Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (7): 1544-1550.DOI: 10.6023/cjoc201502013 Previous Articles     Next Articles



王晨君, 王晗, 马超, 张开新, 韩飞, 李保国, 陈树峰   

  1. 内蒙古大学化学化工学院 内蒙古自治区精细有机合成重点实验室 呼和浩特 010021
  • 收稿日期:2015-02-08 修回日期:2015-03-08 发布日期:2015-03-13
  • 通讯作者: 李保国, 陈树峰;
  • 基金资助:

    国家自然科学基金(No. 21262023)和内蒙古自治区杰出青年培育基金(No. 2014JQ02)资助项目

Synthesis of 1'-Arylmethyl-1-(1,2-dienyl)ferrocenes

Wang Chenjun, Wang Han, Ma Chao, Zhang Kaixin, Han Fei, Li Baoguo, Chen Shufeng   

  1. Inner Mongolia Key Laboratory of Fine Organic Synthesis, Department of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021
  • Received:2015-02-08 Revised:2015-03-08 Published:2015-03-13
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21262023) and the Natural Science Foundation of Inner Mongolia of China (No. 2014JQ02).

A convenient procedure for synthesizing 1'-arylmethyl-1-(1,2-dienyl)ferrocene derivatives was explored. Using commercially available ferrocene as the starting material, the six target compounds were obtained in five steps via Friedel-Crafts acylation, reduction, acetylation, acetylene formation and modified Crabbé reaction. The structures of the obtained allenes were characterized by 1H NMR and 13C NMR and HRMS.

Key words: ferrocene, allene, 1'-arylmethyl-1-(1,2-dienyl)ferrocene, synthesis