Synthesis of MCM-41 Supported Amino-palladium Complex and Its Catalytic Performance for Heck Reaction

Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (05): 825-831. Previous Articles Next Articles

Original Articles

MCM-41固载胺钯配合物的制备及对Heck反应催化性能的研究

周健民*^,a，杨育林^a，赵岚^a，李校堃，周仁贤^b，郑小明^b

(^a温州医学院药学院温州 325035)
(^b浙江大学催化研究所杭州 310028)

收稿日期:2007-07-31 修回日期:2007-09-25 发布日期:2008-05-20
通讯作者: 周健民

Synthesis of MCM-41 Supported Amino-palladium Complex and Its Catalytic Performance for Heck Reaction

ZHOU Jian-Min*^,a,YANG Yu-Lin^a,ZHAO Lan^a,LI Xiao-Kun^a
ZHOU Ren-Xian^b,ZHENG Xiao-Ming^b

(^a School of Pharmacy, Wenzhou Medical College, Wenzhou 325035)
(^b Institute of Catalysis, Zhejiang University, Hangzhou 310028)

Received:2007-07-31 Revised:2007-09-25 Published:2008-05-20
Contact: ZHOU Jian-Min

Abstract

Using MCM-41 as supporter, a series of MCM-41 supported amino-palladium complexes have been prepared and characterized by XRD, XPS, etc. The XRD and XPS results indicate that the Pd coordi-nates with the NH₂ groups on the MCM-41 surface, and the structure of MCM-41 has been not damaged. Its catalytic performance for Heck arylation of alkene with aryl iodide shows that the catalyst has high activity and stereoselectivity in 70～90 ℃. The product of Heck reaction takes E form. And the effect of the preparation condition of the catalyst on the catalytic performance was examined.

Key words: palladium complex, heterogeneous catalyst, Heck reaction, MCM-41

Cite this article

ZHOU Jian-Min*^,a,YANG Yu-Lin^a,ZHAO Lan^a,LI Xiao-Kun^a
ZHOU Ren-Xian^b,ZHENG Xiao-Ming^b. Synthesis of MCM-41 Supported Amino-palladium Complex and Its Catalytic Performance for Heck Reaction[J]. Chin. J. Org. Chem., 2008, 28(05): 825-831.

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MCM-41固载胺钯配合物的制备及对Heck反应催化性能的研究

Synthesis of MCM-41 Supported Amino-palladium Complex and Its Catalytic Performance for Heck Reaction

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