Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (1): 95-108.DOI: 10.6023/cjoc201809010 Previous Articles     Next Articles

Special Issue: 庆祝陈庆云院士九十华诞

Reviews

可见光促进的烯烃异构化反应

张昊a,b, 俞寿云b   

  1. a 扬州大学化学化工学院 扬州 225002;
    b 南京大学化学化工学院 生命分析化学国家重点实验室 南京 210023
  • 收稿日期:2018-09-06 修回日期:2018-10-14 出版日期:2019-01-25 发布日期:2018-10-20
  • 通讯作者: 俞寿云 E-mail:yushouyun@nju.edu.cn
  • 基金资助:

    国家自然科学基金(No.21732003)资助项目.

Visible Light-Promoted Isomerization of Alkenes

Zhang Haoa,b, Yu Shouyunb   

  1. a School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002;
    b State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023
  • Received:2018-09-06 Revised:2018-10-14 Online:2019-01-25 Published:2018-10-20
  • Contact: 10.6023/cjoc201809010 E-mail:yushouyun@nju.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21732003).

The traditional methods for synthesizing Z-olefins generally require the use of high-energy reagents. These methods are usually controlled by kinetics. The reaction conditions are harsh and low atom economic. During the process of separation, Z-olefins are easy to convert to the thermodynamically more stable E-olefins. With the continuous development of organic photochemistry and photocatalysis technology, more and more synthetic challenges have been solved by photocatalysis. Herein, various types of visible light-promoted photocatalytic isomerization of olefins are reviewed.

Key words: photochemistry, olefins, isomerization, energy transfer