Recent Progress on Cu-Catalyzed Asymmetric Conjugate Borylation to α,β-Unsaturated Compounds

doi:10.6023/cjoc201409019

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (1): 1-14.DOI: 10.6023/cjoc201409019 Previous Articles Next Articles

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铜催化的α,β-不饱和化合物的不对称共轭硼化反应研究进展

刘强^a,b, 田兵^a,b, 田平^b, 童晓峰^a, 林国强^b

a 华东理工大学上海市功能性材料化学重点实验室上海 200237;
b 中国科学院上海有机化学研究所天然产物有机合成化学重点实验室上海 200032

收稿日期:2014-09-09 修回日期:2014-09-30 发布日期:2014-10-09
通讯作者: 田平, 童晓峰, 林国强 E-mail:tianping@sioc.ac.cn;tongxf@ecust.edu.cn;lingq@sioc.ac.cn
基金资助:
国家自然科学基金(Nos. 21372243, 21102161)资助项目.

Recent Progress on Cu-Catalyzed Asymmetric Conjugate Borylation to α,β-Unsaturated Compounds

Liu Qiang^a,b, Tian Bing^a,b, Tian Ping^b, Tong Xiaofeng^a, Lin Guo-Qiang^b

a Shanghai Key Laboratory of Functional Materials Chemistry, East China University of Science and Technology, Shanghai 200237;
b CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received:2014-09-09 Revised:2014-09-30 Published:2014-10-09
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21372243, 21102161).

Organoborons are an important class of organic compounds, because organoboronic acids and their derivatives can be readily converted into a wide variety of functionalities in a stereospecific manner. Cu-catalyzed asymmetric conjugate borylation of unsaturated compounds with bis(pinacolato)diboron (B₂pin₂) has emerged as a novel synthetic tool to afford a variety of organoboron compounds. Herein, this research progress, which involves using bisphosphine, N-heterocyclic carbine, and other chiral ligands, is summarized.

Key words: copper, α,β-unsaturated compounds, asymmetric conjugate borylation

Cite this article

Liu Qiang, Tian Bing, Tian Ping, Tong Xiaofeng, Lin Guo-Qiang. Recent Progress on Cu-Catalyzed Asymmetric Conjugate Borylation to α,β-Unsaturated Compounds[J]. Chin. J. Org. Chem., 2015, 35(1): 1-14.

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铜催化的α,β-不饱和化合物的不对称共轭硼化反应研究进展

Recent Progress on Cu-Catalyzed Asymmetric Conjugate Borylation to α,β-Unsaturated Compounds

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