Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (4): 896-901.DOI: 10.6023/cjoc201710031 Previous Articles     Next Articles



冯志刚a, 谢小敏b, 张兆国a,b   

  1. a 上海应用技术大学化学与环境工程学院 上海 201418;
    b 上海交通大学化学化工学院 上海 200240
  • 收稿日期:2017-10-24 修回日期:2017-11-18 发布日期:2017-12-05
  • 通讯作者: 张兆国
  • 基金资助:


Palladium-Catalyzed Cross-Coupling Reaction of Arenesulphonate with Phosphite

Feng Zhiganga, Xie Xiaominb, Zhang Zhaoguoa,b   

  1. a School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418;
    b School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240
  • Received:2017-10-24 Revised:2017-11-18 Published:2017-12-05
  • Contact: 10.6023/cjoc201710031
  • Supported by:

    Project supported by the National Natural Sciences Foundation of China (No. 21472124).

Organo-phosphorus compounds have important applications in metal-organic chemistry, coordination chemistry and biochemistry. Therefore, the C-P cross-coupling reaction was an important method to prepare organo-phosphorus, which is also a hotspot of current research. Hence, we have studied a kind of cross-coupling reaction between arenesulphonate and phosphites using palladium as the catalyst to synthesize a series of organo-phosphorus compounds efficiently, and the approach was applied to prepare a chiral N/P ligand.

Key words: arenesulphonate, phosphite, palladium, cross-coupling