words: N-acyl-7-methoxybenzo[4,5]thiazolo[2,3-c][1,2,4]triazole-3(2H)-thione, synthesis, herbicidal activity

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Wang Hailin, Ruan Lingli, Chen Yong, Liu Xinghai, Weng Jianquan. Synthesis and Herbicidal Activity of Novel N-Acyl-7-methoxybenzo[4,5]thiazolo- [2,3-c][1,2,4]triazole-3(2H)-thione[J]. Chin. J. Org. Chem., 2014, 34(2): 419-423.

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新型N-酰基-7-甲氧基-苯并[4,5]噻唑并[2,3-c][1,2,4]三唑-3(2H)-硫酮的合成及其除草活性

Synthesis and Herbicidal Activity of Novel N-Acyl-7-methoxybenzo[4,5]thiazolo- [2,3-c][1,2,4]triazole-3(2H)-thione

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