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化学学报
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化学学报 ›› 2010, Vol. 68 ›› Issue (16): 1585-1588. 上一篇    下一篇

研究论文

FeTSPc对Pt电极对氧还原的电催化性能和耐甲醇性能的影响

吕艳卓*,1，徐岩2，陆天虹3   

  1. (1哈尔滨工程大学材料科学与化学工程学院 哈尔滨 150001)
    (2哈尔滨工程大学工程训练中心 哈尔滨 150001)
    (3南京师范大学化学与环境科学学院 南京 210097)
  • 投稿日期:2010-01-18 修回日期:2010-03-08 发布日期:2010-04-20
  • 通讯作者: 吕艳卓 E-mail:luyanzhuo@yahoo.com.cn
  • 基金资助:

    黑龙江省自然科学基金;哈尔滨工程大学基础研究基金

Effect of FeTSPc on Electrocatalytic Performance for Oxygen Reduction and Methanol Tolerant Ability of Pt Electrode

Lü Yanzhuo*,1 Xu Yan2 Lu Tianhong3   

  1. (1College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001)
    (2Engineering Training Center, Harbin Engineering University, Harbin 150001)
    (3Environmental Friendship Laboratory, College of Chemistry and Environmental Science, Nanjing Normal University, Nanjing 210097)
  • Received:2010-01-18 Revised:2010-03-08 Published:2010-04-20

PDF

1101

被引次数

3

为了解决直接甲醇燃料电池(DMFC)中“甲醇渗透”的问题, 用大环化合物四磺酸基酞菁铁(FeTSPc)对光滑铂(Pt)电极进行修饰, 发现FeTSPc修饰的Pt电极(Pt-FeTSPc)和Pt电极对氧还原的电催化活性相近, 而Pt-FeTSPc电极对甲醇氧化的电催化活性比Pt电极下降30.9%, 表明Pt-FeTSPc电极有较好的耐甲醇能力.

关键词: 直接甲醇燃料电池, 四磺酸基酞菁铁, Pt电极, 氧还原, 耐甲醇

In order to solve the problem of “methanol crossing-over” in direct methanol fuel cell (DMFC), the smooth Pt electrode was modified with iron tetrasulfonate phthalocyanine (FeTSPc). It was found that the electrocatalytic activity of the FeTSPc modified Pt electrode (Pt-FeTSPc) for oxygen reduction is similar to the Pt electrode. However, the electrocatalytic activity of the Pt-FeTSPc electrode for methanol oxidation is lower than that of the Pt electrode about 30.9%, demonstrating that the Pt-FeTSPc electrode has the good methanol-tolerant ability.

Key words: direct methanol fuel cell, iron tetrasulfonate phthalocyanine, Pt electrode, oxygen reduction, methanol-tolerant