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化学学报
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化学学报 ›› 1995, Vol. 53 ›› Issue (3): 219-222. 上一篇    下一篇

研究论文

三元体系Sm(NO~3)~3-ACAP-H~2O相平衡研究及Sm(ACAP)~2(NO~3)~3的合成和表征

唐宗薰;王志银;郭志箴;赵开续   

  1. 西北大学化学系
  • 发布日期:1995-03-15

A study on the ternary system sm(NO~3)~3-ACAP-H~2O at 30℃ and the prearation and characterizations of the sm(ACAP)~2(NO~3)~3

TANG ZONGXUN;WANG ZHIYIN;GUO ZHIZHEN;ZHAO KAIXU   

  • Published:1995-03-15

PDF

548

被引次数

14

在30℃时采用等温溶度法研究了三元体系Sm(NO~3)~ 3- ACAP- H~ 2OACAP, 4-acetylantipyrine,4-乙铣基安替比林)的相平衡,绘制了体系的溶度图及饱和溶液的折光率一组成图,发现并制备了未见文献报道的同成分溶解的化合物Sm(ACAP)~2(NO~3)~3,通过化学分析,元素分析,摩尔电导(DMF),IR和TG-DTG 对其进行了物理化学性质表征,初步探讨了阴离子对ACAP与稀土相互作用的影响.

关键词: 相平衡, 红外分光光度法, 水, 元素分析, 三元体系, 硝酸盐, 热重量分析, 钐络合物, 硝酸钐, 乙酰基安替比林

The solubilities and the refractive indexes of saturated solns. of the title system at 30?have been studied and the corresponding equilibrium diagram and refractive index diagram were constructed. Both solubility curve and refractive index curve of the system consist of three branches, corresponding to 4-acetylantipyrine (ACAP), Sm(ACAP)2(NO3)3 and Sm(NO3)3?H2O resp. The Sm(ACAP)2(NO3)3 is a new compound It was characterized by chem. and elemental anal., IR spectra, TG-DTG and molar conductivity (in DMF). The influences of the anion on the interaction between the ACAP and the rare earth ion has been discussed briefly.

Key words: PHASE EQUILIBRIUM, INFRARED SPECTROPHOTOMETRY, WATER, ELEMENTAL ANALYSIS, TERNARY SYSTEM, NITRATE, THERMOGRAVIMETRY, SAMARIUM COMPLEX, SAMARIC NITRATE

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