Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (10): 2590-2605.DOI: 10.6023/cjoc201804001 Previous Articles     Next Articles

Reviews

芳香化合物的电化学C—H键官能化研究进展

吴亚星, 席亚超, 赵明, 王思懿   

  1. 中国矿业大学化工学院 徐州 221116
  • 收稿日期:2018-04-01 修回日期:2018-05-13 出版日期:2018-10-25 发布日期:2018-06-06
  • 通讯作者: 赵明,E-mail:ming815zhao@163.com E-mail:ming815zhao@163.com
  • 基金资助:

    中央高校基本科研业务费(No.2015XKMS048)、江苏省自然科学基金(No.BK20160254)、国家自然科学基金(No.U1710102)、中国矿业大学“十三五”品牌专业建设资助项目.

Progress in Electrochemical C—H Functionalizations of Aromatic Compounds

Wu Yaxing, Xi Yachao, Zhao Ming, Wang Siyi   

  1. School of Chemical Engineering, China University of Mining and Technology, Xuzhou 221116
  • Received:2018-04-01 Revised:2018-05-13 Online:2018-10-25 Published:2018-06-06
  • Contact: 10.6023/cjoc201804001 E-mail:ming815zhao@163.com
  • Supported by:

    Project supported by the Fundamental Research Funds for the Central Universities (No. 2015XKMS048), the Natural Science Foundation of Jiangsu Province (No. BK20160254), and the National Natural Science Foundation of China (No. U1710102).

Carbon-hydrogen bonds are the most extensive and basic chemical bonds existed in organic compounds. Electrochemical functionalization and direct conversion of aromatic C—H bonds is a green, sustainable, and atomically economical transformation pathway, which avoids the pre-functionalization of reactants. The anodic electrooxidation of aromatics allows the formation of C—X (X=C, N, O, S) bonds and the preparation of fused aromatic rings without the use of oxidants. Certain C—H activation reactions with chemoselectivity and regioselectivity can also be achieved by the optimization of electrode materials, electrolytes, and solvents. Vourious reactions focusing on the electrochemical functionalizations of C—H bonds in aromatic compounds are mainly reviewed.

Key words: electrochemical synthesis, aromatics, C—H bond functionalization, fused aromatic compounds