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化学学报
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化学学报 ›› 2004, Vol. 62 ›› Issue (20): 2021-2024. 上一篇    下一篇

研究论文

以介孔氧化硅薄膜为模板电沉积合成新型纳米结构

施奇惠, 杨海峰, 程岩, 闫妍, 陈颖, 屠波, 赵东元   

  1. 复旦大学化学系, 分子催化与先进材料实验室, 上海, 200433
  • 投稿日期:2003-11-13 修回日期:2004-03-19 发布日期:2014-02-17
  • 通讯作者: 赵东元,E-mail:dyzhao@fudan.edu.cn;Fax:021-65641740 E-mail:dyzhao@fudan.edu.cn
  • 基金资助:
    国家自然科学基金(Nos.9925309,20173012,20233030,20373013)、科技部973重大基础研究(No.2001CB610505)、上海市纳米科技发展促进中心(No.0212nm043)及复旦大学研究生创新基金资助项目.

Electrodeposition of Novel Nanostructured Materials Using Mesoporous Silica Thin Films as Templates

SHI Qi-Hui, YANG Hai-Feng, CHENG Yan, YAN Yan, CHEN Ying, TU Bo, ZHAO Dong-Yuan   

  1. Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433
  • Received:2003-11-13 Revised:2004-03-19 Published:2014-02-17

PDF

518

被引次数

21

首次以不同孔道结构的介孔氧化硅薄膜为模板,采用电化学沉积的方法,合成了金属铜和半导体氧化锌的纳米材料,并对其结构进行了表征.以六方孔道结构的介孔氧化硅模板获得了直径为7 nm的金属铜纳米线阵列;以笼状体心立方孔道结构的模板获得了具有哑铃状形貌的铜单质纳米颗粒.对于氧化锌纳米结构,电化学沉积过程使得氧化锌完全填充氧化硅模板的孔道,分别得到了具有六方和体心立方介孔结构的ZnO/SiO2纳米复合物薄膜.

关键词: 电沉积, 纳米结构, 介孔材料, 模板, 薄膜

By using mesoporous silica thin films with different porestructure as templates, employing an electrodeposition method, Cu an ZnO nanostructures were synthesized and characterized respectively. By using hexagonal mesostructured template, metal Cu nanowires with diameter of 7 nm were derived and by using body-centered mesostructured template, Cu nanoparticles with dumbbell-like morphology were obtained. As for the ZnO nanostructures, channels of the silica templates were fully occupied with the semiconductor, and ZnO/SiO2 nanocomposites with different mesostructure were prepared. This approach can be further expended to nanostructures with alternative components, which provided a new method for synthesizing small-sized nanostructures by electrodeposition.

Key words: electrodeposition, nanostructure, mesoporous material, template, film