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化学学报
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化学学报 ›› 1990, Vol. 48 ›› Issue (9): 931-935. 上一篇    下一篇

研究论文

杂芳核对(N-N-二烃基胺基)二氯硼烷的三烃基化反应, 二乙胺合三(2-苯并噻唑基)硼烷的合成及其晶体结构

袁国正;王向东;薛孔玲   

  1. 武汉大学化学系
  • 发布日期:1990-09-15

Trisheteroarylation of (N,N-dialkylamino) dichloroborane by heteroaromatic groups, synthesis and crystal structure of Tris(2-benzothiazolyl) borane diethylamine adduct

YUAN GUOZHENG;WANG XIANGDONG;XUE KONGLING   

  • Published:1990-09-15

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536

被引次数

1

本文报道(N,N-二烃基胺基)二氯硼烷的反常三烃化反应, 2-苯并噻唑基Grignard剂与(N,N-二乙胺基)二氯硼烷反应, 得到二乙胺合三(2-苯并噻唑基)硼烷, 并讨论了反应机理。分子结构经X单晶结构分析确证。晶体结构属正交晶系, 空间群为P212121, 晶胞参数a=11.570(3), b=12.496(4), c=16.577(4)nm; Z=4, V=2397.3nm^3,Dc=1.348g/cm^3, μ(MoKa)=3.167cm^-^1。

关键词: 晶体结构测定, 反应机理, 烷基化, 杂环化合物, 硼烷, 硼烷, 格氏试剂, 苯并噻唑, 苯并噻唑, 二乙胺

Reaction of 2-benzothiazolylmagnesium bromide with (diethylamino)dichloroborane took place with trisheteroarylation instead of diheteroarylation at the boron atom, and tris(2-benzothiazolyl)borane was isolated as its diethylamine adduct. The mol. structure of the title adduct was confirmed by x-ray crystallog. anal.

Key words: CRYSTAL STRUCTURE DETERMINATION, REACTION MECHANISM, ALKYLATION, HETEROCYCLIC COMPOUNDS, BORANE, BORANE, GRIGNARD REAGENT, BENZOTHIAZOLE, BENZOTHIAZOLE, DIETHYLAMINE

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