化学学报 ›› 1987, Vol. 45 ›› Issue (1): 55-58. 上一篇    下一篇

研究论文

阴离子型微乳液的电导行为及其溶液结构

郭荣;李干佐   

  1. 扬州师范学院;山东大学化学系
  • 发布日期:1987-01-15

Electrical conduction behaviour and solution structure of anionic microemulsion

GUO RONG;LI GANZUO   

  • Published:1987-01-15

根据电导测量,研究了属于W/O→双连续→O/W一类微乳液的十二烷基硫酸钠(SDS)/正丁醇/辛烷/水体系的溶液结构.并探讨了表面活性剂离子对微乳液导电行为的贡献,以及表面活性剂与助表面活性剂含量、油含量对微乳液溶液结构的影响.微乳液的导电行为在W/O子区域中主要是由于SDS阴离子和在O/W子区域中是由于Na离子的影响.在双连续区(IZ)中SDS阴离子和Na阳离子都能影响导电行为增加表面活性剂含量有助于形成O/W微乳液,而助表面活性剂和油含量都增加有助于于形成W/O微乳液.

关键词: 水, 丁醇, 高级烷烃 P, 阴离子表面活性剂, 电导率, 辛烷 P, 硫酸钠, 十二碳化合物, 溶液化学, 相图

Conductivity measurements show that there are 3 types of sub-regions (W/O, IZ and O/W) in the SDS/BuOH/n-C8H18/H2O microemulsion. Conduction behavior of the microemulsion is due mainly to the SDS anion in the W/O and Na+ ion in the O/W sub-regions, resp. In the bi-continuous region (IZ), both the SDS anion and Na+ make their contributions to conduction. Increasing surfactant content helps to form O/W microemulsion, but both increasing cosurfactant and initial oil content help to form W/O microemulsion.

Key words: WATER, BUTANOL, HIGHER ALKANE P, ANIONIC SURFACTANTS, ELECTRICAL CONDUCTIVITY, OCTANE P, SODIUM SULFATE, C12 COMPOUNDS, SOLUTION CHEMISTRY, PHASE DIAGRAM

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