Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (8): 2308-2321.DOI: 10.6023/cjoc202003006 Previous Articles     Next Articles

有机聚合物负载铑催化剂在氢甲酰化反应中的应用研究进展

宗玲博a, 陈建宾b, 任新意c, 张国营a, 贾肖飞a   

  1. a 青岛科技大学化学与分子工程学院 山东省生化分析重点实验室 山东青岛 266042;
    b 齐鲁工业大学化学与制药工程学院 山东省分子工程重点实验室 济南 250353;
    c 华东师范大学化学与分子工程学院 绿色化学与化工过程绿色化上海市重点实验室 上海 200241
  • 收稿日期:2020-03-03 修回日期:2020-05-01 出版日期:2020-08-25 发布日期:2020-05-20
  • 通讯作者: 贾肖飞 E-mail:jiaxiaofei139@163.com
  • 基金资助:
    国家自然科学基金(Nos.21703116,51702180)、青岛科技大学化学学部开放基金(Nos.QUSTHX201932,QUSTHX202010)资助项目.

Progress in Application of Organic Polymers Supported Rhodium Catalysts in Hydroformylation

Zong Lingboa, Chen Jianbinb, Ren Xinyic, Zhang Guoyinga, Jia Xiaofeia   

  1. a Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042;
    b Shandong Provincial Key Laboratory of Molecular Engineering, School of Chemistry and Chemical Engineering, Qilu University of Technology, Jinan 250353;
    c Shanghai Key Laboratory of Green Chemistry and Chemical Process, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241
  • Received:2020-03-03 Revised:2020-05-01 Online:2020-08-25 Published:2020-05-20
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Nos. 21703116, 51702180) and the Open Fund of the Department of Chemistry, Qingdao University of Science and Technology (Nos. QUSTHX201932, QUSTHX202010).

Hydroformylation is considered one of the most important homogenously catalyzed processes in dustry. Hydroformylation has been widely used in the production of aldehydes, and aldehydes can also be further converted into high value-added alcohols, acids and other derivatives. Compared with the homogeneous reaction, the heterogeneous catalysts present significant advantages in terms of recyclability, separation of catalysts and products and so on. In recent years, organic polymer-supported rhodium catalysts have shown excellent catalytic activity, high selectivity, and good recycleability in heterogeneous hydroformylation, and have attracted widespread attention. The research progress of the application of organic polymer supported catalysts in hydroformylation is summarized, including synthesis, material characteristics and application of supported catalysts. Finally, the prospect of the reaction is discussed.

Key words: rhodium, hydroformylation, organic polymers, heterogeneous catalysts