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化学学报
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化学学报 ›› 2007, Vol. 65 ›› Issue (19): 2139-2143. 上一篇    下一篇

研究论文

溶剂热合成法制备纳米颗粒自组装的线形和球形铜的硫化物

王学营2, 南照东*,1, 郝海燕2, 李亚生2,3   

  1. (1扬州大学化学化工学院 扬州 225002)
    (2曲阜师范大学化学科学学院 曲阜 273165)
    (3济宁职业技术学院 济宁 272037)
  • 投稿日期:2006-06-09 修回日期:2006-10-24 发布日期:2007-10-14
  • 通讯作者: 南照东

Self-assembly of Copper Sulfide Nanoparticles to Structures of Wires and Spheres by a Solvothermal Method

WANG Xue-Ying2; NAN Zhao-Dong*,1; HAO Hai-Yan2; LI Ya-Sheng2,3   

  1. (1 College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002)
    (2 College of Chemical Science, Qufu Normal University, Qufu 273165)
    (3 Jining Vocational Technology College, Jining 272037)
  • Received:2006-06-09 Revised:2006-10-24 Published:2007-10-14
  • Contact: NAN Zhao-Dong

PDF

800

被引次数

14

在130 ℃, 以水和乙二醇混合体系为溶剂, 无水硫酸铜和硫脲反应, 制备了不同物相结构和形貌的铜的硫化物. 通过扫描电镜(SEM)、透射电镜(TEM)、电子衍射(SAED)及X射线衍射(XRD)等技术, 对所得产物进行了表征. 结果表明, 溶剂中水含量的变化对铜的硫化物的物相影响不明显, 但显著影响其形貌; 反应时间对其物相和形貌都产生影响. 并对其形成机理进行了探讨.

关键词: 铜的硫化物, 水, 乙二醇, 形貌, 物相结构

Copper sulfides, such as Cu1.8S and Cu7S4, in the wire-like and ball-like shapes congregated from nano-spherical particles and nanoslices have been prepared by a solvothermal method without using any surfactants. The products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and the selected area electron diffraction techniques. A systematic investigation has been carried out to understand the factors, such as the systematic composition of the mixture solvent and the reaction time, influencing the structure bulky phase and the morphology of the samples. The results showed that the water content in the solvent affected the morphology of the samples, and the reaction time affected both the crystal structure and morphology. Possi-ble crystal growth process was also discussed.

Key words: copper sulfide, water, ethyleneglycol, morphology, phase structure