手性超分子组装圆偏振室温磷光材料的研究进展

doi:10.6023/A25010004

化学学报 ›› 2025, Vol. 83 ›› Issue (6): 639-654.DOI: 10.6023/A25010004 上一篇

综述

手性超分子组装圆偏振室温磷光材料的研究进展

潘禹州, 殷炜杰, 张雨霞^*()

南京邮电大学信息材料与纳米技术研究院/材料科学与工程学院南京 210000

投稿日期:2025-01-02 发布日期:2025-03-24

作者简介:

潘禹州, 南京邮电大学有机电子与信息显示国家重点实验室及先进材料研究所材料科学与工程学院材料物理专业大三本科生, 国家励志奖学金获得者. 包括中国国际大学生创新大赛全国金奖在内的国家级省级奖项6项, 本科期间申请发表专利4件, 发表SCI论文一篇. 研究方向主要集中在手性聚合物光电材料的设计与合成, 以及圆偏振电致发光的应用研究.

殷炜杰, 南京邮电大学有机电子与信息显示国家重点实验室及先进材料研究所材料科学与工程学院材料物理专业大三本科生, 曾获鼓楼绿色低碳奖学金, 主持1项国家级大创项目, 获得包括中国国际大学生创新大赛全国金奖在内的国家级省级奖项5项, 本科期间申请发表专利1件, 研究方向主要集中在小分子光电功能材料设计及圆偏振有机发光二极管应用研究.

张雨霞, 2022年在南京大学成义祥教授的指导下获得博士学位. 目前任职南京邮电大学有机电子与信息显示国家重点实验室及先进材料研究所的讲师、校聘副教授, 硕士生导师. 研究方向主要集中在手性聚合物光电材料的设计与合成及其圆偏振电致发光器件.

基金资助:
国家自然科学基金(62305172); 江苏省高校自然科学基金(23KJB430026); 南京邮电大学人才引进自然科学研究启动基金(NY223052)

Research Progress of Circularly Polarized Room-temperature Phosphorescent Materials based on Chiral Supramolecular Assembly

Yuzhou Pan, Weijie Yin, Yuxia Zhang^*()

Institute of Advanced Materials/School of Materials Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210000

Received:2025-01-02 Published:2025-03-24
Contact: *E-mail: iamyxzhang@njupt.edu.cn
Supported by:
National Natural Science Foundation of China(62305172); Natural Science Fund for Colleges and Universities in Jiangsu Province(23KJB430026); Natural Science Research Start-up Foundation of Recruiting Talents of Nanjing University of Posts and Telecommunications(NY223052)

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摘要/Abstract

圆偏振室温磷光(CP-RTP)材料因其优异的光学灵敏度和空间分辨率, 在三维显示、防伪和信息存储等领域展现出广泛的应用潜力. 然而, 提升CP-RTP材料的发光不对称因子(g_lum)依然面临挑战. 近年来, 研究者们发现手性超分子组装策略能够提供高阶有序的排列方式, 从而有利于实现更高的g_lum值. 分析了手性超分子组装体系中螺旋结构对材料光物理性质的影响, 总结了近年来手性超分子室温磷光材料的研究进展及其在信息加密和安全防伪等领域的应用.

关键词: 手性超分子组装, 圆偏振发光, 室温磷光, 圆偏振发光不对称因子, 分子间相互作用, 液晶

Circularly polarized room-temperature phosphorescence (CP-RTP) materials have garnered significant attention due to their exceptional optical sensitivity and spatial resolution, making them highly promising for a wide array of applications, such as three-dimensional displays, anti-counterfeiting, and information storage. Generally, the polarization magnitude is quantified by the luminescence dissymmetry factor (g_lum), which has a value between －2 and 2. However, while chiral organic RTP materials often demonstrate higher luminous efficiency, they typically display remarkably low g_lum values, generally in the order of 10^-5 to 10^-3, owing to their inherently weak magnetic transition dipole moment. This limitation significantly hinders the practical application of high-performance CP-RTP materials. Therefore, enhancing the g_lum values of CP-RTP materials remains a substantial challenge. With the rapid advancement of chiral supramolecular assembly, researchers have discovered that this system can construct long-range ordered helical nanostructures by precisely regulating intermolecular interactions, such as π-π stacking and hydrogen bonding. This approach facilitates the attainment of a high g_lum value while maintaining favorable luminous efficiency. Meanwhile, the processes of chiral self-assembly or co-assembly frequently involve chiral transfer, chiral induction, and intermolecular Förster resonance energy transfer. These processes are advantageous for inducing achiral dyes to achieve CP-RTP. This dramatically simplifies the synthesis of CP-RTP materials, circumventing the often-complex and costly preparation of intrinsically chiral RTP chromophores. Consequently, chiral supramolecular assembly systems have emerged as a highly effective strategy for the development of CP-RTP materials exhibiting substantially improved g_lum values. This review comprehensively examines the influence of helical structures on the photophysical properties of chiral supramolecular assembly systems, summarizing recent progress in the design, synthesis, and application of chiral supramolecular RTP materials, with a particular focus on their exploitation in advanced information encryption and anti-counterfeiting technologies. We delve into the underlying mechanisms driving enhanced circular polarization and discuss future directions for this rapidly evolving field.

Key words: chiral supramolecular assembly, circularly polarized luminescence, room temperature phosphorescence, circular polarization luminescence dissymmetry factor, intermolecular interactions, liquid crystal

引用此文

潘禹州, 殷炜杰, 张雨霞. 手性超分子组装圆偏振室温磷光材料的研究进展[J]. 化学学报, 2025, 83(6): 639-654.

Yuzhou Pan, Weijie Yin, Yuxia Zhang. Research Progress of Circularly Polarized Room-temperature Phosphorescent Materials based on Chiral Supramolecular Assembly[J]. Acta Chimica Sinica, 2025, 83(6): 639-654.

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图/表 17

图1. 近年来实现CP-RTP发射的示意图及各种类CP-RTP材料的glum值

Figure 1. Schematic diagrams of achieving CP-RTP emission and the glum values of recent various CP-RTP materials

图2. (A) LGluP (DGluP)的化学结构; (B)从纳米纤维到纳米束的自组装机制; (C)螺旋纳米纤维激发能图; (D)纳米束激发能图[40].

Figure 2. (A) Chemical structure of LGluP (DGluP); (B) self-assembly mechanisms from nanoﬁber to nanobundle; excitation energy diagram of helical nanoﬁber (C) and nanobundle (D)[40] Reproduced with permission. Copyright 2024, Wiley-VCH.

图3. 具有颜色可调和紫外线可检测应用的RTP和CP-RTP材料设计方案[18]

图4. (a) Pg和芳烃之间的主客体络合机制促使的多色发光和手性发光活性; (b)客体的化学结构[43]

Figure 4. (a) Host-guest complexation between Pg and aromatics allows for versatile emission behaviors and chiroptical activities; (b) chemical structures of guests[43] Reproduced with permission. Copyright 2022, American Chemical Society.

图5. (a) HTB-DG/LG的结构和刺激响应性手性单组分溶胶-凝胶体系示意图; HTB-DG/LG凝胶的(b) CD光谱和(c) glum值图(λex=365 nm); (d)在环境光(顶部)和紫外光(底部)的凝胶态和溶胶态的HTB-DG图像[51]

Figure 5. (a) Structures of HTB-DG/LG and a schematic of the stimuli-responsive chiral single-component sol-gel system; (b) CD spectra and (c) corresponding glum curves (λex=365 nm) for HTB-DG/LG organogels; (d) photographs of HTB-DG in gel and sol states under ambient light (top) and UV light (bottom)[51] Reproduced with permission. Copyright 2021, Royal Society of Chemistry.

图6. (a) L-Lys-C14/18和L-Lys-Amide-C18自组装形成纳米管、纳米片和纤维的分子结构; (b) L-Lys-C18的激发波长依赖CP-RTP和多色圆偏振余辉示意图[54]

Figure 6. (a) Molecular structure of L-Lys-C18, L-Lys-C14 and L-Lys-Amide-C18, which self-assembled to form nanotube, nanosheet and fiber, respectively; (b) Schematic diagram of excitation wavelength-dependent CP-RTP and multicolor CP afterglow of L-Lys-C18 [54] Reproduced with permission. Copyright 2024, American Chemical Society.

图7. 手性单体与CB[8]组装络合形成超分子聚合物(SPs)的示意图[57]

图8. 通过苯偶酰的手性超分子聚合实现圆偏振磷光的示意图及聚合单体和发光单体(S)-1~(S)-5和6的化学结构[58]

Figure 8. Schematic illustration for circularly polarized phosphorescence via chiral supramolecular polymerization of benzils and the chemical structures of (S)-1~(S)-5 and 6[58] Reproduced with permission. Copyright 2024, Wiley-VCH.

图9. (a)三齿配体, 其中臂侧在配位相互作用的驱动下沿一个方向发生旋转, 以及具有两种螺旋链的简化网络[60]; (b) D/L-cam、四吡啶乙烯和客体分子结构式; (c)将客体发射体封装到手性孔中以形成三明治结构和客体和主体之间的传输模型[61]

Figure 9. (a) Tridentate ligand like a fan, where the arm side occurs the rotation in one direction driven by coordination interaction and simplified network with two kinds of helix chains[60], Reproduced with permission. Copyright 2020, Wiley-VCH; (b) the molecular structures of D/L-cam, 1,1,2,2-tetra(pyridin-4-yl)ethene and guest emitters; (c) guest emitters were encapsulated into chiral pores to form the sandwich structure and proposed transfer model between guest and host[61], Reproduced with permission. Copyright 2023, Wiley-VCH

图10. (a)由PtN和PtBox组成的超螺旋共组装获得圆偏振磷光的策略[62]; (b)结合自下而上和自上而下的方法提高磷光Pt(II)配合物的CPL性能[63]

Figure 10. (a) Strategy to obtaining circularly polarized phosphorescence from superhelical co-assemblies consisting of PtN and PtBox[62], Reproduced with permission. Copyright 2019, Royal Society of Chemistry; (b) Combined bottom-up and top-down approach toward improving the CPL performance of phosphorescent Pt(II) complexes[63], Reproduced with permission. Copyright 2022, Wiley-VCH.

图11. 利用MJLCP的“将军-士兵”效应和手性螺旋柱状相来实现长寿命CP-RTP示意图[79]

Figure 11. The “sergeant-soldier” effect in the chiral helical columnar phase of MJLCPs and the activation of circularly polarized fluorescence and phosphorescence[79] Reproduced with permission. Copyright 2024, American Chemical Society.

图12. 制备具有高glum值和可调CP-RTP的CLC共聚物的简单策略[81]

图13. (a)液晶单体、共聚物和手性诱导剂的化学结构式; (b)共组装原理图; (c)信息的有效加密和传输应用[83]

Figure 13. (a) The chemical structures of monomers, co-polymers and chiral inducer; (b) schematic diagram of co-assembly; (c) The application of effective encryption and transmission of information[83] Reproduced with permission. Copyright 2024, Elsevier.

图14. (a) XT-3-Br, BBXT-3-Br, BOHXT-3-Br, RM257和Irg651化学结构式; (b)基于BOHXT-3-Br@PRM257薄膜的写入、读取和擦除的智能信息存储应用[86]

Figure 14. (a) The chemical structures of XT-3-Br, BBXT-3-Br, BOHXT-3-Br, RM257 and Irg651; (b) the intelligent information storage device based on BOHXT-3-Br@PRM257 ﬁlm, including writing, removing and erasing of information[86] Reproduced with permission. Copyright 2024, Wiley-VCH.

图15. (a) RTP polymer, RM257, R811和IRG 651的化学结构式[87]; (b)在“UV开启、UV关闭后无偏振片、UV关闭后左旋圆偏片, UV关闭后右旋圆偏片”条件下的数字图案照片[87]; (c)光响应材料M1的化学结构式[88]; (d) 405 nm 紫外光照射下P1-SHS-M1薄膜通过不同掩模的动态、可逆光控制[88]

Figure 15. (a) The molecular structures of RTP polymer, RM257, R811 and IRG 651[87]; (b) photographs of number patterns under the conditions of UV on, UV off without filter, UV off with L-CPF, and UV off with R-CPF[87], Reproduced with permission. Copyright 2023, Wiley-VCH; (c) chemical structures of the photo-responsive material M1[88]; (d) dynamic and reversible light control of P1-SHS-M1 film upon the irradiation of 405 nm UV by passing through different masks[88], Reproduced with permission. Copyright 2024, Wiley-VCH.

图16. (a)基于CLCES的可调CP-RTP原理图; (b) CLCE的合成路线; (c)结合CP-RTP和CLCE动态可重构特性的4D信息加密[91]

Figure 16. (a) Schematic diagram of tunable CP-RTP based on CLCEs; (b) synthesis route of CLCE; (c) 4D information encryption combining CP-RTP with dynamic reconfigurable features of CLCEs[91] Reproduced with permission. Copyright 2022, Elsevier.

图17. (a) 多环芳烃掺杂PMMA的CNCs复合膜的制备工艺; (b)基于CNC膜的结构色、RTP和CP-RTP原理图; (c)基于CNC薄膜的3×3像素阵列生成的5通道(结构色、磷光、3 s延迟发射、在L-CPF和R-CPF下的CP-RTP)信息加密[97]

Figure 17. (a) Fabrication process of hybrid film based on CNCs infiltrated with polycyclic aromatic hydrocarbon doped PMMA; (b) Schematic illustration of CNC based hybrid film pad with structural color, RTP and CP-RTP; (c) information encryption with 5 channels (structural color, phosphorescence, delayed emission with 3 s, CP-RTP with L-CPF and R-CPF) information created by 3×3 pixels’ array based on hybrid CNCs film[97] Reproduced with permission. Copyright 2024, Elsevier.

参考文献 97

[1]	Zhan, X.; Xu, F. F.; Zhou, Z.; Yan, Y.; Yao, J.; Zhao, Y. S. Adv. Mater. 2021, 33, e2104418.
[2]	Wu, P.; Li, P.; Chen, M.; Rao, J.; Chen, G.; Bian, J.; Lü, B.; Peng, F. Adv. Mater. 2024, 36, 2402666.
[3]	Rajamani, S.; Simeone, D.; Pecora, A.; Manoccio, M.; Balestra, G.; Bayramov, A. H.; Mamedov, N. T.; Passaseo, A.; Gigli, G.; Tobaldi, D. M.; Tasco, V.; Esposito, M.; Cola, A.; Cuscunà, M. Adv. Mater. Technol. 2024, 9, 2301250.
[4]	Zhao, Y.; Dong, M.; Feng, J.; Zhao, J.; Guo, Y.; Fu, Y.; Gao, H.; Yang, J.; Jiang, L.; Wu, Y. Adv. Opt. Mater. 2022, 10, 2102227.
[5]	Jiang, S.; Kotov, N. A. Adv. Mater. 2023, 35, 2108431.
[6]	Shi, L.; Ding, L.; Zhang, Y.; Lu, S. Nano Today 2024, 55, 102200.
[7]	Li, J.; Wang, Y.; Zhang, Y.; Zheng, D.; Wang, X. Part. Part. Syst. Charact. 2022, 39, 2100254.
[8]	Yang, L.; Zhang, Q.; Ma, Y.; Li, H.; Sun, S.; Xu, Y. Chem. Eng. J. 2024, 490, 151679.
[9]	Wang, D.; Gong, J.; Xiong, Y.; Wu, H.; Zhao, Z.; Wang, D.; Tang, B. Z. Adv. Funct. Mater. 2023, 33, 2208895.
[10]	Shi, J.; Tao, W.; Zhou, Y.; Liang, G. Chem. Eng. J. 2023, 475, 146178.
[11]	Li, Z.; Yue, Q.; Zhang, H.; Zhao, Y. Mater. Today 2024, 78, 209.
[12]	Zhou, L.; Li, K.; Chang, Y.; Yao, Y.; Peng, Y.; Li, M.; He, R. Chem. Sci. 2024, 15, 10046. doi: 10.1039/d4sc01630k pmid: 38966385
[13]	Chao, C.; Kang, L.; Dai, W.; Zhao, C.; Shi, J.; Tong, B.; Cai, Z.; Dong, Y. J. Mater. Chem. B 2023, 11, 3106.
[14]	Xu, Z.; Jiang, Y.; Shen, Y.; Tang, L.; Hu, Z.; Lin, G.; Law, W. C.; Ma, M.; Dong, B.; Yong, K. T.; Xu, G.; Tao, Y.; Chen, R.; Yang, C. Mater. Horiz. 2022, 9, 1283.
[15]	Zhao, Y.; Yang, J.; Liang, C.; Wang, Z.; Zhang, Y.; Li, G.; Qu, J.; Wang, X.; Zhang, Y.; Sun, P.; Shi, J.; Tong, B.; Xie, H. Y.; Cai, Z.; Dong, Y. Angew. Chem., Int. Ed. 2024, 63, e202317431.
[16]	Chen, J.; Zhang, S.; Liu, G.; Zhang, Y.; Xue, S.; Sun, Q.; Yang, W. Adv. Opt. Mater. 2023, 11, 2301163.
[17]	Liu, H.; Ren, D. D.; Gao, P. F.; Zhang, K.; Wu, Y. P.; Fu, H. R.; Ma, L. F. Chem. Sci. 2022, 13, 13922.
[18]	An, S.; Gao, L.; Hao, A.; Xing, P. ACS Nano 2021, 15, 20192.
[19]	Zheng, H.; Zhang, Z.; Cai, S.; An, Z.; Huang, W. Adv. Mater. 2024, 36, e2311922.
[20]	Liu, F.; Li, Z.; Li, Y.; Feng, Y.; Feng, W. Carbon 2021, 181, 9.
[21]	Wang, X.; Yang, K.; Zhao, B.; Deng, J. Small 2024, 20, 2404576.
[22]	Fu, H. R.; Zhang, R. Y.; Ren, D. D.; Zhang, K.; Yuan, J.; Lu, X. Y.; Ding, Q. R. Cryst Growth Des. 2024, 24, 4819.
[23]	Huang, Z.; He, Z.; Ding, B.; Tian, H.; Ma, X. Nat. Commun. 2022, 13, 7841.
[24]	Zhang, Y.; Zhang, S.; Liu, G.; Sun, Q.; Xue, S.; Yang, W. Chem. Sci. 2023, 14, 5177.
[25]	Jia, S.; Tao, T.; Xie, Y.; Yu, L.; Kang, X.; Zhang, Y.; Tang, W.; Gong, J. Small 2023, 20, 2307874.
[26]	Liu, Q.; Liu, X.; Yu, X.; Zhang, X.; Zhu, M.; Cheng, Y. Angew. Chem., Int. Ed. 2024, 63, e202403391.
[27]	McCourt, J. M.; Kewalramani, S.; Gao, C.; Roth, E. W.; Weigand, S. J.; Olvera de la Cruz, M.; Bedzyk, M. J. ACS Cent. Sci. 2022, 8, 1169.
[28]	Jedrych, A.; Pawlak, M.; Gorecka, E.; Lewandowski, W.; Wojcik, M. M. ACS Nano 2023, 17, 5548.
[29]	Wang, X.; Zhao, B.; Deng, J. Adv. Mater. 2023, 35, 2304405.
[30]	Jiang, Y.; Zhang, C.; Wang, R.; Lei, Y.; Dai, W.; Liu, M.; Wu, H.; Tao, Y.; Huang, X. Adv. Opt. Mater. 2024, 12, 2302482.
[31]	Chen, R.; Feng, R.; Huang, Z.; Feng, D.; Long, Y.; Zhang, J.; Yang, Y.; Ma, Z.; Yuan, Z.; Lu, S.; Zhao, Z.; Chen, X. Adv. Funct. Mater. 2024, 34, 2404602.
[32]	Scalabre, A.; Gutiérrez-Vílchez, A. M.; Sastre-Santos, Á.; Fernández-Lázaro, F.; Bassani, D. M.; Oda, R. J. Phys. Chem. C 2020, 124, 23839.
[33]	Li, H.; Li, H.; Wang, W.; Tao, Y.; Wang, S.; Yang, Q.; Jiang, Y.; Zheng, C.; Huang, W.; Chen, R. Angew. Chem., Int. Ed. 2020, 59, 4756.
[34]	McCready, M. S.; Puddephatt, R. J. ACS Omega 2018, 3, 13621. doi: 10.1021/acsomega.8b01860 pmid: 31458067
[35]	Xu, H.; Lu, H.; Zhang, Q.; Chen, M.; Shan, Y.; Xu, T. Y.; Tong, F.; Qu, D. H. J. Mater Chem C 2022, 10, 2763.
[36]	Huang, X.; Hao, A.; Xing, P. Chem. Mater. 2024, 36, 10361.
[37]	Jiang, H.; Zhang, L.; Chen, J.; Liu, M. ACS Nano 2017, 11, 12453.
[38]	Huang, R.; Yu, K.; Chen, S.; Chen, K.; Luo, Y.; Lu, Z.; Dias, F. B.; Zheng, X. Adv. Opt. Mater. 2024, 12, 2400210.
[39]	Zhang, L.; Zhao, W. L.; Li, M.; Lyu, H. Y.; Chen, C. F. Acta Chim. Sinica 2020, 78, 1030 (in Chinese). doi: 10.6023/A20060243
	(张亮, 赵文龙, 李猛, 吕海燕, 陈传峰, 化学学报 2020, 78, 1030.) doi: 10.6023/A20060243
[40]	Heo, J. M.; Kim, J.; Hasan, M. I.; Woo, H.; Lahann, J.; Kim, J. Adv. Opt. Mater. 2024, 12, 2400572.
[41]	Guo, C.; Zhang, Q.; Zhu, B.; Zhang, Z.; Ma, X.; Dai, W.; Gong, X.; Ren, G.; Mei, X. Cryst. Growth Des. 2020, 20, 3053.
[42]	Friščić, T.; Lancaster, R. W.; Fábián, L.; Karamertzanis, P. G. PNAS 2010, 107, 13216.
[43]	Wang, L.; Hao, A.; Xing, P. ACS Appl. Mater. 2022, 14, 44902.
[44]	Duraisamy, D. K.; Reddy, S. M. M.; Saveri, P.; Deshpande, A. P.; Shanmugam, G. Macromol. Rapid Commun. 2024, 45, 2400018.
[45]	Guo, Y.; Han, Y.; Du, X. S.; Chen, C. F. ACS Appl. Polym. Mater. 2022, 4, 3473.
[46]	Cao, R.; Yang, X.; Wang, Y.; Xiao, Y. Nano Res. 2022, 16, 1459.
[47]	Du, S.; Zhu, X.; Zhang, L.; Liu, M. ACS Appl. Mater. 2021, 13, 15501.
[48]	Song, S.; Shi, Y.; Zhu, L.; Yue, B. Sci. China: Chem. 2024, 67, 1865.
[49]	Zhao, C. L.; Qin, M. G.; Dou, X. Q.; Feng, C. L. Chin. J. Appl. Chem. 2022, 39, 177 (in Chinese).
	(赵常利, 秦明高, 窦晓秋, 冯传良, 应用化学, 2022, 39, 177.) doi: 10.19894/j.issn.1000-0518.210487
[50]	Wu, S.; Tao, W.; Wang, T.; Xu, J.; Wei, P. Chem. Commun. 2024, 60, 8232.
[51]	Wu, B.; Wu, H.; Gong, Y.; Li, A.; Jia, X.; Zhu, L. J. Mater. Chem. C 2021, 9, 4275.
[52]	Andrieux, V.; Gibaud, T.; Bauland, J.; Divoux, T.; Manneville, S.; Guy, S.; Bensalah-Ledoux, A.; Guy, L.; Chevallier, F.; Frath, D.; Bucher, C. J. Mater. Chem. C 2023, 11, 12764.
[53]	Smith, D. K. Soft Matter 2024, 20, 10.
[54]	Hao, W.; Wang, Y.; Liu, M. ACS Mater. Lett. 2024, 6, 3487.
[55]	Hartlieb, M.; Mansfield, E. D. H.; Perrier, S. Polym. Chem. 2020, 11, 1083.
[56]	Li, C.; Xiong, Q.; Clemons, T. D.; Sai, H.; Yang, Y.; Hussain Sangji, M.; Iscen, A.; Palmer, L. C.; Schatz, G. C.; Stupp, S. I. Chem. Sci. 2023, 14, 6095.
[57]	Xu, C.; Yin, C.; Wu, W.; Ma, X. Sci. China: Chem. 2022, 65, 75.
[58]	Guang, L.; Lu, Y.; Zhang, Y.; Liao, R.; Wang, F. Angew. Chem., Int. Ed. 2024, 63, e202315362.
[59]	Li, M.; Zhang, T.; Shi, Y.; Duan, C. Chem Rec. 2023, 23, e202300158.
[60]	Fu, H. R.; Wang, N.; Wu, X. X.; Li, F. F.; Zhao, Y.; Ma, L. F.; Du, M. Adv. Opt. Mater. 2020, 8, 2000330.
[61]	Gao, P.; Zhang, K.; Ren, D.; Liu, H.; Zhang, H.; Fu, H.; Ma, L.; Li, D. Adv. Funct. Mater. 2023, 33, 2300105.
[62]	Park, G.; Kim, H.; Yang, H.; Park, K. R.; Song, I.; Oh, J. H.; Kim, C.; You, Y. Chem. Sci. 2019, 10, 1294.
[63]	Park, G.; Jeong, D. Y.; Yu, S. Y.; Park, J. J.; Kim, J. H.; Yang, H.; You, Y. Angew. Chem., Int. Ed. 2023, 62, e202309762.
[64]	Zhang, L. L. Chin. J. Liq. Cryst. Disp. 2016, 31, 1023 (in Chinese).
	(张伶莉, 液晶与显示, 2016, 31, 1023 )
[65]	Kang, W. X.; Ren, T. Q.; Meng, X. Y.; Li, S.; Guo, J. B. Sci. Sin.: Chim. 2024, 54, 1321 (in Chinese).
	(康文欣, 任天淇, 孟宪宇, 李山, 郭金宝, 中国科学: 化学, 2024, 54, 1321.)
[66]	Wang, Y. C.; Wang, X.; Zhang, J.; Zhang, Y. X.; Ma, Y.; Zhao, Q. Sci. Sin.: Chim. 2024, 54, 1329 (in Chinese).
	(王煜昌, 王潇, 张京, 张雨霞, 马云, 赵强, 中国科学: 化学, 2024, 54, 1329.)
[67]	Li, M.; Li, X.; An, X.; Chen, Z.; Xiao, H. Front. Chem. 2019, 7, 00447.
[68]	Li, C.; Shi, X.; Zhang, X. Polymers 2022, 14, 4050.
[69]	Xie, Y.; Wang, Z.; Zhang, M.; Wu, X.; Sun, Y.; Wu, J.; Sun, C. L.; Zhang, B.; Pan, X. Inorg. Chem. Commun. 2024, 168, 112895.
[70]	Dou, X.; Zhou, Q.; Chen, X.; Tan, Y.; He, X.; Lu, P.; Sui, K.; Tang, B. Z.; Zhang, Y.; Yuan, W. Z. Biomacromolecules 2018, 19, 2014.
[71]	Liao, P.; Zang, S.; Wu, T.; Jin, H.; Wang, W.; Huang, J.; Tang, B. Z.; Yan, Y. Nat. Commun. 2021, 12, 5496.
[72]	Zhou, M.; Gong, Y.; Yuan, Y.; Zhang, H. J. Phys. Chem. C 2022, 126, 15485.
[73]	Zhou, M.; Zhang, J.; Chen, Y.; Chen, Z.; Yuan, Y.; Gong, Y.; Zhang, H. Macromol. Rapid Commun. 2023, 44, 2300449.
[74]	Gong, W.; Zhou, M.; Xiao, L.; Fan, C.; Yuan, Y.; Gong, Y.; Zhang, H. Adv. Opt. Mater. 2024, 12, 2301922.
[75]	Chen, X. F.; Shen, Z.; Wan, X. H.; Fan, X. H.; Chen, E. Q.; Ma, Y.; Zhou, Q. F. Chem. Soc. Rev. 2010, 39, 3072.
[76]	Gao, L.; Shen, Z.; Fan, X.; Zhou, Q. Polym. Chem. 2012, 3, 1947.
[77]	Liu, Z.; Fan, C.; Yuan, Y.; Zhang, H. Eur. Polym. J. 2024, 202, 112611.
[78]	Zhang, Y. F.; Wang, Y. C.; Yu, X. S.; Zhao, Y.; Ren, X. K.; Zhao, J. F.; Wang, J.; Jiang, X. Q.; Chang, W. Y.; Zheng, J. F.; Yu, Z. Q.; Yang, S.; Chen, E. Q. Macromolecules 2019, 52, 2495. doi: 10.1021/acs.macromol.9b00171
[79]	Liu, Z.; Deng, F.; Huang, S.; Fan, C.; Yuan, Y.; Zhang, H. ACS Appl. Polym. 2024, 6, 9582.
[80]	Zhang, Y.; Li, H.; Geng, Z.; Zheng, W. H.; Quan, Y.; Cheng, Y. ACS Nano 2022, 16, 3173.
[81]	Huang, S.; Wu, Q.; Luo, R.; Tan, B.; Yuan, Y.; Zhang, H. Macromolecules 2024, 57, 9017.
[82]	Li, D.; Jiang, Z.; Zheng, S.; Fu, C.; Wang, P.; Cheng, Y. J. Colloid Interface Sci. 2025, 678, 1213.
[83]	Liu, C.; Li, H.; Chen, Y.; Xu, D.; Cheng, Y. Chem. Eng. J. 2024, 486, 150442.
[84]	Nemati, H.; Liu, S.; Moheghi, A.; Tondiglia, V. P.; Lee, K. M.; Bunning, T. J.; Yang, D.-K. J. Mol. Liq. 2018, 267, 120.
[85]	Huang, A.; Huang, J.; Luo, H. Y.; Luo, Z. W.; Wang, P.; Wang, P.; Guan, Y.; Xie, H. L. J. Mater. Chem. C 2023, 11, 4104.
[86]	Xu, D.; Liu, C.; Li, H.; Cheng, Y.; Zheng, W. H. Adv. Opt. Mater. 2024, 12, 2303019.
[87]	Liu, J.; Song, Z. P.; Wei, J.; Wu, J. J.; Wang, M. Z.; Li, J. G.; Ma, Y.; Li, B. X.; Lu, Y. Q.; Zhao, Q. Adv. Mater. 2023, 36, 2306834.
[88]	Liu, J.; Wu, J. J.; Wei, J.; Huang, Z. J.; Zhou, X. Y.; Bao, J. Y.; Lan, R. C.; Ma, Y.; Li, B. X.; Yang, H.; Lu, Y. Q.; Zhao, Q. Angew. Chem., Int. Ed. 2024, 63, e202319536.
[89]	Schlafmann, K. R.; Alahmed, M. S.; Pearl, H. M.; White, T. J. ACS Appl. Mater. 2024, 16, 23780.
[90]	Kwon, C.; Nam, S.; Han, S. H.; Choi, S. S. Adv. Funct. Mater. 2023, 33, 2304506.
[91]	Fan, Q.; Li, Z.; Jiang, K.; Gao, J.; Lin, S.; Guo, J. Cell Rep. Phys. Sci. 2023, 4, 101583.
[92]	Ganguly, K.; Patel, D. K.; Dutta, S. D.; Shin, W. C.; Lim, K. T. Int. J. Biol. Macromol. 2020, 155, 456. doi: S0141-8130(20)32750-1 pmid: 32222290
[93]	Parker, R. M.; Frka-Petesic, B.; Guidetti, G.; Kamita, G.; Consani, G.; Abell, C.; Vignolini, S. ACS Nano 2016, 10, 8443.
[94]	Revol, J. F.; Bradford, H.; Giasson, J.; Marchessault, R. H.; Gray, D. G. Int. J. Biol. Macromol. 1992, 14, 170. pmid: 1390450
[95]	Xu, M.; Wu, X.; Yang, Y.; Ma, C.; Li, W.; Yu, H.; Chen, Z.; Li, J.; Zhang, K.; Liu, S. ACS Nano 2020, 14, 11130.
[96]	Zheng, H.; Ju, B.; Wang, X.; Wang, W.; Li, M.; Tang, Z.; Zhang, S. X. A.; Xu, Y. Adv. Opt. Mater. 2018, 6, 1801246.
[97]	Wang, X.; Miao, Q.; Zhang, W.; Zhou, Y.; Xiong, R.; Duan, Y.; Meng, X.; Ye, C. Chem. Eng. J. 2024, 481, 148463.

手性超分子组装圆偏振室温磷光材料的研究进展

Research Progress of Circularly Polarized Room-temperature Phosphorescent Materials based on Chiral Supramolecular Assembly

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