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化学学报
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化学学报 ›› 1989, Vol. 47 ›› Issue (9): 842-845. 上一篇    下一篇

研究论文

双齿杂环胺酞花菁铁(II)盐配合物的吸收谱分析及电导

赵尚勃;郑芊;谢军楷   

  1. 四川师范大学化学系
  • 发布日期:1989-09-15

The absorption spectrum analysis and electric conductivities of phthalocyaninato-Fe(II) polymerized via a bidentate bridging heterocyclic amine

ZHAO SHANGBO;ZHENG QIAN;XIE JUNKAI   

  • Published:1989-09-15

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假设双齿杂环胺酞花菁铁(II)盐配合物(FePcL)n具有D4h对称性, 通过对其吸收谱分析, 得到了晶场参量Dq和配合物结构间的关系, 从而关联观测电导值和配合物结构,在谱分析中利用了减少可调参量数目的技巧, 以增加理论分析的可靠性。

关键词: 胺, 铁络合物, 亚铁化合物, 光谱分析, 矩阵, 不可约表示, 杂环化合物, 长链化合物, 最小二乘法, 桥环化合物

The crystal field parameter D4h, the elec. conductivity, the magnetic moment and the structure parameter of [FePcL]n complexes, where Pc = phthalocyaninato, and L = pyrazine, 4,4'-bipyridine, trans-1,2-bis(4-pyridyl)ethylene, 1,2-bis(4-pyridyl)ethane and 4,4'-trimethylenebipyridine, are given. The stability and compressibility of these compounds are also given.

Key words: AMINES, IRON COMPLEX, FERROUS COMPOUNDS, SPECTROGRAPHIC ANALYSIS, MATRICES, IRREDUABLE REPRESENTATION, HETEROCYCLIC COMPOUNDS, LONG CHAIN COMPOUND, LEAST SQUARE METHODS, BRIDGE COMPOUNDS

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