化学学报 ›› 1988, Vol. 46 ›› Issue (6): 612-614. 上一篇    下一篇

研究论文

活性镁及活性氢化镁的合成

廖世健;张双青;余淑文   

  1. 中国科学院大连化学物理研究所
  • 发布日期:1988-06-15

Synthesis of active magnesium and magnesium hydride

LIAO SHIJIAN;ZHANG SHUANGQING;YU SHUWEN   

  • Published:1988-06-15

研究了在真空下90-150℃间使蒽镁分解生成高活性镁. 再常压加氢, 制得氢化镁的方法. 这一过程中, 镁的活化可循环使用蒽, 基本上不消耗任何试剂, 在分解前用过渡金属化合物掺杂到蒽镁中去可改善活化镁的氢化行为. 当蒽镁中掺杂5%的Cp2TiCl2时, 吸氢温度可降至90℃.

关键词: 镁, 反应动力学, 加氢, 环戊二烯 P, 活化, 掺杂, 氢化物, 钛络合物, 镁化合物, 有机过渡金属络合物

MgH2 was prepared at normal pressure simply by decomposing Mg anthracene thermally under vacuum and then hydrogenating the resulting activated Mg. In this process, Mg is activated while anthracene can be recycled in principle without consuming any reagent. The hydrogenation behavior of the activated Mg can be modified by doping the Mg anthracene with transition metal compounds before decomposition The doped Mg can take up H even at 90?

Key words: MAGNESIUM, REACTION KINETICS, HYDROGENATION, CYCLOPENTADIENE P, ACTIVATION, DOPE, HYDRIDES, TITANIUM COMPLEX, MAGNESIUM COMPOUNDS, ORGANO TRANSITION METAL COMPLEX

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