化学学报 ›› 1992, Vol. 50 ›› Issue (4): 326-329. 上一篇    下一篇

研究论文

混合溶剂中氨基酸热力学性质的研究 IV: 278.15-318.15K下甘氨酸-乙醇-水体系

申丽;吕殿祯;邵长伟;杨家振   

  1. 辽宁大学化学系
  • 发布日期:1992-04-15

Studies on thermodynamics of the dissociation of amino acid in mixed solvents IV: Glycine-Alcohol-Water system at 278.15-318.15K

SHEN LI;LU DIANZHEN;SHAO CHANGWEI;YANG JIAZHEN   

  • Published:1992-04-15

在混合溶剂中恒定乙醇的质量百分数χ=10%, 应用电动势法测定了无液接电池(A)和电池(B)的电动势。根据电池(A)和电池(B)的电动势, 用传统的Debye-Huckel外推法和我们在前文提出的多项式逼近程序, 确定了甘氨酸有278.15-318.15k范围内5个温度下的第一、第二热力学解离常数, 两种方法所得的结果在实验误差范围内一致。并相应计算了该体系的热力学量。

关键词: 乙醇, 水, 热力学性质, 电动势, 甘氨酸, 混合溶剂, 解离常数

Dissociation constants of glycine were determine by using emf. measurements with a liquid cell at 278.15-318.15 K in solution containing 10% of alcohol Thermodn. parameters were calculated from smoothed experimental data.

Key words: ETHANOL, WATER, THERMODYNAMIC PROPERTIES, ELECTROMOTIVE FORCES, GLYCINE, MIX SOLVENT

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