Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (6): 1511-1521.DOI: 10.6023/cjoc201903078 Previous Articles     Next Articles

Special Issue: 碳氢活化合辑2018-2019 元素有机化学合辑2018-2019 金属有机化学

Reviews

过渡金属催化的C-H键硅烷化反应研究进展

黄鸿泰, 李涛, 王家状, 秦贵平, 肖铁波   

  1. 昆明理工大学理学院 昆明 650500
  • 收稿日期:2019-03-30 修回日期:2019-05-09 出版日期:2019-06-25 发布日期:2019-05-28
  • 通讯作者: 肖铁波 E-mail:xiaotb@kmust.edu.cn
  • 基金资助:

    国家自然科学基金(No.21801011)资助项目.

Recent Advance in Transition-Metal-Catalyzed Silylation of C-H Bonds

Huang Hongtai, Li Tao, Wang Jiazhuang, Qin Guiping, Xiao Tiebo   

  1. Faculty of Science, Kunming University of Science and Technology, Kunming 650500
  • Received:2019-03-30 Revised:2019-05-09 Online:2019-06-25 Published:2019-05-28
  • Contact: 10.6023/cjoc201903078 E-mail:xiaotb@kmust.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21801011).

Organosilicon compounds play an important role in pharmaceutical chemistry, material science and organic synthesis. Transition-metal-catalyzed direct silylation of C-H bond, as one of the most concise and efficient methods for the synthesis of organosilanes, has developed rapidly in recent years. In this paper, the recent advance in transition-metal-catalyzed silylation of C-H bonds since 2015 is mainly reviewed.

Key words: C-H functionalization, transition-metal catalysis, silylation, organosilanes