Advances in the Application of Triethylamine Tris(hydrofluoride) to Organic Synthesis

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (9): 1307-1316. Next Articles

Review

三乙胺三(氟化氢)在有机合成中的应用

戴希杰王亚平赵圣印*

(东华大学化学化工与生物工程学院上海 201620)

收稿日期:2008-09-14 修回日期:2008-11-11 发布日期:2009-12-30
通讯作者: 赵圣印

Advances in the Application of Triethylamine Tris(hydrofluoride) to Organic Synthesis

Dai, Xijie Wang, Yaping Zhao, Shengyin*

(College of Chemistry, Chemical Engineering & Biotechnology, Donghua University, Shanghai 201620)

Received:2008-09-14 Revised:2008-11-11 Published:2009-12-30
Contact: Zhao, Shengyin

Abstract

Fluorination is widely used in organic synthesis. As a kind of fluorinating reagent, triethylamine tris(hydrofluoride) has the advantage on top of others. Several applications of triethylamine tris(hydrofluoride) to organic synthesis are summarized according to reaction type, especially for nucleophilic substitution, the ring-opening fluorination reaction of epoxide, electrophilic addition, desilylation reaction and so on.

Key words: organic synthesis, fluorination, application, triethylamine tris(hydrofluoride)

Cite this article

Dai, Xijie Wang, Yaping Zhao, Shengyin*. Advances in the Application of Triethylamine Tris(hydrofluoride) to Organic Synthesis[J]. Chin. J. Org. Chem., 2009, 29(9): 1307-1316.

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三乙胺三(氟化氢)在有机合成中的应用

Advances in the Application of Triethylamine Tris(hydrofluoride) to Organic Synthesis

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