化学学报 ›› 1990, Vol. 48 ›› Issue (7): 686-689. 上一篇    下一篇

研究论文

稀土配位催化合成聚乳酸

沈之荃;孙俊全;吴良江;吴兰亭   

  1. 浙江大学化学系
  • 发布日期:1990-07-15

The synthesis of poly (lactic acid) by rare earth coordination catalysts

SHEN ZHIQUAN;SUN JUNQUAN;WU LIANGJIANG;WU LANTING   

  • Published:1990-07-15

本文开发了合成聚乳的一类新型催化剂, 它是由稀土化合物-三烷基铝-水组的配位催化剂。试验表明稀土配位催化剂可以使丙交酯在甲苯溶液中以高转化率聚合, 得到分子量可控的聚乳酸。并研究了稀土元素种类、不同配位基团及聚合条件变化对丙交酯开环聚合的影响。

关键词: 乳酸, 水, 烷基铝, X射线衍射分析, 稀土金属络合物, 聚合催化剂, 开环聚合, 粘均分子量

Catalysts composed of rare earth compounds, (iso-Bu)3Al, and water were developed for the preparation of poly(lactic acid). D,L-Lactide could be polymd. into poly(lactic acid) with high yield and controllable mol. wt. in PhMe solution using the above catalysts.

Key words: LACTIC ACID, WATER, ALUMINIUM ALKYLS, X-RAY DIFFRACTION ANALYSIS, RARE EARTH METAL COMPLEX, POLYMERISATION CATALYST, RING OPEN POLYMERIZATION, VISCOSITY AVERAGE MOLECULAR WEIGHT

中图分类号: