Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (01): 178-183.DOI: 10.6023/cjoc201207045 Previous Articles     Next Articles

Notes

德国小蠊性信息素类似物的设计与合成

王晓波a, 张钟宁b, 杨新玲a   

  1. a 中国农业大学理学院应用化学系 北京 100193;
    b 中国科学院动物研究所农业虫害鼠害综合治理研究国家重点实验室 北京 100101
  • 收稿日期:2012-07-28 修回日期:2012-09-18 发布日期:2012-09-21
  • 通讯作者: 杨新玲 E-mail:yangxl@cau.edu.cn

Design and Synthesis of German Cockroach (Blattella germanica) Sex Pheromone Analogues

Wang Xiaoboa, Zhang Zhongningb, Yang Xinlinga   

  1. a Department of Applied Chemistry, College of Science, China Agricultural University, Beijing 100193;
    b State Key Laboratory of Integrated Management of Pest Insects and Rodents, Institute of Zoology, Chinese Academy of Sciences, Beijing 100101
  • Received:2012-07-28 Revised:2012-09-18 Published:2012-09-21

As one of the most important sanitation pests worldwide, German cockroach (Blattella germanica L.) is difficult to control. Insect sex pheromones are safe and efficient attractants used in integrated pest management. The sex pheromone of German cockroach had been identified as blattellaquinone. The instability hampered the application of this compound. In order to find new and stable structures, a number of analogues were designed and synthesized by modification of the quinone ring (A), aliphatic terminal (B) and ester group (C) of blattellaquinone. The structures were confirmed by 1H NMR, IR spectra and HRMS analysis.

Key words: Blattella germanica, blattellaquinone, sex pheromone analogues, synthesis