Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (10): 2519-2533.DOI: 10.6023/cjoc201804017 Previous Articles     Next Articles



徐方宁, 韩维   

  1. 南京师范大学化学与材料科学学院 南京 210023
  • 收稿日期:2018-04-10 修回日期:2018-05-28 发布日期:2018-06-07
  • 通讯作者: 韩维,
  • 基金资助:


Research Progress in Transition-Metal-Free Carbonylation Reactions

Xu Fangning, Han Wei   

  1. School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023
  • Received:2018-04-10 Revised:2018-05-28 Published:2018-06-07
  • Contact: 10.6023/cjoc201804017
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21776139), the Natural Science Foundation of Jiangsu Province (No. BK20161553), the Natural Science Foundation of Jiangsu Provincial Colleges and Universities (No. 16KJB150019), the Qing Lan Project of Nanjing Normal University and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

Carbon monoxide is a readily available and cheap C1 feedstock. Carbonylation, the direct incorporation of carbon monoxide into organic molecules, is a very important and fundamental chemical transformation. In recent years, developing transition-metal-free systems for the carbonylation has attracted highly attention from many researchers. The recent rearch progress of transition-metal-free carbonylations for the synthesis of aldehydes, ketones, esters, amides, acids, anhydrides, acyl chloride, and alcohols is reviewed. And the development and application prospects for transition-metal-free carbonylation are also discussed.

Key words: carbon monoxide, carbonylation, transition-metal-free, synthetic methods