Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (3): 622-625.DOI: 10.6023/cjoc201509033 Previous Articles     Next Articles



孙宏顺a,b, 王建强a, 谭文文b, 杨海东b, 李玉龙b, 沈临江a, 郭成a   

  1. a 南京工业大学化学与分子工程学院 南京 211816;
    b 南京科技职业学院化学工程系 南京 210048
  • 收稿日期:2015-09-25 修回日期:2015-10-27 发布日期:2015-11-06
  • 通讯作者: 沈临江
  • 基金资助:

    国家自然科学青年基金(No. 21106069)、南京科技职业学院院级重点(No. NHKY-2015-1)资助项目.

Synthesis and Crystal Structure of a Novel 1,3,4-Oxadiazin-one Compound

Sun Hongshuna,b, Wang Jianqianga, Tan Wenwenb, Yang Haidongb, Li Yulongb, Shen Linjianga, Guo Chenga   

  1. a College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816;
    b Department of Chemical Engineering, Nanjing Polytechnic Institute, Nanjing 210048
  • Received:2015-09-25 Revised:2015-10-27 Published:2015-11-06
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21106069) and the Key Program of Nanjing Polytechnic Institute (No. NHKY-2015-1).

Using benzothiophene-2-carboxylic acid as a raw material, 2-(1-benzothiophen-2-yl)-4H-1,3,4-oxadiazin-5(6H)-one (4) was synthesized by esterification and hydrazinolysis, followed by the acylation and cyclization reactions. The novel compound 4 was characterized by 1H NMR, 13C NMR, ESI-MS, FT-IR, elemental analysis and X-ray single crystal diffraction.

Key words: benzothiophen, oxadiazin, synthesis, crystal structure