化学学报 ›› 2001, Vol. 59 ›› Issue (5): 780-783. 上一篇    下一篇

研究论文

NaCl介质中盐浓度、pH对α-Al~2O~3表面相互作用力的影响

孙静;高濂   

  1. 中国科学院上海硅酸盐研究所.上海(200050);中国科学院高性能陶瓷与超微结 构国家重点实验室
  • 发布日期:2001-05-15

Effects of pH and salt concentration on the interaction between alumina surfaces in NaCl solutions

Sun Jing;Gao Lian   

  1. Shanghai Inst Ceram., CAS.Shanghai(200050)
  • Published:2001-05-15

利用原子显微镜研究NaCl介质浓度及体pH值对氧化铝表面作用力的影响规律。发现较低的盐浓度下,相互作用表示为长程排斥力,双电层厚度的实际值与理论值较好地吻合,随NaCl介质浓度的提高,双电层压缩长程斥力减弱,测定了pHMH4.0变化到9.67的作用力曲线,发现当pH等于7/90时,两表面的相互作用表现为吸引力,通过恒电荷、恒电位拟合,发现氧化铝的等电点在pH8.2处,与Zeta电位的测定结果相一致。

关键词: 氯化钠, 原子力显微镜, 氧化铝, 相互作用

Interaction between alumina surfaces has been measured using atomic force microscope (AFM). The effects of pH and electrolyte concentration of NaCl on the forec measurement were investigated. At low ionic strenght around 0.0003mol/L, the interaction behaves as long- tanged repulsive force. With the rising of salt concentration, the magnitude of the repulsive force decreases due to compression of the electric double layer. The measured double layer decay lengths were consistent with the theoretical values. The measured force curve of 0.000 3mol.L was forred with DLVO theory with condtant change and constant potential as 8.8mV. The pH value has great influence on the interaction magnitude. A t pH 7.90, the interaction force is attractive. The fitted constant charge data show the isoelectric point of alumina is at 8.2, which is consistent with the results obtained from the eletrophoretic mobility measurement .

Key words: SODIUM CHLORIDE, ALUMINIUM OXIDE, INTERACTIONS

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