Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (12): 4661-4689.DOI: 10.6023/cjoc202105041 Previous Articles     Next Articles

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N-羟基邻苯二甲酰亚胺酯在光催化烷基化反应中的研究进展

贺帅旗a, 李昊聪a, 陈晓岚a,*(), Igor B. Krylovb, Alexander O. Terent'evb,*(), 屈凌波a, 於兵a,*()   

  1. a 郑州大学化学学院 绿色催化中心 郑州 450001
    b 俄罗斯科学院泽林斯基有机化学研究所 莫斯科 119991 俄罗斯
  • 收稿日期:2021-05-23 修回日期:2021-06-07 发布日期:2021-06-08
  • 通讯作者: 陈晓岚, Alexander O. Terent'ev, 於兵
  • 作者简介:
    † 共同第一作者
  • 基金资助:
    国家自然科学基金(21971224); 国家自然科学基金(22071222); 高等学校学科创新引智计划(111项目); 高等学校学科创新引智计划(D20003); 河南省高校重点科研(20A150006); 河南省高校重点科研(21A150053); 河南省自然科学基金(202300410375)

Advances of N-Hydroxyphthalimide Esters in Photocatalytic Alkylation Reactions

Shuaiqi Hea, Haocong Lia, Xiaolan Chena(), Igor B. Krylovb, Alexander O. Terent'evb(), Lingbo Qua, Bing Yua()   

  1. a Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
    b Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation
  • Received:2021-05-23 Revised:2021-06-07 Published:2021-06-08
  • Contact: Xiaolan Chen, Alexander O. Terent'ev, Bing Yu
  • About author:
    † These authors contributed equally to this work.
  • Supported by:
    National Natural Science Foundation of China(21971224); National Natural Science Foundation of China(22071222); Programme of Introducing Talents of Discipline to Universities(111项目); Programme of Introducing Talents of Discipline to Universities(D20003); Key Research Projects of Universities in Henan Province(20A150006); Key Research Projects of Universities in Henan Province(21A150053); Natural Science Foundation of Henan Province(202300410375)

N-Hydroxyphthalimide (NHP) esters are easily available, stable, inexpensive, and highly photoactive compounds, which are derived from the corresponding carboxylic acids. In recent years, the application of NHP esters in photocatalytic decarboxylative reactions has captured huge attention. Herein, the vigorous development of photocatalytic alkylation reactions using alkyl NHP esters as alkylating reagents is summarized based on the classification of photocatalysts.

Key words: N-hydroxyphthalimide (NHP) ester, photocatalytic, decarboxylation, alkylation, photocatalyst