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化学学报
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化学学报 ›› 2010, Vol. 68 ›› Issue (22): 2319-2324. 上一篇    下一篇

研究论文

5-(4-烟酸酰亚胺基)苯基-10,15,20-三苯基卟啉及其锌配合物的合成及性质研究

庄长福1,2，孙园园1，王运方1，石建慧1，师宇华1，师同顺*,1   

  1. (1吉林大学化学学院 长春 130023)
    (2西南林业大学木质科学与装饰工程学院 昆明 650224)
  • 投稿日期:2009-10-29 修回日期:2010-04-01 发布日期:2010-07-19
  • 通讯作者: 师同顺 E-mail:tsshi@email.jlu.edu.cn
  • 基金资助:

    国家自然科学基金（批准号：20801022）

Preparation and Properties of 5-(4-Nicotinicaminophenyl)-10,15,20- triphenylporphyrin and Its Zn Complexes

Zhuang Changfu1,2 Sun Yuanyuan1 Wang Yunfang1 Shi Jianhui1 Shi Yuhua1 Shi Tongshun*,1   

  1. (1 College of Chemistry, Jilin University, Changchun 130023)
    (1 Faculty of Wood Science and Decoration Engineering, Southwest Forestry University, Kuming 650224)
  • Received:2009-10-29 Revised:2010-04-01 Published:2010-07-19
  • Contact: SHI Tong-Shun E-mail:tsshi@email.jlu.edu.cn

PDF

1041

被引次数

13

合成了未见文献报道的5-(4-烟酸酰亚胺基)苯基-10,15,20-三苯基卟啉配体(H2P)及其锌配合物(ZnP), 并通过紫外-可见光谱、红外光谱、核磁共振氢谱、元素分析等测试方法对化合物的结构加以确认, 研究了配体和配合物的荧光光谱的变化和电化学性质. 热分析研究表明, 卟啉配体及配合物显示了很高的热稳定性, 超过390 ℃才开始分解.

关键词: 卟啉, 配合物, 合成, 荧光光谱, 电化学

The new 5-(4-nicotinicaminophenyl)-10,15,20-triphenylporphyrin ligand (H2P) and its complexe ZnP have been synthesized and confirmed by means of elemental analyses, UV-Vis spectra, FT-IR spectra and 1H NMR spectra. Fluorescence spectra of the porphyrin ligand and the complexes were investigated. We also studied the electrochemistry of the ligand and the complexes. The results showed that there are much difference between the ligand and the complexes of the UV-Vis spectra, infrared spectra, and fluorescence spectra. The cyclic voltammetry of the ligand and ZnP are investigated. The thermal studies show that the porphyrins have higher thermal stability and could be decomposed until 390 ℃.

Key words: porphyrin, complex, synthesis, fluorescence spectra, electrochemistry