稀土圆偏振发光材料研究进展

doi:10.6023/A24030071

化学学报 ›› 2024, Vol. 82 ›› Issue (6): 707-730.DOI: 10.6023/A24030071 上一篇

综述

稀土圆偏振发光材料研究进展

李小贞^a^,^b, 孙庆福^b^,^*()

a 福建师范大学海峡柔性电子实验室福州 350117
b 中国科学院福建物质结构研究所结构化学国家重点实验室福州 350002

投稿日期:2024-03-06 发布日期:2024-04-28

作者简介:

李小贞, 2018年于中国科学院福建物质结构研究所获得理学博士学位, 2018~2021年在中国科学院福建物质结构研究所从事博士后研究, 2021年~2022年在中国科学院福建物质结构研究所担任副研究员, 2022年入职福建师范大学. 主要研究方向为超分子自组装和手性稀土功能材料.

孙庆福, 中国科学院福建物质结构研究所研究员, 课题组长. 2011年获东京大学应用化学专业博士学位, 留日期间曾获日本学术振兴会青年科学家(JSPS-DC及JSPS-PD)项目及国家优秀自费留学生奖学金资助. 2012年赴美国能源部资助下的劳伦斯伯克利国家实验室及加州大学伯克利分校进行博士后研究. 2013年以国家高层次人才引进到中国科学院福建物质结构研究所独立开展研究工作. 主要研究兴趣包括大环和笼状超分子配合物的设计合成、发光及磁性调控、主客体性质及仿酶催化等, 研究成果发表在Science, Nat. Chem., Nat. Commun., J. Am. Chem. Soc.等知名期刊. 曾获得国家自然科学基金委杰出青年基金、中组部“海外高层次人才计划”、中科院“人才引进计划”、福建省“创新创业人才计划”等人才项目, 获得中国化学会青年化学奖、中科院优秀导师奖、福建省青年五四奖章标兵、福建省青年科技奖等荣誉.

基金资助:
福建省自然科学基金(2021J02016); 福建省自然科学基金(2023J01528); 国家自然科学基金(21901245)

Research Progress of Rare Earth-Based Circularly Polarized Luminescent Materials

Xiaozhen Li^a^,^b, Qingfu Sun^b,*()

a Strait Institute of Flexible Electronics, Fujian Normal University, Fuzhou 350117
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002

Received:2024-03-06 Published:2024-04-28
Contact: * E-mail: qfsun@fjirsm.ac.cn
Supported by:
Natural Science Foundation of Fujian Province(2021J02016); Natural Science Foundation of Fujian Province(2023J01528); National Natural Science Foundation of China(21901245)

文章分享

摘要/Abstract

圆偏振光(CPL)是一种特殊而重要的光, 在三维显示、有机光电器件、安全油墨、生物和化学探针等方面具有广泛应用前景. 发光不对称因子和发光量子产率是衡量圆偏振发光性能的重要指标. 受磁跃迁偶极矩较小的影响, 大部分手性材料的发光不对称因子较小. 稀土金属离子优异的光、电性能和部分磁偶极跃迁允许特性使手性稀土化合物被认为是理想的具有高发光不对称因子和高发光量子产率的圆偏振发光材料. 基于此, 本综述归纳总结了手性稀土材料在可见光、近红外光和双光子激发圆偏振发光材料等方面的研究进展, 探讨了配体、溶剂、阴离子、多级自组装作用和外界刺激等因素对圆偏振发光性能的调控规律, 总结了手性稀土圆偏振发光材料在圆偏振有机发光二极管、生物传感、检测、防伪和成像等方面的应用, 以及该领域目前面临的主要机遇和挑战.

关键词: 稀土, 手性, 圆偏振发光, 自组装, 发光不对称因子

As a special and important light, circularly polarized light (CPL) has shown unprecedented potentials in the applications of advanced three-dimensional (3D) displays, organic optoelectronic devices, security inks, and biological or chemical probes. Luminescence dissymmetry factor (g_lum) and quantum yields (Φ) are important factors that adopted to evaluate the magnitudes of CPL signals. Most chiral luminescent materials have low g_lum values due to the low magnetic-dipole transition moments. Attributing to the unique photophysical, optoelectronic properties and magnetic-dipole allowed transitions, chiral rare earth materials are promising candidates for circularly polarized luminescent materials possessing both large g_lum and high Φ. Herein, a comprehensive and up-to-date overview of the research progress of rare earth-based circularly polarized luminescent materials is presented, which contains: (i) the developments of visible light, near-infrared light (NIR) and two-photon circularly polarized luminescence; (ii) the effects of ligands, solvents, anions, supermolecular self-assembly, external stimulus on the circularly polarized luminescence performances; (iii) the applications in circularly polarized-organic light-emitting diodes (CP-OLED), biosensing, detection, and security devices. Finally, current challenges and future opportunities are discussed.

Key words: rare earth, chirality, circularly polarized luminescence, self-assembly, luminescence dissymmetry factor

引用此文

李小贞, 孙庆福. 稀土圆偏振发光材料研究进展[J]. 化学学报, 2024, 82(6): 707-730.

Xiaozhen Li, Qingfu Sun. Research Progress of Rare Earth-Based Circularly Polarized Luminescent Materials[J]. Acta Chimica Sinica, 2024, 82(6): 707-730.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

图/表 10

图1. 通过“天线效应”激发Ln3+发光的能量传递机理示意图[12]

化合物	λ_em/nm	PLQY/%	跃迁	g_lum		文献
[EuL1]³⁺		0.06/H₂O 0.3/D₂O				[45]
[Eu^RL4]³⁺	588, 593, 615, 668, 687		⁵D₀→⁷F_J	+0.02, –0.03 (ΔJ=1), 0.12, 0.4, –0.11 (ΔJ=2,3,4)		[45]
[Eu^RL5]³⁺	580, 590, 615, 650, 680		⁵D₀→⁷F_J	–0.12, +0.18 (ΔJ=1） –0.1, –0.3, –0.11 (ΔJ=2,3,4)		[46]
[Eu^SL6]³⁺	588, 595, 614	21/H₂O 27/D₂O	⁵D₀→⁷F_J	+0.18, –0.16 (ΔJ=1), –0.04 (ΔJ=2)		[47]
[Eu^SL7]^–	591, 657	14/H₂O/MeOH 47/DMSO	⁵D₀→⁷F_J	–0.18 (ΔJ=1) +0.17 (ΔJ=3)		[50]
[Eu^RL7]^–	591, 657	14.9/H₂O/MeOH 53/DMSO	⁵D₀→⁷F_J	+0.17 (ΔJ=1) +0.13 (ΔJ=3)		[50]
[Eu^SL8]^–	591, 657	11/H₂O/MeOH 0.45/DMSO	⁵D₀→⁷F_J	–0.11 (ΔJ=1) –0.12 (ΔJ=3)		[50]
[Eu^SL9]^–	591, 657	0.40/DMSO	⁵D₀→⁷F_J	+0.30 (ΔJ=1) +0.25 (ΔJ=3)		[50]
[Eu^SL10]^–	591, 653	10.2/H₂O/MeOH 44.1/DMSO	⁵D₀→⁷F_J	–0.11 (ΔJ=1) –0.10 (ΔJ=3)		[50]
[Eu^SL11]^–	588, 657	21.9/H₂O/MeOH 49.7/DMSO	⁵D₀→⁷F_J	–0.17 (ΔJ=1) –0.29 (ΔJ=3)		[50]
[Eu^RL14]⁺	596	2.3	⁵D₀→⁷F₁	+0.298		[53]
EuL15	586.6, 594.2, 543.6	7.7	⁵D₀→⁷F₁	±0.046, ±0.12, ±0.083		[54]
[Eu^RRL17]³⁺			⁵D₀→⁷F₁ ⁵D₀→⁷F₄	–0.19, –0.22		[55]
[Eu^RL18]³⁺	590		⁵D₀→⁷F₁	+0.02		[56]
[Eu^RL19-Me]²⁺	587	55		1.7×10^–3		[57]
[Eu^RL19-ⁱPr]²⁺	560	53		1.8×10^–3		[57]
[EuL20]⁺	598, 607		⁵D₀→⁷F_J	±0.2 (ΔJ=1), ±0.2 (ΔJ=2)		[58]
Eu(+L23)₃	588.2			–0.78		[59]
Eu(+L24)₃	612		⁵D₀→⁷F₂	+0.003		[15]
Cs[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+1.38 (ΔJ=1) –0.23 (ΔJ=2)		[15]
Cs[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+1.32 (ΔJ=1) –0.19 (ΔJ=2)		[15]
Na[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+0.06 (ΔJ=1) –0.01 (ΔJ=2)		[15]
Cs[Eu(L24)₄]	594		⁵D₀→⁷F₁	±0.15		[61]
Cs[Eu(L25)₄]	594		⁵D₀→⁷F₁	±0.15		[61]
Cs[Eu(L25)₄]	594		⁵D₀→⁷F₁	±0.82		[61]
[Eu(L27)₃]³⁺	590.5, 595.3, 615.6		⁵D₀→⁷F_J	±0.19, ±0.18 (ΔJ=1) ±0.21 (ΔJ=2)		[63]
Eu(L30)₃	600, 619			±0.13, ±0.06		[64]
[Eu(L32)₂]³⁺	593			±0.12		[65]
[Eu(L33)₂]³⁺	592.2, 616.2	17		±0.18, ±0.03		[66]
[Eu(L34)₃]³⁺		4	⁵D₀→⁷F₁	±0.028, ±0.020		[67]
Eu(L37)₂(OTf)₃	593		⁵D₀→⁷F₁	±0.120		[68]
Eu^SL62	595, 600, 658, 708, 713	11	⁵D₀→⁷F_J	+0.18, +0.33, –0.25, +0.31, –0.37		[69]
EuL63	557, 599, 655, 708	47	⁵D₀→⁷F_J	±0.19, ±0.15, ±0.19, ±0.32		[70]
[Tb^SL1]³⁺	545, 620	25	⁵D₄→⁷F_J	–0.25 (ΔJ=–1), +0.29(ΔJ=+1)		[44,45]
[Tb^RL4]³⁺		49/H₂O 81/D₂O				[45]
[Tb^SL6]³⁺	545	36/H₂O 46/D₂O	⁵D₄→⁷F₅		+0.12	[47]
[Tb^SL6']³⁺	489, 540, 583		⁵D₄→⁷F_J		+0.02, –0.13, +0.01	[48]
[Tb^SL12]^–	542.5, 551		⁵D₄→⁷F₅		0.285, 0.173	[51]
[Tb^SL13]^–	542.5, 551		⁵D₄→⁷F₅		0.241, 0.151	[51]
[Tb^RL14]⁺	543	63	⁵D₄→⁷F₅		+0.044	[53]
TbL15	545.8, 551	57	⁵D₄→⁷F₅		±0.078, ±0.051	[54]
TbL16	542.0, 545.6, 551.2	30	⁵D₄→⁷F₅		±0.14, ±0.34, ±0.40	[26]
[Tb^RRL17]³⁺			⁵D₄→⁷F₅		–0.19	[55]
[Tb^RL18]³⁺	540		⁵D₄→⁷F₅		–0.01, +0.06, –0.02	[56]
[TbL20]⁺	546		⁵D₄→⁷F₅		±0.01 (ΔJ=1)	[58]
[Tb(^RL26)₃]³⁺	542	1.2	⁵D₄→⁷F₅		0.02	[62]
[Tb(L29)₃]³⁺	546		⁵D₄→⁷F₅		±0.05	[71]
[Tb(L31)₃]³⁺	542				±0.14	[65]
[Tb(L34)₃]³⁺		0.022	⁵D₄→⁷F₅		±0.06	[67]
Tb(L35)₃Na₃(thf)₆	524	26	⁵D₄→⁷F₅		±0.32	[72]
Tb(L36)₃Na₃(thf)₆	545	84.6	⁵D₄→⁷F₅		±0.53	[73]
Tb^SL62	539, 543, 548, 620, 622	50	⁵D₄→⁷F_J		+0.16, –0.25, +0.32, +0.28, –0.32	[69]
[Dy^RL1]³⁺	657, 667		⁴F_9/2→⁶H_11/2		0.35, –0.41	[45]
[Dy^RL14]⁺	669	1.3	⁴F_9/2→⁶H_11/2		+0.013	[53]
Dy(L35)₃Na₃(thf)₆	756	17	⁴F_9/2→⁶H_9/2		±0.33	[72]
Dy(L36)₃Na₃(thf)₆	760	15.5	⁴F_9/2→⁶H_9/2		±0.53	[73]
[Sm^RL14]⁺	565, 597	0.8	⁴G_5/2→⁶H_7/2 ⁴G_5/2→⁶H_5/2		–0.027, –0.028	[53]
Cs[Sm(+L24)₄]	553, 561, 575, 588, 598, 605, 611, 617		⁴G_5/2→⁶H_J		–1.15, –0.35, +0.96 (ΔJ=0) –0.45, +1.15, –0.76, +0.24, +0.15 (ΔJ=1)	[18]
[Sm(L29)₃]³⁺	560, 600				±0.5, ±0.28	[74]
Sm(L35)₃Na₃(thf)₆	603	4	⁴G_5/2→⁶H_7/2		±0.44	[72]
Sm(L36)₃Na₃(thf)₆	610	2.8	⁴G_5/2→⁶H_7/2		±0.50	[73]
Sm(L37)₂(OTf)₃	559		⁴G_5/2→⁶H_5/2		±0.272	[68]

化合物	λ_em/nm	PLQY/%	跃迁	g_lum		文献
[EuL1]³⁺		0.06/H₂O 0.3/D₂O				[45]
[Eu^RL4]³⁺	588, 593, 615, 668, 687		⁵D₀→⁷F_J	+0.02, –0.03 (ΔJ=1), 0.12, 0.4, –0.11 (ΔJ=2,3,4)		[45]
[Eu^RL5]³⁺	580, 590, 615, 650, 680		⁵D₀→⁷F_J	–0.12, +0.18 (ΔJ=1） –0.1, –0.3, –0.11 (ΔJ=2,3,4)		[46]
[Eu^SL6]³⁺	588, 595, 614	21/H₂O 27/D₂O	⁵D₀→⁷F_J	+0.18, –0.16 (ΔJ=1), –0.04 (ΔJ=2)		[47]
[Eu^SL7]^–	591, 657	14/H₂O/MeOH 47/DMSO	⁵D₀→⁷F_J	–0.18 (ΔJ=1) +0.17 (ΔJ=3)		[50]
[Eu^RL7]^–	591, 657	14.9/H₂O/MeOH 53/DMSO	⁵D₀→⁷F_J	+0.17 (ΔJ=1) +0.13 (ΔJ=3)		[50]
[Eu^SL8]^–	591, 657	11/H₂O/MeOH 0.45/DMSO	⁵D₀→⁷F_J	–0.11 (ΔJ=1) –0.12 (ΔJ=3)		[50]
[Eu^SL9]^–	591, 657	0.40/DMSO	⁵D₀→⁷F_J	+0.30 (ΔJ=1) +0.25 (ΔJ=3)		[50]
[Eu^SL10]^–	591, 653	10.2/H₂O/MeOH 44.1/DMSO	⁵D₀→⁷F_J	–0.11 (ΔJ=1) –0.10 (ΔJ=3)		[50]
[Eu^SL11]^–	588, 657	21.9/H₂O/MeOH 49.7/DMSO	⁵D₀→⁷F_J	–0.17 (ΔJ=1) –0.29 (ΔJ=3)		[50]
[Eu^RL14]⁺	596	2.3	⁵D₀→⁷F₁	+0.298		[53]
EuL15	586.6, 594.2, 543.6	7.7	⁵D₀→⁷F₁	±0.046, ±0.12, ±0.083		[54]
[Eu^RRL17]³⁺			⁵D₀→⁷F₁ ⁵D₀→⁷F₄	–0.19, –0.22		[55]
[Eu^RL18]³⁺	590		⁵D₀→⁷F₁	+0.02		[56]
[Eu^RL19-Me]²⁺	587	55		1.7×10^–3		[57]
[Eu^RL19-ⁱPr]²⁺	560	53		1.8×10^–3		[57]
[EuL20]⁺	598, 607		⁵D₀→⁷F_J	±0.2 (ΔJ=1), ±0.2 (ΔJ=2)		[58]
Eu(+L23)₃	588.2			–0.78		[59]
Eu(+L24)₃	612		⁵D₀→⁷F₂	+0.003		[15]
Cs[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+1.38 (ΔJ=1) –0.23 (ΔJ=2)		[15]
Cs[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+1.32 (ΔJ=1) –0.19 (ΔJ=2)		[15]
Na[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+0.06 (ΔJ=1) –0.01 (ΔJ=2)		[15]
Cs[Eu(L24)₄]	594		⁵D₀→⁷F₁	±0.15		[61]
Cs[Eu(L25)₄]	594		⁵D₀→⁷F₁	±0.15		[61]
Cs[Eu(L25)₄]	594		⁵D₀→⁷F₁	±0.82		[61]
[Eu(L27)₃]³⁺	590.5, 595.3, 615.6		⁵D₀→⁷F_J	±0.19, ±0.18 (ΔJ=1) ±0.21 (ΔJ=2)		[63]
Eu(L30)₃	600, 619			±0.13, ±0.06		[64]
[Eu(L32)₂]³⁺	593			±0.12		[65]
[Eu(L33)₂]³⁺	592.2, 616.2	17		±0.18, ±0.03		[66]
[Eu(L34)₃]³⁺		4	⁵D₀→⁷F₁	±0.028, ±0.020		[67]
Eu(L37)₂(OTf)₃	593		⁵D₀→⁷F₁	±0.120		[68]
Eu^SL62	595, 600, 658, 708, 713	11	⁵D₀→⁷F_J	+0.18, +0.33, –0.25, +0.31, –0.37		[69]
EuL63	557, 599, 655, 708	47	⁵D₀→⁷F_J	±0.19, ±0.15, ±0.19, ±0.32		[70]
[Tb^SL1]³⁺	545, 620	25	⁵D₄→⁷F_J	–0.25 (ΔJ=–1), +0.29(ΔJ=+1)		[44,45]
[Tb^RL4]³⁺		49/H₂O 81/D₂O				[45]
[Tb^SL6]³⁺	545	36/H₂O 46/D₂O	⁵D₄→⁷F₅		+0.12	[47]
[Tb^SL6']³⁺	489, 540, 583		⁵D₄→⁷F_J		+0.02, –0.13, +0.01	[48]
[Tb^SL12]^–	542.5, 551		⁵D₄→⁷F₅		0.285, 0.173	[51]
[Tb^SL13]^–	542.5, 551		⁵D₄→⁷F₅		0.241, 0.151	[51]
[Tb^RL14]⁺	543	63	⁵D₄→⁷F₅		+0.044	[53]
TbL15	545.8, 551	57	⁵D₄→⁷F₅		±0.078, ±0.051	[54]
TbL16	542.0, 545.6, 551.2	30	⁵D₄→⁷F₅		±0.14, ±0.34, ±0.40	[26]
[Tb^RRL17]³⁺			⁵D₄→⁷F₅		–0.19	[55]
[Tb^RL18]³⁺	540		⁵D₄→⁷F₅		–0.01, +0.06, –0.02	[56]
[TbL20]⁺	546		⁵D₄→⁷F₅		±0.01 (ΔJ=1)	[58]
[Tb(^RL26)₃]³⁺	542	1.2	⁵D₄→⁷F₅		0.02	[62]
[Tb(L29)₃]³⁺	546		⁵D₄→⁷F₅		±0.05	[71]
[Tb(L31)₃]³⁺	542				±0.14	[65]
[Tb(L34)₃]³⁺		0.022	⁵D₄→⁷F₅		±0.06	[67]
Tb(L35)₃Na₃(thf)₆	524	26	⁵D₄→⁷F₅		±0.32	[72]
Tb(L36)₃Na₃(thf)₆	545	84.6	⁵D₄→⁷F₅		±0.53	[73]
Tb^SL62	539, 543, 548, 620, 622	50	⁵D₄→⁷F_J		+0.16, –0.25, +0.32, +0.28, –0.32	[69]
[Dy^RL1]³⁺	657, 667		⁴F_9/2→⁶H_11/2		0.35, –0.41	[45]
[Dy^RL14]⁺	669	1.3	⁴F_9/2→⁶H_11/2		+0.013	[53]
Dy(L35)₃Na₃(thf)₆	756	17	⁴F_9/2→⁶H_9/2		±0.33	[72]
Dy(L36)₃Na₃(thf)₆	760	15.5	⁴F_9/2→⁶H_9/2		±0.53	[73]
[Sm^RL14]⁺	565, 597	0.8	⁴G_5/2→⁶H_7/2 ⁴G_5/2→⁶H_5/2		–0.027, –0.028	[53]
Cs[Sm(+L24)₄]	553, 561, 575, 588, 598, 605, 611, 617		⁴G_5/2→⁶H_J		–1.15, –0.35, +0.96 (ΔJ=0) –0.45, +1.15, –0.76, +0.24, +0.15 (ΔJ=1)	[18]
[Sm(L29)₃]³⁺	560, 600				±0.5, ±0.28	[74]
Sm(L35)₃Na₃(thf)₆	603	4	⁴G_5/2→⁶H_7/2		±0.44	[72]
Sm(L36)₃Na₃(thf)₆	610	2.8	⁴G_5/2→⁶H_7/2		±0.50	[73]
Sm(L37)₂(OTf)₃	559		⁴G_5/2→⁶H_5/2		±0.272	[68]

表1. 部分单核稀土配合物的圆偏振发光性能

Table 1. The circularly polarized luminescence of some mononuclear rare-earth complexes

表1. 部分单核稀土配合物的圆偏振发光性能

Table 1. The circularly polarized luminescence of some mononuclear rare-earth complexes

图2. ML单核手性配合物的结构示意图(只展示配体的一种手性结构)

Figure 2. Structures of some chiral ML mononuclear coordination complexes (only one chiral structure of the ligands is illustrated)

图3. 构筑MLn单核手性稀土配合物的部分手性和非手性配体的结构示意图(只展示配体的一种手性结构)

Figure 3. Structures of some chiral and achiral ligands that have been used to construct chiral MLn mononuclear rare-earth complexes (only one chiral structure of the ligands is illustrated)

图4. (a) 合成手性稀土基超分子组装体的部分配体的结构. (b) [Eu2(L41)3]6+组装体的合成、发光光谱和CPL光谱[78]. (c) [Eu2(L58)4]2–组装体的合成[79]. (d) [Eu3(SL60)6]3+和轮状[Eu?(Δ-Eu(SL60)2Λ-Eu(SL60)2)3]9+的合成[80]

Figure 4. Structures of some ligands that have been used to synthesis chiral rare earth-based supermolecular assemblies. (b) Synthesis of [Eu2(L41)3]6+, luminescence spectrum and CPL spectra of [Eu2(L41)3]6+.[78] Reproduced with permission from Ref. [78]. Copyright 2009, American Chemical Society. (c) Synthesis of [Eu2(L58)4]2–.[79] Reproduced with permission from Ref. [79]. Copyright 2020, American Chemical Society. (d) Synthesis of [Eu3(SL60)6]3+ and wheel-like [Eu?(Δ-Eu(SL60)2Λ-Eu(SL60)2)3]9+.[80] Reproduced with permission from Ref. [80]. Copyright 2012, American Chemical Society

图5. (a) D4对称性[R/SL32]8Ln8(thp)8的反应示意图[1]. (b) Δ/Λ-Eu4(tdtp)4(R/SL37)4四面体笼的合成及其在氯仿溶液中的CPL光谱[103]. (c)客体分子诱导的Eu4L4四面体笼的自组装和转化, 手性诱导分子的结构示意图和手性Eu4L4笼的CPL光谱[104]

Figure 5. (a) Reaction scheme of D4-symmetrical [R/SL32]8Ln8(thp)8.[1] Reproduced with permission from Ref. [1]. Copyright 2020, American Chemical Society. (b) Syntheses of the tetrahedral cages of Δ/Λ-Eu4(tdtp)4(R/SL37)4 and their CPL spectra in CHCl3.[103] Reproduced with permission from Ref. [103]. Copyright 2019, American Chemical Society. (c) Guest-driven self-assembly/transformation showing chiral induction of Eu4L4 tetrahedral cages, the chemical structures of chiral induction molecules, and the CPL spectra of chiral Eu4L4 cages.[104] Reproduced with permission from Ref. [104]. Copyright 2022, American Chemical Society.

图6. (a) M[Eu(L24)4] (M=Na, K, Rb, Cs)聚集体的TEM图像及相应的CD, UV-吸收, CPL和发射光谱[16]. (b) Eu-基配位聚合物的设计原则及化学结构式[110]. (c) (S/R-M3HQ)2RbEu(NO3)6的晶体结构及其晶体样品和粉末样品的CPL光谱[111]

Figure 6. (a) TEM images of the aggregates formed from M[Eu(L24)4] (M=Na, K, Rb, Cs), CD, UV-vis absorption, CPL, and emission spectra of M[Eu(L24)4] (M=Na, K, Rb, Cs).[16] Reproduced with permission from Ref. [16]. Copyright 2016, The Royal Society of Chemistry. (b) The conceptual design of a chiral Eu-based coordination polymer and the chemical structures of the chiral coordination polymers.[110] Reproduced with permission from Ref. [110]. Copyright 2023, The Royal Society of Chemistry. (c) Crystal structures of (S/RM3HQ)2RbEu(NO3)6 and the CPL spectra of the crystal and powder samples.[111] Reproduced with permission from Ref. [111]. Copyright 2022, The Royal Society of Chemistry

图7. (a) (RBinol)3LnNa3的合成和在四氢呋喃溶液中的CPL光谱[19]. (b) [Er(dpe-pybox)2]3+的结构及其在氘代氯仿中的NIR-CPL光谱[127]. (c) (R/SSpinol)3LnNa3(thf)6的合成及(R/SSpinol)3SmNa3(thf)6在四氢呋喃中的CPL光谱[73]. (d) [Eu(pi-pybox)2]3+和[Eu(pp-pybox)3]3+的结构及[Eu(pp-pybox)3]3+的双光子激发CPL光谱[128]. (e) R-Vanol和[Ln(pc)]Cl的化学结构式

Figure 7. (a) Synthesis of (RBinol)3LnNa3 and normalized CPL spectra of (R/SBinol)3LnNa3 in tetrahydrofuran solutions.[19] Reproduced with permission from Ref. [19]. Copyright 2022, American Chemical Society. (b) Structure of [Er(dpe-pybox)2]3+ and NIR-CPL spectra of enantiomers of [Er(dpe-pybox)2]3+ in deuterated chloroform.[127] Reproduced with permission from Ref. [127]. Copyright 2022, Wiley-VCH. (c) Synthesis of (R/S-Spinol)3LnNa3(thf)6 and CPL spectra of (R/S-Spinol)3SmNa3(thf)6 in tetrahydrofuran solutions.[73] Reproduced with permission from Ref. [73]. Copyright 2022, American Chemical Society. (d) The structures of [Eu(pi-pybox)2]3+ and [Eu(pp-pybox)3]3+, and the two-photon excitation CPL spectra of [Eu(pp-pybox)3]3+.[128] Reproduced with permission from Ref. [128]. Copyright 2023, American Chemical Society. (e) Structures of R-Vanol and [Ln(pc)]Cl

图8. (a)部分单核手性稀土配合物及手性配体的结构. (b) [(Eu(R-L)(hfa)3] (L=L31, L32, L64)的结构、ORTEP和空间填充结构示意图[129]. (c)[Eu4L6]12+(L=L50, L54, L56)组装体手性发光性能不同的来源示意图及其相应的CD和CPL光谱. (d) Eu4(RRL50)n(L67)6–n(OTf)12 (n=0~6)四面体笼中的手性放大效应, 归一化的CD和UV-Vis吸收光谱及归一化的CD光谱与配体含量的关系图[108]. (e) Eu4L4四面体笼的自组装和手性放大过程[130]

Figure 8. (a) Structures of some chiral mononuclear rare earth complexes and chiral ligands. (b) Chemical structures, ORTEP and space-filling (bottom) views of [(Eu(R-L)(hfa)3] (L=L31, L32, L64).[129] Reproduced with permission from Ref. [129]. Copyright 2011, American Chemical Society. (c) Schematic representation of a plausible reason to explain the different extent of chiral optical intensity of [Eu4L6]12+(L=L50, L54, L56) complexes and the corresponding CD and CPL spectra. (d) Schematic diagram of chiral amplification experiment of Eu4(RRL50)n(L67)6–n(OTf)12 (n=0~6) tetrahedral cage, normalized CD (top) and normalized UV-Vis absorption spectra of Eu4(RRL50)n(L67)6–n(OTf)12 and plots of normalized CD intensities as a function of the contents of the ligands.[108] Reproduced with permission from Ref. [108]. Copyright 2017, Nature Publishing Group. (e) Process of self-assembly and chiral amplification in Eu4L4 tetrahedral cages.[130] Reproduced with permission from Ref. [130]. Copyright 2023, Wiley-VCH

图9. (a) 1(Eu)-o和1(Eu)-c之间可逆的光转化反应及光照前后手性配合物的圆偏振发光性能的变化[119]. (b) [Eu2(L52)3]6+优化的结构模型[147]. (c) EuL (L=L69~L75)的分子结构[148]. (d) CP-OLED器件的发光层和传输层的分子结构[149]. (e)具有圆偏振发光性能的Eu4(L76)4四面体笼的自组装及用于检测的手性胺和氨基醇的分子结构[150]. (f) 基于Eu(±L23)-tmpo(2)的膜材料的照片和在紫外光照射下的图像[151]

Figure 9. (a) Reversible photo-switching reaction of 1(Eu)-o and 1(Eu)-c and CPL spectral changes before and after photoirradiation.[119] Reproduced with permission from Ref. [119]. Copyright 2018, American Chemical Society. (b) Optimized structures of [Eu2(L52)3]6+.[147] Reproduced with permission from Ref. [147]. Copyright 2018, The Royal Society of Chemistry. (c) Molecular structures of EuL (L=L69~L75).[148] Reproduced with permission from Ref. [148]. Copyright 2021, Wiley-VCH. (d) Molecular structures of the emitting and carrier-transporting layers of the CP-OLED device.[149] Reproduced with permission from Ref. [149]. Copyright 2015, Wiley-VCH. (e) Self-assembly of the CPL-emitting Eu4(L76)4 tetrahedral cage and structures of chiral amines and amino alcohol tested.[150] Reproduced with permission from Ref. [150]. Copyright 2022, American Chemical Society. (f) Photographs and images of the films of Eu(±L23)-tmpo(2) prepared on glasses under UV-light.[151] Reproduced with permission from Ref. [151]. Copyright 2020, Nature Publishing Group

参考文献 176

[1]	Tan, Y. B.; Okayasu, Y.; Katao, S.; Nishikawa, Y.; Asanoma, F.; Yamada, M.; Yuasa, J.; Kawai, T. J. Am. Chem. Soc. 2020, 142, 17653.
[2]	Zhang, M.; Guo, Q.; Li, Z.; Zhou, Y.; Zhao, S.; Tong, Z.; Wang, Y.; Li, G.; Jin, S.; Zhu, M.; Zhuang, T.; Yu, S.-H. Sci. Adv. 2023, 9, eadi9944.
[3]	Luo, J.; Lin, T.; Zhang, J.; Chen, X.; Blackert, E. R.; Xu, R.; Yakobson, B. I.; Zhu, H. Science 2023, 382, 698.
[4]	Cui, Y.; Chen, B.; Qian, G. Coord. Chem. Rev. 2014, 273-274, 76.
[5]	Xu, L.-J.; Xu, G.-T.; Chen, Z.-N. Coord. Chem. Rev. 2014, 273-274, 47.
[6]	Liu, Z.; Wang, Y.-X.; Fang, Y.-H.; Qin, S.-X.; Wang, Z.-M.; Jiang, S.-D.; Gao, S. Nat. Sci. Rev. 2020, 7, 1557.
[7]	Su, P.-R.; Wang, T.; Zhou, P.-P.; Yang, X.-X.; Feng, X.-X.; Zhang, M.-N.; Liang, L.-J.; Tang, Y.; Yan, C.-H. Nat. Sci. Rev. 2021, 9, nwab016.
[8]	Hu, S.-J.; Guo, X.-Q.; Zhou, L.-P.; Cai, L.-X.; Sun, Q.-F. Chin. J. Chem. 2019, 37, 657.
[9]	Carr, R.; Evans, N. H.; Parker, D. Chem. Soc. Rev. 2012, 41, 7673.
[10]	Gong, Z.-L.; Zhu, X.; Zhou, Z.; Zhang, S.-W.; Yang, D.; Zhao, B.; Zhang, Y.-P.; Deng, J.; Cheng, Y.; Zheng, Y.-X.; Zang, S.-Q.; Kuang, H.; Duan, P.; Yuan, M.; Chen, C.-F.; Zhao, Y. S.; Zhong, Y.-W.; Tang, B. Z.; Liu, M. Sci. China Chem. 2021, 64, 2060.
[11]	Luo, X.-Y.; Pan, M. Coord. Chem. Rev. 2022, 468, 214640.
[12]	Zhong, Y.; Wu, Z.; Zhang, Y.; Dong, B.; Bai, X. InfoMat 2022, 5, e12392.
[13]	Zhang, Y.; Yu, S.; Han, B.; Zhou, Y.; Zhang, X.; Gao, X.; Tang, Z. Matter 2022, 5, 837.
[14]	Richardson, S., F. Inorg. Chem. 1980, 19, 2806.
[15]	Lunkley, J. L.; Shirotani, D.; Yamanari, K.; Kaizaki, S.; Muller, G. J. Am. Chem. Soc. 2008, 130, 13814. doi: 10.1021/ja805681w pmid: 18816117
[16]	Kumar, J.; Marydasan, B.; Nakashima, T.; Kawai, T.; Yuasa, J. Chem. Commun. 2016, 52, 9885.
[17]	Schnable, D.; Freedman, K.; Ayers, K. M.; Schley, N. D.; Kol, M.; Ung, G. Inorg. Chem. 2020, 59, 8498. doi: 10.1021/acs.inorgchem.0c00946 pmid: 32469213
[18]	Lunkley, J. L.; Shirotani, D.; Yamanari, K.; Kaizaki, S.; Muller, G. Inorg. Chem. 2011, 50, 12724. doi: 10.1021/ic201851r pmid: 22074461
[19]	Mukthar, N. F. M.; Schley, N. D.; Ung, G. J. Am. Chem. Soc. 2022, 144, 6148. doi: 10.1021/jacs.2c01134 pmid: 35377146
[20]	Arrico, L.; Di Bari, L.; Zinna, F. Chem. - Eur. J. 2021, 27, 2920.
[21]	Dee, C.; Zinna, F.; Kitzmann, W. R.; Pescitelli, G.; Heinze, K.; Di Bari, L.; Seitz, M. Chem. Commun. 2019, 55, 13078.
[22]	Piguet, C.; Bünzli, J.-C. G. In Handbook on the Physics and Chemistry of Rare Earths, Vol. 40, Elsevier, Amsterdam, The Netherlands, 2010, p. 301.
[23]	Bunzli, J.-C. G.; Piguet, C. Chem. Soc. Rev. 2005, 34, 1048.
[24]	Zhou, W.-L.; Chen, Y.; Liu, Y. Acta Chim. Sinica 2020, 78, 1164. (in Chinese)
	(周维磊, 陈湧, 刘育, 化学学报, 2020, 78, 1164.) doi: 10.6023/A20100486
[25]	Wang, J.; Li, X.; Chu, H.; He, J.; Chen, Z. Chin. J. Org. Chem. 2019, 39, 3399. (in Chinese)
	(王军, 李小成, 初红涛, 何进军, 陈志娇, 有机化学, 2019, 39, 3399.) doi: 10.6023/cjoc201904016
[26]	Seitz, M.; Do, K.; Ingram, A. J.; Moore, E. G.; Muller, G.; Raymond, K. N. Inorg. Chem. 2009, 48, 8469.
[27]	Zhu, Q.-Y.; Zhou, L.-P.; Cai, L.-X.; Li, X.-Z.; Zhou, J.; Sun, Q.-F. Chem. Commun. 2020, 56, 2861.
[28]	Ning, Y.; Ke, X.-S.; Hu, J.-Y.; Liu, Y.-W.; Ma, F.; Sun, H.-L.; Zhang, J.-L. Inorg. Chem. 2017, 56, 1897.
[29]	Zhang, M.; Zheng, W.; Liu, Y.; Huang, P.; Gong, Z.; Wei, J.; Gao, Y.; Zhou, S.; Li, X.; Chen, X. Angew. Chem., Int. Ed. 2019, 58, 9556.
[30]	Wu, Z.; Ke, J.; Liu, Y.; Sun, P.; Hong, M. Acta Chim. Sinica 2022, 80, 542. (in Chinese)
	(吴志芬, 柯建熙, 刘永升, 孙蓬明, 洪茂椿, 化学学报, 2022, 80, 542.) doi: 10.6023/A21120571
[31]	Li, X.-Z.; Tian, C.-B.; Sun, Q.-F. Chem. Rev. 2022, 122, 6374.
[32]	Yan, B. Acc. Chem. Res. 2017, 50, 2789.
[33]	Qin, Y.; Ge, Y.; Zhang, S.; Sun, H.; Jing, Y.; Li, Y.; Liu, W. RSC Adv. 2018, 8, 12641.
[34]	Yang, D.; Wang, Y.; Liu, D.; Li, Z.; Li, H. J. Mater. Chem. C 2018, 6, 1944.
[35]	Jia, J.-H.; Li, Q.-W.; Chen, Y.-C.; Liu, J.-L.; Tong, M.-L. Coord. Chem. Rev. 2019, 378, 365.
[36]	Jiang, L.; Li, J.; Xia, D.; Gao, M.; Li, W.; Fu, D.-Y.; Zhao, S.; Li, G. ACS Appl. Mater. Inter. 2021, 13, 49462.
[37]	Tang, X.; Chu, D.; Gong, W.; Cui, Y.; Liu, Y. Angew. Chem., Int. Ed. 2021, 60, 9099.
[38]	Huang, W.; Chen, W.; Bai, Q.; Zhang, Z.; Feng, M.; Zheng, Z. Angew. Chem., Int. Ed. 2022, 61, e202205385.
[39]	Zhang, P.; Luo, Q.-C.; Zhu, Z.; He, W.; Song, N.; Lv, J.; Wang, X.; Zhai, Q.-G.; Zheng, Y.-Z.; Tang, J. Angew. Chem., Int. Ed. 2023, 62, e202218540.
[40]	Liu, S.; Liu, W.; Chen, C.; Sun, Y.; Bai, S.; Liu, W. Inorg. Chem. 2024, 63, 1725.
[41]	Wang, Y.; Yan, J. Acta Chim. Sinica 2023, 81, 275. (in Chinese)
	(汪阳, 阎敬灵, 化学学报, 2023, 81, 275.) doi: 10.6023/A23010004
[42]	Guan, Y.; Chang, K.; Sun, Q.; Xu, X. Chin. J. Org. Chem. 2022, 42, 1326. (in Chinese)
	(管怡雯, 常克俭, 孙千林, 徐信, 有机化学, 2022, 42, 1326.) doi: 10.6023/cjoc202112008
[43]	Woods, M.; Kovacs, Z.; Zhang, S.; Sherry, A. D. Angew. Chem. Int. Ed. 2003, 42, 5889.
[44]	Dickins, R. S.; Howard, J. A. K.; Lehmann, C. W.; Moloney, J.; Parker, D.; Peacock, R. D. Angew. Chem., Int. Ed. 1997, 36, 521.
[45]	Dickins, R. S.; Howard, J. A. K.; Maupin, C. L.; Moloney, J. M.; Parker, D.; Riehl, J. P.; Siligardi, G.; Williams, J. A. G. Chem. Eur. J. 1999, 5, 1095.
[46]	Dickins, R. S.; Howard, J. A. K.; Moloney, J. M.; Parker, D.; Peacock, R. D.; Siligardi, G. Chem. Commun. 1997, 1747.
[47]	Poole, R. A.; Bobba, G.; Cann, M. J.; Frias, J.-C.; Parker, D.; Peacock, R. D. Org. Biomol. Chem. 2005, 3, 1013.
[48]	Montgomery, C. P.; Parker, D.; Lamarque, L. Chem. Commun. 2007, 3841.
[49]	Dai, L.; Jones, C. M.; Chan, W. T. K.; Pham, T. A.; Ling, X.; Gale, E. M.; Rotile, N. J.; Tai, W. C.-S.; Anderson, C. J.; Caravan, P.; Law, G.-L. Nat. Commun. 2018, 9, 857.
[50]	Dai, L.; Lo, W.-S.; Coates, I. D.; Pal, R.; Law, G.-L. Inorg. Chem. 2016, 55, 9065.
[51]	Dai, L.; Zhang, J.; Chen, Y.; Mackenzie, L. E.; Pal, R.; Law, G.-L. Inorg. Chem. 2019, 58, 12506.
[52]	Petoud, S.; Cohen, S. M.; Bünzli, J.-C. G.; Raymond, K. N. J. Am. Chem. Soc. 2003, 125, 13324.
[53]	Petoud, S.; Muller, G.; Moore, E. G.; Xu, J.; Sokolnicki, J.; Riehl, J. P.; Le, U. N.; Cohen, S. M.; Raymond, K. N. J. Am. Chem. Soc. 2007, 129, 77.
[54]	Seitz, M.; Moore, E. G.; Ingram, A. J.; Muller, G.; Raymond, K. N. J. Am. Chem. Soc. 2007, 129, 15468.
[55]	Tsubomura, T.; Yasaku, K.; Sato, T.; Morita, M. Inorg. Chem. 1992, 31, 447.
[56]	Gregolinski, J.; Starynowicz, P.; Hua, K. T.; Lunkley, J. L.; Muller, G.; Lisowski, J. J. Am. Chem. Soc. 2008, 130, 17761.
[57]	Qi, H.; Huo, P.; Han, B.; Zheng, J.; Wang, L.; Yan, W.; Guo, R.; Li, T.; Yu, K.; Liu, Z.; Bian, Z. Cell Rep. Phys. Sci. 2022, 3, 101107.
[58]	Leonzio, M.; Melchior, A.; Faura, G.; Tolazzi, M.; Zinna, F.; Di Bari, L.; Piccinelli, F. Inorg. Chem. 2017, 56, 4413. doi: 10.1021/acs.inorgchem.7b00430 pmid: 28388073
[59]	Brittain, H. G.; Richardson, F. S. J. Am. Chem. Soc. 1976, 98, 5858.
[60]	Di Pietro, S.; Di Bari, L. Inorg. Chem. 2012, 51, 12007.
[61]	Zinna, F.; Resta, C.; Abbate, S.; Castiglioni, E.; Longhi, G.; Mineo, P.; Di Bari, L. Chem. Commun. 2015, 51, 11903.
[62]	Muller, G.; Schmidt, B.; Jiricek, J.; Hopfgartner, G.; Riehl, J. P.; Bünzli, J.-C. G.; Piguet, C. J. Chem. Soc., Dalton Trans. 2001, 2655.
[63]	Bonsall, S. D.; Houcheime, M.; Straus, D. A.; Muller, G. Chem. Commun. 2007, 3676.
[64]	Lincheneau, C.; Destribats, C.; Barry, D. E.; Kitchen, J. A.; Peacock, R. D.; Gunnlaugsson, T. Dalton Trans. 2011, 40, 12056.
[65]	Arrico, L.; Benetti, C.; Di Bari, L. ChemPhotoChem 2021, 5, 815.
[66]	Matsumoto, K.; Suzuki, K.; Tsukuda, T.; Tsubomura, T. Inorg. Chem. 2010, 49, 4717. doi: 10.1021/ic901743q pmid: 20438091
[67]	Muller, G.; Bünzli, J.-C. G.; Riehl, J. P.; Suhr, D.; Zelewsky, A.; Mürner, H. Chem. Commun. 2002, 1522.
[68]	Cotter, D.; Dodder, S.; Klimkowski, V. J.; Hopkins, T. A. Chirality 2019, 31, 301.
[69]	Walton, J. W.; Bari, L. D.; Parker, D.; Pescitelli, G.; Puschmann, H.; Yufit, D. S. Chem. Commun. 2011, 47, 12289.
[70]	Frawley, A. T.; Pal, R.; Parker, D. Chem. Commun. 2016, 52, 13349.
[71]	Homberg, A.; Navazio, F.; Le Tellier, A.; Zinna, F.; Fürstenberg, A.; Besnard, C.; Di Bari, L.; Lacour, J. Dalton Trans. 2022, 51, 16479.
[72]	Deng, M.; Schley, N. D.; Ung, G. Chem. Commun. 2020, 56, 14813.
[73]	Willis, B.-A. N.; Schnable, D.; Schley, N. D.; Ung, G. J. Am. Chem. Soc. 2022, 144, 22421.
[74]	Leonard, J. P.; Jensen, P.; McCabe, T.; O'Brien, J. E.; Peacock, R. D.; Kruger, P. E.; Gunnlaugsson, T. J. Am. Chem. Soc. 2007, 129, 10986. pmid: 17696537
[75]	Starck, M.; MacKenzie, L. E.; Batsanov, A. S.; Parker, D.; Pal, R. Chem. Commun. 2019, 55, 14115.
[76]	Muller, G.; Bünzli, J.-C. G.; Schenk, K. J.; Piguet, C.; Hopfgartner, G. Inorg. Chem. 2001, 40, 2642. pmid: 11375674
[77]	Liu, B.; Chen, P. Acta Chim. Sinica 2022, 80, 929. (in Chinese)
	(刘斌, 陈磅宽, 化学学报, 2022, 80, 929.) doi: 10.6023/A22030122
[78]	Stomeo, F.; Lincheneau, C.; Leonard, J. P.; O’Brien, J. E.; Peacock, R. D.; McCoy, C. P.; Gunnlaugsson, T. J. Am. Chem. Soc. 2009, 131, 9636.
[79]	Zhou, Y.; Yao, Y.; Cheng, Z.; Gao, T.; Li, H.; Yan, P. Inorg. Chem. 2020, 59, 12850.
[80]	Bozoklu, G.; Gateau, C.; Imbert, D.; Pécaut, J.; Robeyns, K.; Filinchuk, Y.; Memon, F.; Muller, G.; Mazzanti, M. J. Am. Chem. Soc. 2012, 134, 8372. doi: 10.1021/ja3020814 pmid: 22548280
[81]	Harada, T.; Hasegawa, Y.; Nakano, Y.; Fujiki, M.; Naito, M.; Wada, T.; Inoue, Y.; Kawai, T. J. Alloy. Compd. 2009, 488, 599.
[82]	Harada, T.; Nakano, Y.; Fujiki, M.; Naito, M.; Kawai, T.; Hasegawa, Y. Inorg. Chem. 2009, 48, 11242.
[83]	Kono, Y.; Hara, N.; Shizuma, M.; Fujiki, M.; Imai, Y. Dalton Trans. 2017, 46, 5170.
[84]	Taniguchi, A.; Hara, N.; Shizuma, M.; Tajima, N.; Fujiki, M.; Imai, Y. Photoch. Photobio. Sci. 2019, 18, 2859.
[85]	Harada, T.; Tsumatori, H.; Nishiyama, K.; Yuasa, J.; Hasegawa, Y.; Kawai, T. Inorg. Chem. 2012, 51, 6476.
[86]	Okayasu, Y.; Yuasa, J. Molecul. Syst. Des. Eng. 2018, 3, 66.
[87]	Górecki, M.; Carpita, L.; Arrico, L.; Zinna, F.; Di Bari, L. Dalton Trans. 2018, 47, 7166. doi: 10.1039/c8dt00865e pmid: 29774898
[88]	Zinna, F.; Arrico, L.; Di Bari, L. Chem. Commun. 2019, 55, 6607.
[89]	Abhervé, A.; Mastropasqua Talamo, M.; Vanthuyne, N.; Zinna, F.; Di Bari, L.; Grasser, M.; Le Guennic, B.; Avarvari, N. Eur. J. Inorg. Chem. 2022, 2022, e202200010.
[90]	Dhbaibi, K.; Grasser, M.; Douib, H.; Dorcet, V.; Cador, O.; Vanthuyne, N.; Riobé, F.; Maury, O.; Guy, S.; Bensalah-Ledoux, A.; Baguenard, B.; Rikken, G. L. J. A.; Train, C.; Le Guennic, B.; Atzori, M.; Pointillart, F.; Crassous, J. Angew. Chem., Int. Ed. 2023, 62, e202215558.
[91]	Cavalli, E.; Nardon, C.; Willis, O. G.; Zinna, F.; Di Bari, L.; Mizzoni, S.; Ruggieri, S.; Gaglio, S. C.; Perduca, M.; Zaccone, C.; Romeo, A.; Piccinelli, F. Chem. - Eur. J. 2022, 28, e202200574.
[92]	Ruggieri, S.; Mizzoni, S.; Nardon, C.; Cavalli, E.; Sissa, C.; Anselmi, M.; Cozzi, P. G.; Gualandi, A.; Sanadar, M.; Melchior, A.; Zinna, F.; Willis, O. G.; Di Bari, L.; Piccinelli, F. Inorg. Chem. 2023, 62, 8812. doi: 10.1021/acs.inorgchem.3c00196 pmid: 37262334
[93]	Leonzio, M.; Bettinelli, M.; Arrico, L.; Monari, M.; Di Bari, L.; Piccinelli, F. Inorg. Chem. 2018, 57, 10257. doi: 10.1021/acs.inorgchem.8b01480 pmid: 30080030
[94]	Yin, S.; Li, X.; Wang, H.; Li, J.; Huang, W.; Gao, T.; Yan, P.; Zhou, Y.; Li, H. CrystEngComm 2023, 25, 1541.
[95]	Brittain, H.; Richardson, F. J. Am. Chem. Soc. 1977, 99, 65.
[96]	Yao, M.-X.; Cai, L.-Z.; Deng, X.-W.; Zhang, W.; Liu, S.-J.; Cai, X.-M. New J. Chem. 2018, 42, 17652.
[97]	Zheng, X.-Y.; Xie, J.; Kong, X.-J.; Long, L.-S.; Zheng, L.-S. Coord. Chem. Rev. 2019, 378, 222.
[98]	Sun, Q.-F.; Li, X.-Z. Chin. J. Lumin. 2020, 41, 770. (in Chinese)
	(孙庆福, 李小贞, 发光学报, 2020, 41, 770.)
[99]	Song, L.; Zhou, Y.; Gao, T.; Yan, P.; Li, H. Acta Chim. Sinica 2021, 79, 1042. (in Chinese)
	(宋龙飞, 周妍妍, 高婷, 闫鹏飞, 李洪峰, 化学学报, 2021, 79, 1042.) doi: 10.6023/A21040185
[100]	Yan, L.-L.; Tan, C.-H.; Zhang, G.-L.; Zhou, L.-P.; Bünzli, J.-C.; Sun, Q.-F. J. Am. Chem. Soc. 2015, 137, 8550.
[101]	Li, X.-Z.; Zhou, L.-P.; Yan, L.-L.; Yuan, D.-Q.; Lin, C.-S.; Sun, Q.-F. J. Am. Chem. Soc. 2017, 139, 8237.
[102]	Cantuel, M.; Bernardinelli, G.; Muller, G.; Riehl, J. P.; Piguet, C. Inorg. Chem. 2004, 43, 1840.
[103]	Zhou, Y.; Li, H.; Zhu, T.; Gao, T.; Yan, P. J. Am. Chem. Soc. 2019, 141, 19634.
[104]	Hu, S.-J.; Guo, X.-Q.; Zhou, L.-P.; Yan, D.-N.; Cheng, P.-M.; Cai, L.-X.; Li, X.-Z.; Sun, Q.-F. J. Am. Chem. Soc. 2022, 144, 4244.
[105]	Lincheneau, C.; Peacock, R. D.; Gunnlaugsson, T. Chem. - Asian J. 2010, 5, 500.
[106]	Kotova, O.; Comby, S.; Pandurangan, K.; Stomeo, F.; O'Brien, J. E.; Feeney, M.; Peacock, R. D.; McCoy, C. P.; Gunnlaugsson, T. Dalton Trans. 2018, 47, 12308. doi: 10.1039/c8dt02753f pmid: 30113616
[107]	Wang, Z.; Zhou, L.-P.; Zhao, T.-H.; Cai, L.-X.; Guo, X.-Q.; Duan, P.-F.; Sun, Q.-F. Inorg. Chem. 2018, 57, 7982.
[108]	Yeung, C.-T.; Yim, K.-H.; Wong, H.-Y.; Pal, R.; Lo, W.-S.; Yan, S.-C.; Yee-Man Wong, M.; Yufit, D.; Smiles, D. E.; McCormick, L. J.; Teat, S. J.; Shuh, D. K.; Wong, W.-T.; Law, G.-L. Nat. Commun. 2017, 8, 1128.
[109]	Han, G.; Zhou, Y.; Yao, Y.; Cheng, Z.; Gao, T.; Li, H.; Yan, P. Dalton Trans. 2020, 49, 3312.
[110]	Tsurui, M.; Kitagawa, Y.; Shoji, S.; Fushimi, K.; Hasegawa, Y. Dalton Trans. 2023, 52, 796.
[111]	Wang, C.-F.; Shi, C.; Zheng, A.; Wu, Y.; Ye, L.; Wang, N.; Ye, H.-Y.; Ju, M.-G.; Duan, P.; Wang, J.; Zhang, Y. Mater. Horiz. 2022, 9, 2450.
[112]	Niu, X.; Zeng, Z.; Wang, Z.; Lu, H.; Sun, B.; Zhang, H.-L.; Chen, Y.; Du, Y.; Long, G. Sci. China Chem. 2024, DOI: 10.1007/s11426-024-1946-7.
[113]	Mamula, O.; Lama, M.; Telfer, S. G.; Nakamura, A.; Kuroda, R.; Stoeckli-Evans, H.; Scopelitti, R. Angew. Chem., Int. Ed. 2005, 44, 2527.
[114]	Bing, T. Y.; Kawai, T.; Yuasa, J. J. Am. Chem. Soc. 2018, 140, 3683. doi: 10.1021/jacs.7b12663 pmid: 29433303
[115]	Bi, S.; Zhou, Y.; Yao, Y.; Cheng, Z.; Gao, T.; Yan, P.; Li, H. Aust. J. Chem 2021, 74, 145.
[116]	Yao, Z.; Zhou, Y.; Gao, T.; Yan, P.; Li, H. RSC Adv. 2021, 11, 10524.
[117]	Liu, D.; Zhou, Y.; Zhang, Y.; Li, H.; Chen, P.; Sun, W.; Gao, T.; Yan, P. Inorg. Chem. 2018, 57, 8332.
[118]	Wang, Y.; Zhou, Y.; Yao, Z.; Huang, W.; Gao, T.; Yan, P.; Li, H. Dalton Trans. 2022, 51, 10973.
[119]	Hashimoto, Y.; Nakashima, T.; Yamada, M.; Yuasa, J.; Rapenne, G.; Kawai, T. J. Phys. Chem. Lett. 2018, 9, 2151. doi: 10.1021/acs.jpclett.8b00690 pmid: 29641885
[120]	Hasegawa, Y.; Miura, Y.; Kitagawa, Y.; Wada, S.; Nakanishi, T.; Fushimi, K.; Seki, T.; Ito, H.; Iwasa, T.; Taketsugu, T.; Gon, M.; Tanaka, K.; Chujo, Y.; Hattori, S.; Karasawa, M.; Ishii, K. Chem. Commun. 2018, 54, 10695.
[121]	Islam, M. J.; Kitagawa, Y.; Tsurui, M.; Hasegawa, Y. Dalton Trans. 2021, 50, 5433.
[122]	Kitchen, J. A.; Barry, D. E.; Mercs, L.; Albrecht, M.; Peacock, R. D.; Gunnlaugsson, T. Angew. Chem., Int. Ed. 2012, 51, 704.
[123]	Barry, D. E.; Kitchen, J. A.; Mercs, L.; Peacock, R. D.; Albrecht, M.; Gunnlaugsson, T. Dalton Trans. 2019, 48, 11317. doi: 10.1039/c9dt02003a pmid: 31271402
[124]	Liu, X. K.; Xu, W.; Bai, S.; Jin, Y.; Wang, J.; Friend, R. H.; Gao, F. Nat. Mater. 2021, 20, 10.
[125]	Zhu, C.; Jin, J.; Wang, Z.; Xu, Z.; Folgueras, M. C.; Jiang, Y.; Uzundal, C. B.; Le, H. K. D.; Wang, F.; Zheng, X.; Yang, P. Science 2024, 383, 86.
[126]	Gao, Y.; Pan, Y.; Zhou, F.; Niu, G.; Yan, C. J. Mater. Chem. A 2021, 9, 11931.
[127]	Willis, O. G.; Petri, F.; Pescitelli, G.; Pucci, A.; Cavalli, E.; Mandoli, A.; Zinna, F.; Di Bari, L. Angew. Chem., Int. Ed. 2022, 61, e202208326.
[128]	Willis, O. G.; Petri, F.; De Rosa, D. F.; Mandoli, A.; Pal, R.; Zinna, F.; Di Bari, L. J. Am. Chem. Soc. 2023, 145, 25170.
[129]	Yuasa, J.; Ohno, T.; Miyata, K.; Tsumatori, H.; Hasegawa, Y.; Kawai, T. J. Am. Chem. Soc. 2011, 133, 9892.
[130]	Hu, S.-J.; Guo, X.-Q.; Zhou, L.-P.; Cai, L.-X.; Tian, C.-B.; Sun, Q.-F. Chin. J. Chem. 2023, 41, 797.
[131]	Goto, T.; Okazaki, Y.; Ueki, M.; Kuwahara, Y.; Takafuji, M.; Oda, R.; Ihara, H. Angew. Chem., Int. Ed. 2017, 56, 2989.
[132]	Han, J.; You, J.; Li, X.; Duan, P.; Liu, M. Adv. Mater. 2017, 29, 1606503.
[133]	Huo, S.; Duan, P.; Jiao, T.; Peng, Q.; Liu, M. Angew. Chem., Int. Ed. 2017, 56, 12174.
[134]	Zhang, C.; Li, Z.-S.; Dong, X.-Y.; Niu, Y.-Y.; Zang, S.-Q. Adv. Mater. 2022, 34, 2109496.
[135]	Sugimoto, M.; Liu, X.-L.; Tsunega, S.; Nakajima, E.; Abe, S.; Nakashima, T.; Kawai, T.; Jin, R.-H. Chem. - Eur. J. 2018, 24, 6519.
[136]	Maupin, C. L.; Parker, D.; Williams, J. A. G.; Riehl, J. P. J. Am. Chem. Soc. 1998, 120, 10563.
[137]	Maupin, C. L.; Dickins, R. S.; Govenlock, L. G.; Mathieu, C. E.; Parker, D.; Williams, J. A. G.; Riehl, J. P. J. Phys. Chem. A 2000, 104, 6709.
[138]	Willis, O. G.; Zinna, F.; Pescitelli, G.; Micheletti, C.; Di Bari, L. Dalton Trans. 2022, 51, 518.
[139]	Adewuyi, J. A.; Ung, G. J. Am. Chem. Soc. 2024, 146, 7097.
[140]	Riehl, J. P.; Richardson, F. S. Chem. Rev. 1986, 86, 1.
[141]	Adewuyi, J. A.; Schley, N. D.; Ung, G. Chem. Eur. J. 2023, 29, e202300800.
[142]	Denk, W.; Strickler, J. H.; Webb, W. W. Science 1990, 248, 73. doi: 10.1126/science.2321027 pmid: 2321027
[143]	Picot, A.; D'Aléo, A.; Baldeck, P. L.; Grichine, A.; Duperray, A.; Andraud, C.; Maury, O. J. Am. Chem. Soc. 2008, 130, 1532.
[144]	Mizzoni, S.; Ruggieri, S.; Sickinger, A.; Riobé, F.; Guy, L.; Roux, M.; Micouin, G.; Banyasz, A.; Maury, O.; Baguenard, B.; Bensalah-Ledoux, A.; Guy, S.; Grichine, A.; Nguyen, X.-N.; Cimarelli, A.; Sanadar, M.; Melchior, A.; Piccinelli, F. J. Mater. Chem. C 2023, 11, 4188.
[145]	Aspinall, H. C. Chem. Rev. 2002, 102, 1807. pmid: 12059255
[146]	Brittain, H. G.; Desreux, J. F. Inorg. Chem. 1984, 23, 4459.
[147]	Cai, L.-X.; Yan, L.-L.; Li, S.-C.; Zhou, L.-P.; Sun, Q.-F. Dalton Trans. 2018, 47, 14204. doi: 10.1039/c8dt01808a pmid: 29957816
[148]	Zhang, J.; Dai, L.; Webster, A. M.; Chan, W. T. K.; Mackenzie, L. E.; Pal, R.; Cobb, S. L.; Law, G.-L. Angew. Chem., Int. Ed. 2021, 60, 1004.
[149]	Zinna, F.; Giovanella, U.; Di Bari, L. Adv. Mater. 2015, 27, 1791. doi: 10.1002/adma.201404891
[150]	Li, W.; Zhou, Y.; Gao, T.; Li, J.; Yin, S.; Huang, W.; Li, Y.; Ma, Q.; Yao, Z.; Yan, P.; Li, H. ACS Appl. Mater. Inter. 2022, 14, 55979.
[151]	Kitagawa, Y.; Wada, S.; Islam, M. D. J.; Saita, K.; Gon, M.; Fushimi, K.; Tanaka, K.; Maeda, S.; Hasegawa, Y. Commun. Chem. 2020, 3, 119. doi: 10.1038/s42004-020-00366-1 pmid: 36703364
[152]	Yeung, C.-T.; Chan, W. T. K.; Yan, S.-C.; Yu, K.-L.; Yim, K.-H.; Wong, W.-T.; Law, G.-L. Chem. Commun. 2015, 51, 592.
[153]	Vonci, M.; Mason, K.; Suturina, E. A.; Frawley, A. T.; Worswick, S. G.; Kuprov, I.; Parker, D.; McInnes, E. J. L.; Chilton, N. F. J. Am. Chem. Soc. 2017, 139, 14166.
[154]	Fradgley, J. D.; Frawley, A. T.; Pal, R.; Parker, D. Phys. Chem. Chem. Phys. 2021, 23, 11479. doi: 10.1039/d1cp01686e pmid: 33959741
[155]	Wada, S.; Kitagawa, Y.; Nakanishi, T.; Gon, M.; Tanaka, K.; Fushimi, K.; Chujo, Y.; Hasegawa, Y. Sci. Rep. 2018, 8, 16395.
[156]	Arrico, L.; De Rosa, C.; Di Bari, L.; Melchior, A.; Piccinelli, F. Inorg. Chem. 2020, 59, 5050.
[157]	Okayasu, Y.; Wakabayashi, K.; Yuasa, J. Inorg. Chem. 2022, 61, 15108.
[158]	Liu, M.; Zhang, L.; Wang, T. Chem. Rev. 2015, 115, 7304.
[159]	Wang, Y.; Gong, J.; Wang, X.; Li, W.-J.; Wang, X.-Q.; He, X.; Wang, W.; Yang, H.-B. Angew. Chem., Int. Ed. 2022, 61, e202210542.
[160]	Liu, L.; Yang, Y.; Wei, Z. Acta Chim. Sinica 2022, 80, 970. (in Chinese)
	(刘丽萱, 杨扬, 魏志祥, 化学学报, 2022, 80, 970.) doi: 10.6023/A22030123
[161]	Zinna, F.; Pasini, M.; Galeotti, F.; Botta, C.; Di Bari, L.; Giovanella, U. Adv. Funct. Mater. 2017, 27, 1603719.
[162]	Zinna, F.; Arrico, L.; Funaioli, T.; Di Bari, L.; Pasini, M.; Botta, C.; Giovanella, U. J. Mater. Chem. C 2022, 10, 463.
[163]	Zinna, F.; Pasini, M.; Cabras, M.; Scavia, G.; Botta, C.; Di Bari, L.; Giovanella, U. Chirality 2023, 35, 270.
[164]	Shuvaev, S.; Suturina, E. A.; Mason, K.; Parker, D. Chem. Sci. 2018, 9, 2996. doi: 10.1039/c8sc00482j pmid: 29732083
[165]	Montgomery, C. P.; New, E. J.; Parker, D.; Peacock, R. D. Chem. Commun. 2008, 4261.
[166]	Moore, E. G.; Samuel, A. P.; Raymond, K. N. Acc. Chem. Res. 2009, 42, 542.
[167]	Brichtová, E.; Hudecová, J.; Vršková, N.; Šebestík, J.; Bouř, P.; Wu, T. Chem. Eur. J. 2018, 24, 8664.
[168]	Brittain, H. G. Inorg. Chem. 1981, 20, 3007.
[169]	Muller, G.; Riehl, J. P. J. Fluoresc. 2005, 15, 553.
[170]	Iwamura, M.; Kimura, Y.; Miyamoto, R.; Nozaki, K. Inorg. Chem. 2012, 51, 4094.
[171]	Okutani, K.; Nozaki, K.; Iwamura, M. Inorg. Chem. 2014, 53, 5527.
[172]	Iwamura, M.; Fujii, M.; Yamada, A.; Koike, H.; Nozaki, K. Chem. - Asian J. 2019, 14, 561.
[173]	Uchida, T.; Nozaki, K.; Iwamura, M. Chem. - Asian J. 2016, 11, 2415.
[174]	Carr, R.; Di Bari, L.; Lo Piano, S.; Parker, D.; Peacock, R. D.; Sanderson, J. M. Dalton Trans. 2012, 41, 13154.
[175]	Neil, E. R.; Fox, M. A.; Pal, R.; Parker, D. Dalton Trans. 2016, 45, 8355.
[176]	Wu, T.; Průša, J.; Kessler, J.; Dračínský, M.; Valenta, J.; Bouř, P. Anal. Chem. 2016, 88, 8878.

稀土圆偏振发光材料研究进展

Research Progress of Rare Earth-Based Circularly Polarized Luminescent Materials

RichHTML

PDF

可视化

摘要/Abstract

引用此文

分享此文

图/表 10

参考文献 176

相关文章 15

编辑推荐

相关统计

本文评价

[1]	郑灏宁, 刘金宇. 有机催化吲哚碳环官能团化研究进展[J]. 化学学报, 2024, 82(6): 641-657.
[2]	刘雪朋, 李博桐, 韩明远, 张先付, 陈建林, 戴松元. 自组装单分子空穴传输层在反式钙钛矿太阳电池的研究进展[J]. 化学学报, 2024, 82(3): 348-366.
[3]	王敏, 陈帮塘, 陈桥林, 王俊, 陈名钊, 蒋志龙, 王平山. 6,6″-二(2,6-二甲氧基苯)-三联吡啶及其衍生物金属配位自组装的研究进展[J]. 化学学报, 2024, 82(3): 336-347.
[4]	高炜洋, 邓伟超, 高扬, 梁仁校, 贾义霞. 吲哚分子间不对称去芳构化氧化Heck反应[J]. 化学学报, 2024, 82(1): 1-4.
[5]	胡立伟, 刘宪虎, 刘春太, 宋延林, 李明珠. 光子晶体结构色材料的自组装制备与应用^★[J]. 化学学报, 2023, 81(7): 809-819.
[6]	陈慧敏, 王龙, 张盼, 白西林, 周国君. 高效率Tb^3＋单掺绿色荧光粉的光致/应力发光研究[J]. 化学学报, 2023, 81(7): 771-776.
[7]	李兰英, 陶晴, 闻艳丽, 王乐乐, 郭瑞妍, 刘刚, 左小磊. 多聚腺嘌呤DNA探针及其生物传感应用^★[J]. 化学学报, 2023, 81(6): 681-690.
[8]	蔡新红, 陈建中, 张万斌. 镍催化不对称氢化构建手性C—X键的研究进展^★[J]. 化学学报, 2023, 81(6): 646-656.
[9]	王银凤, 李猛, 陈传峰. 基于手性三蝶烯的红光热激活延迟荧光聚合物及其有机发光二极管研究^★[J]. 化学学报, 2023, 81(6): 588-594.
[10]	汪阳, 阎敬灵. 不同配体的稀土金属配合物在烯烃聚合领域的研究进展[J]. 化学学报, 2023, 81(3): 275-288.
[11]	苏东芮, 任小康, 于沄淏, 赵鲁阳, 王天宇, 闫学海. 酪氨酸衍生物调控酶催化路径可控合成功能黑色素^★[J]. 化学学报, 2023, 81(11): 1486-1492.
[12]	钟越文, 钱希宁, 马超, 刘凯, 张洪杰. 稀土生物制造及其高附加值材料应用^★[J]. 化学学报, 2023, 81(11): 1624-1632.
[13]	韩叶强, 史炳锋. 钯(II)催化不对称C(sp³)—H键官能团化研究进展^★[J]. 化学学报, 2023, 81(11): 1522-1540.
[14]	高杨, 张学鑫, 余金生, 周剑. α-手性三级叠氮化合物的不对称催化合成新进展^★[J]. 化学学报, 2023, 81(11): 1590-1608.
[15]	溥旭, 李泽娟, 石隽秋, 朱云卿, 杜建忠. 器官靶向的聚合物核酸载体研究进展^★[J]. 化学学报, 2023, 81(10): 1438-1446.