Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (6): 2302-2309.DOI: 10.6023/cjoc202102002 Previous Articles Next Articles
ARTICLES
收稿日期:
2021-02-01
修回日期:
2021-02-28
发布日期:
2021-03-12
通讯作者:
曾程初
基金资助:
Mingyang Sun, Kun Xu, Bingbing Guo, Chengchu Zeng()
Received:
2021-02-01
Revised:
2021-02-28
Published:
2021-03-12
Contact:
Chengchu Zeng
Supported by:
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Mingyang Sun, Kun Xu, Bingbing Guo, Chengchu Zeng. Copper-Catalyzed Vicinal C(sp2)—H Selenylation of Benzoic Acid Derivatives Using Air as Oxidant[J]. Chinese Journal of Organic Chemistry, 2021, 41(6): 2302-2309.
Entry | Catalyst | Base | Temp./℃ | Yield/% |
---|---|---|---|---|
1 | Ni(acac)2 | NaOAc | 60 | 0 |
2 | Co(acac)2 | NaOAc | 60 | 0 |
3 | Pd(OAc)2 | NaOAc | 60 | 0 |
4 | Cu(OAc)2 | NaOAc | 60 | 67 |
5 | Cu(CHCN)4PF6 | NaOAc | 60 | 66 |
6c | Cu(OAc)2 | NaOAc | 60 | 48 |
7d | Cu(OAc)2 | NaOAc | 60 | 0 |
8e | Cu(OAc)2 | NaOAc | 60 | 70 |
9 | Cu(OAc)2 | NaOAc | 25 | Trace |
10 | Cu(OAc)2 | NaOAc | 40 | 30 |
11 | Cu(OAc)2 | NaOAc | 80 | 77 |
12 | Cu(OAc)2 | CsOAc | 80 | 65 |
13 | Cu(OAc)2 | NaOPiv | 80 | 67 |
14 | Cu(OAc)2 | NaH2PO4 | 80 | 0 |
15 | Cu(OAc)2 | Na2HPO4 | 80 | Trace |
16 | Cu(OAc)2 | Na3PO4 | 80 | 35 |
17 | Cu(OAc)2 | t-BuONa | 80 | 0 |
18 | Cu(OAc)2 | Cs2CO3 | 80 | 0 |
19f | Cu(OAc)2 | NaOAc | 80 | 54 |
Entry | Catalyst | Base | Temp./℃ | Yield/% |
---|---|---|---|---|
1 | Ni(acac)2 | NaOAc | 60 | 0 |
2 | Co(acac)2 | NaOAc | 60 | 0 |
3 | Pd(OAc)2 | NaOAc | 60 | 0 |
4 | Cu(OAc)2 | NaOAc | 60 | 67 |
5 | Cu(CHCN)4PF6 | NaOAc | 60 | 66 |
6c | Cu(OAc)2 | NaOAc | 60 | 48 |
7d | Cu(OAc)2 | NaOAc | 60 | 0 |
8e | Cu(OAc)2 | NaOAc | 60 | 70 |
9 | Cu(OAc)2 | NaOAc | 25 | Trace |
10 | Cu(OAc)2 | NaOAc | 40 | 30 |
11 | Cu(OAc)2 | NaOAc | 80 | 77 |
12 | Cu(OAc)2 | CsOAc | 80 | 65 |
13 | Cu(OAc)2 | NaOPiv | 80 | 67 |
14 | Cu(OAc)2 | NaH2PO4 | 80 | 0 |
15 | Cu(OAc)2 | Na2HPO4 | 80 | Trace |
16 | Cu(OAc)2 | Na3PO4 | 80 | 35 |
17 | Cu(OAc)2 | t-BuONa | 80 | 0 |
18 | Cu(OAc)2 | Cs2CO3 | 80 | 0 |
19f | Cu(OAc)2 | NaOAc | 80 | 54 |
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