化学学报 ›› 1992, Vol. 50 ›› Issue (10): 973-977. 上一篇    下一篇

研究论文

烷基钴卟啉[(TPP)CoR]的电化学合成和现场伏安/现场光谱电化学研究

刘殿骏;林祥钦   

  1. 中国科学院长春应用化学研究所;中国科学院电分析化学开放研究实验室
  • 发布日期:1992-10-15

studies on electrogeneration in-situ electrochemistry and spectroelectrochemistry of alkyl cobalt porphyrin

LIU DIANJUN;LIN XIANGQIN   

  • Published:1992-10-15

本文报道甲基、乙基、丙基和丁基钴卟啉化合物的电化学合成和现场伏安、现场光谱电化学研究,烷基化反应的速度被确定.这些烷钴卟啉还原反应生成烷基饱和的四苯基chlorin钴化合物.

关键词: 伏安法, 还原反应, 反应速度, 电化学合成, 烷基钴卟啉, 现场光谱电化学, 甲基钴卟啉, 乙基钴卟啉, 丙基钴卟啉, 丁基钴卟啉

Methyl-, ethyl-, propyl- and n-butyl-Co porphyrins were electrochem. synthesized and studied by in-situ cyclic voltammetry and UV visible spectroelectrochem. Rate constants for the alkylations were determine The electrochem. reduction of the alkyl Co porphyrins was also studied.

Key words: VOLTAMMETRY, REDUCTION REACTION, REACTION RATE, ELECTROCHEMICAL SYNTHESIS

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