Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (9): 1167-1170. Previous Articles     Next Articles

Reports

一类新型酯类离子液体的合成

张青山*,赵丹,赵君波,郭炳南,吴锋   

  1. (北京理工大学化工与环境学院 北京 100081)
  • 收稿日期:2006-05-23 修回日期:2006-11-09 发布日期:2007-08-30
  • 通讯作者: 张青山

Synthesis of a New Kind of Ester Ionic Liquid

ZHANG Qing-Shan*,ZHAO Dan,ZHAO Jun-Bo,GUO Bing-Nan,WU Feng   

  1. (School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081)
  • Received:2006-05-23 Revised:2006-11-09 Published:2007-08-30
  • Contact: ZHANG Qing-Shan

A series of ionic liquids containing ethyl acetate moiety on the cations were designed and synthesized, using starting material ethyl chloroacetate and N-heterocyclic compounds (1-methylimidazole, pyridine, N-ethylpiperidine and N-methyl morpholine) through two synthesis steps. All 12 synthesized compounds were characterized by some physical property measurement, elemental analysis and 1H NMR spectra. The melting points of the most compounds are below 100 ℃. They are room temperature ionic liquids. The relative stability of the prepared ionic liquids owes to the wide scope of their thermostability.

Key words: synthesis, functionalized ionic liquid, ester, ionic liquid