Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (8): 2221-2231.DOI: 10.6023/cjoc202003039 Previous Articles     Next Articles

以二氧化碳为C1合成子的羧基化/环化反应研究进展

周聪, 李渺, 于金涛, 孙松, 成江   

  1. 常州大学石油化工学院 江苏常州 213164
  • 收稿日期:2020-03-15 修回日期:2020-05-13 出版日期:2020-08-25 发布日期:2020-05-15
  • 通讯作者: 孙松, 成江 E-mail:sunsong@cczu.edu.cn;chengjiang@cczu.edu.cn
  • 基金资助:
    国家自然科学基金(Nos.21602019,21971025)、江苏省绿色催化材料与技术重点实验室(No.BM2012110)和江苏省先进催化与绿色制造协同创新中心资助项目.

Recent Progress in the Carboxylation/Cyclization Reactions Using Carbon Dioxide as the C1 Source

Zhou Cong, Li Miao, Yu Jintao, Sun Song, Cheng Jiang   

  1. School of Petrochemical Engineering, Changzhou University, Changzhou, Jiangsu 213164
  • Received:2020-03-15 Revised:2020-05-13 Online:2020-08-25 Published:2020-05-15
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Nos. 21602019, 21971025), the Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology (No. BM2012110) and the Advanced Catalysis and Green Manufacturing Collaborative Innovation Center.

Carbon dioxide is a readily available, low-cost, abundant, non-toxic C1 source, which can potentially serve as an ideal building block in synthetic chemistry. Recently, much progress, expecially multi-component reactions (MCRs) has been achieved in construction of carbonyl-containing heterocycles through annulation by using carbon dioxide as carbonyl/carboxyl source. Herein, the advances on the annulation reaction of atmospheric CO2 with N-, and O-nucleophiles for the constructioin of various carbonyl-containing heterocycles, including benzoxazin, cyclic carbamates, lactams, oxazolidine-2,4-diones are reviewed. In addition, the carboxylation of C-nucleophiles with CO2 toward carboxylic acids is also summarized.

Key words: carbon dioxide, multicomponent reaction, annulation, carboxylic acid, heterocycle