化学学报 ›› 2003, Vol. 61 ›› Issue (10): 1664-1666. 上一篇    下一篇

研究论文

含氮竹节状碳纳米管的催化合成

王利军;郭昌文;田汀;吴浩青   

  1. 复旦大学化学系分子催化与创新材料实验室
  • 发布日期:2003-10-15

Catalytic Synthesis of Bamboo-shaped Nitrogen-doped Carbon Nanotubes

Wang Lijun;Guo Changwen;Tian Ting;Wu Haoqing   

  1. Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University
  • Published:2003-10-15

以二乙胺为原料,用催化方法合成出了含氮大管径竹节状碳纳米管,以含铁 SAPO-5分子筛为催化剂,二乙胺经过1073K高温裂解得到的碳纳米管材料,其内径 约60nm,壁厚为6nm,并且成竹节状。它有较高的表面和较高的氮碳比。

关键词: 二乙胺, 铁化合物, 分子筛, 纳米相材料, 催化反应

Bamboo-shaped, nitrogen-doped, large-inner diameter carbon nanotubes were synthesized by catalytic method with diethylamine as carbon source. By using Fe-containing SAPO-5 molecular sieve as catalyst, carbon nanotubes were synthesized under 1073 K high cracking reaction temperture, with inner diameter of about 60 nm, wall depth of about 6 nm, and being bamboo-shaped. It has high BET surface (103 m~2/g) and high N/C atom ratio (N/ C atom ratio is 0.15/0.85).

Key words: DIETHYLAMINE, IRON COMPOUNDS, MOLECULAR SIEVE, NANOPHASE MATERIALS, CATALYTIC REACTION

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