化学学报 ›› 2002, Vol. 60 ›› Issue (10): 1754-1759. 上一篇    下一篇

研究论文

银、镧改性混合型吸热碳氢燃料裂解分子筛催化剂的研究

张波;林瑞森;王彬成;咸春雷   

  1. 浙江大学化学系,杭州(310027)
  • 发布日期:2002-10-15

Study of Cracking Catalysts of Mixed Zeolites Modified by Ag and La to Endothermic Hydrocarbon Fuels

Zhang Bo;Lin Ruisen;Wang Bincheng;Xian Chunlei   

  1. Department of Chemistry, Zhejiang University,Hagzhou(310027)
  • Published:2002-10-15

为提高吸热型碳氢燃料的吸热能效,制备了吸热型碳氢燃料NNJ-150和银、镧 离子交换改性USY,ZSM-5分子筛及混合分子筛,考察了NNJ-150在USHY,HZSM-5和 二者混合物以及银、镧改性混合分子筛催化剂上的裂解情况。结果表明,NNJ-150 在Ag-LaUSY + Ag-LaZSM-5(75:25)混合分子筛上裂解时,低碳烯烃选择性较高 (600 ℃,47.92%),催化剂寿命较长(35 min以上),催化性能比较稳定,可满 足冷却高超音速飞行器的要求。

关键词: HZSM-5, 催化裂解, 离子交换, 催化活性, 银,

In order to improve endothermic ability of endothermic hydrocarbon fuel, the endothermic hydrocarbon fuel NNJ-150 and the catalysts mixed with USY and ZSM-5 which have been modified by La~(3+) and Ag~+ were prepared. NNJ-150 cracked on USHY, HZSM-5, their mixture and mixed zeolite catalysts modified by Ag~+ and La~(3+) was studied. Results show that the selectivity of light olefins is high (600 ℃, 47.92%), the lifetime of catalyst is long (above 35 min, 500 ℃), and the performance of catalyst is stable when NNJ-150 is cracked on Ag-LaUSY + Ag-LaZSM-5 (75:25). It can satisfy the need of cooling high supersonic craft.

Key words: HZSM-5, CATAROLE PROCESS, ION EXCHANGING, CATALYTIC ACTIVITY, Ag, La

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