Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (4): 1319-1336.DOI: 10.6023/cjoc202007063 Previous Articles     Next Articles



陈鑫a,b, 陈春霞a,b,*(), 彭进松a,*()   

  1. a 东北林业大学 化学化工与资源利用学院 哈尔滨 150040
    b 东北林业大学 材料科学与工程学院 哈尔滨 150040
  • 收稿日期:2020-07-28 修回日期:2020-10-23 发布日期:2020-11-19
  • 通讯作者: 陈春霞, 彭进松
  • 基金资助:
    黑龙江省自然科学基金(LC2018003); 中央高校基本科研业务费专项资金(2572019CG06)

Research Progress of Cellulose and Its Derivatives Supported Copper Catalyst Catalyzed Organic Reactions

Xin Chena,b, Chunxia Chena,b,*(), Jinsong Penga,*()   

  1. a College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040
    b Material Science and Engineering College, Northeast Forestry University, Harbin 150040
  • Received:2020-07-28 Revised:2020-10-23 Published:2020-11-19
  • Contact: Chunxia Chen, Jinsong Peng
  • About author:
    * Corresponding authors. E-mail: ;
  • Supported by:
    Natural Science Foundation of Heilongjiang Province(LC2018003); Fundamental Research Funds for the Central Universities(2572019CG06)

Cellulose, the most abundant natural polymer in nature, is found in vascular plant, cotton, algae and bacteria, and it can be widely employed in organic synthesis and catalytic chemistry as a loading material for metal nanoparticles. In modern times, the field of transition metal catalysis has been developed rapidly, but it has the disadvantages of high cost, difficulty of separation and non-recyclable reuse, thus more and more researchers use cellulose and its derivatives to carry out heterogeneous catalysis. From an economic and efficient point of view, cheap cellulose and its derivatives-loaded copper particles can not only participate in various types of organic conversion efficiently, but also can be recycled and reused many times, thus solving many disadvantages of homogeneous catalysts and achieving green process. The organic reactions catalyzed by different types of cellulose-supported copper catalysts are reviewed, including the construction of C—X bond, cycloaddition, oxidation, reduction, photocatalytic degradation and electrocatalysis. It will promote the application of cellulose and its derivatives-sup- ported catalysts in the future.

Key words: cellulose-supported copper catalyst, functional cellulose, synthesis, organic reaction, heterogeneous catalysis