Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (10): 3826-3843.DOI: 10.6023/cjoc202107030 Previous Articles     Next Articles

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共价有机框架材料作为非均相配体在有机合成中的应用

陈育萱a, 陈奇b, 张占辉a,*()   

  1. a 河北师范大学化学与材料科学学院 河北省有机功能分子重点实验室 化学国家级实验教学示范中心 石家庄 050024
    b 河北化工医药职业技术学院 质量检测与管理系 石家庄 050026
  • 收稿日期:2021-07-15 修回日期:2021-08-26 发布日期:2021-09-02
  • 通讯作者: 张占辉
  • 基金资助:
    国家自然科学基金(21272053); 河北省自然科学基金(B2020205026)

Application of Covalent Organic Framework Materials as Heterogeneous Ligands in Organic Synthesis

Yuxuan Chena, Qi Chenb, Zhanhui Zhanga()   

  1. a Hebei Key Laboratory of Organic Functional Molecules, National Experimental Chemistry Teaching Center, College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024
    b Department of Quality Inspection and Management, Hebei Chemical and Pharmaceutical Vocational Technology College, Shijiazhuang 050026
  • Received:2021-07-15 Revised:2021-08-26 Published:2021-09-02
  • Contact: Zhanhui Zhang
  • Supported by:
    National Natural Science Foundation of China(21272053); Natural Science Foundation of Hebei Province(B2020205026)

Covalent organic frameworks (COFs) are a new type of crystalline porous material composed of light elements (C, O, N, B, etc.) through covalent bonds. Because of its high specific surface area, high porosity, and high crystallinity, COFs have advantages that other traditional materials can not match. By using COFs as heterogeneous ligands to support metal ions, different types of catalytic reactions can be realized, and the catalyst can be reused. The latest research progress of COFs as heterogeneous ligands supporting different metal ions to catalyze various organic reactions is summarized.

Key words: covalent organic framework materials, heterogeneous catalysis, organic synthesis, heterogeneous ligands