化学学报 ›› 1993, Vol. 51 ›› Issue (12): 1191-1194. 上一篇    下一篇

研究论文

钐试剂在合成中的应用 Ⅱ.金属钐作用下烯丙基卤代物与酯的反应

高翔;曾瑾;周景尧;吴世晖   

  1. 复旦大学化学系
  • 发布日期:1993-12-15

Samarium in organic synthesis.Ⅱ.reaction of allyl halides with esters in the presence of samarium metal

GAO XIANG;ZENG JIN;ZHOU JINGYAO;WU SHIHUI   

  • Published:1993-12-15

在金属钐的作用下,烯丙基卤代物与酯反应,生成α,α-二烯丙基叔醇,其中,与γ-丁内酯反应,开环生成4-烯丙基-6-庚烯-1,4-二醇

关键词: 酯, 卤代烃, 丁酸 P, 有机合成, 加成反应, 钐, 丙烯 P, γ-内酯

a,a-Diallyl carbinols were obtained in the reaction of samarium metal, allyl halides and esters. If the substrate is g-butyllactone the corresponding 4-allyl-6-heptene-1,4-diol was produced.

Key words: ESTERS, HALOHYDROCARBON, BUTANOIC ACID P, ORGANIC SYNTHESIS, ADDITION REACTION, SAMARIUM, PROPENE P

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