Ag2CO3 Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds

doi:10.6023/cjoc201607007

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (1): 226-231.DOI: 10.6023/cjoc201607007 Previous Articles Next Articles

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碳酸银介导的芳胺氧化脱氢偶联制备芳香偶氮化合物

安玉龙, 谭鸿儒, 赵圣印

东华大学化学化工与生物工程学院上海 201620

收稿日期:2016-07-05 修回日期:2016-08-17 发布日期:2016-09-01
通讯作者: 赵圣印 E-mail:syzhao8@dhu.edu.cn
基金资助:
上海市科学自然基金（No. 15ZR1401400）以及中央高校教育基金（Nos. CUSF-DH-D-2016028，BCZD2016004）资助项目.

Ag₂CO₃ Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds

An Yulong, Tan Hongru, Zhao Shengyin

College of Chemistry, Chemical and Biological Engineering, Donghua University, Shanghai 201620

Received:2016-07-05 Revised:2016-08-17 Published:2016-09-01
Supported by:
Project supported by the Natural Science Foundation of Shanghai Municipality(No. 15ZR1401400) and the Fundamental Research Funds for the Central Universities from the Ministry of Education of China(Nos. CUSF-DH-D-2016028, BCZD2016004).

Aromatic azo compounds are widely used as organic dyes,biological medicines,food additives,radical initiators and so on.This paper describes an efficient protocol for the synthesis of aromatic azo compounds from anilines via Ag₂CO₃ mediated oxidative dehydrogenative coupling reactions in the presence of(CH₃)₃COK in PhCl.The yields are up to 92%,and this method is easy-operation and provides a practical process to synthesize aromatic azo compounds under mild conditions.

Key words: anilines, Ag₂CO₃, (CH₃)₃COK, aromatic azo compounds

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An Yulong, Tan Hongru, Zhao Shengyin. Ag₂CO₃ Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds[J]. Chin. J. Org. Chem., 2017, 37(1): 226-231.

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碳酸银介导的芳胺氧化脱氢偶联制备芳香偶氮化合物

Ag₂CO₃ Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds

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