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化学学报
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化学学报 ›› 1998, Vol. 56 ›› Issue (6): 550-556. 上一篇    下一篇

研究论文

顺式和反式-2-氨基-3-氰基-4-苯基-1-(4'-甲基苯基)-2-环戊烯-1-醇的合成和晶体结构

史达清;路再生;沐来龙;戴桂元   

  1. 徐州师范大学化学系
  • 发布日期:1998-06-15

Synthesis and crystal structure of cis and trans-2-amino-3-cyano-4-phenyl-1-(4'-methylphenyl)-2cyclopentene-1-ol

SHI DAQING;LU ZAISHENG;MU LAILONG;DAI GUIYUAN   

  • Published:1998-06-15

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被引次数

4

用低价钛试剂(TiCl4-Zn)与4, 4-二氰基-3-苯基-1-(4'-甲基苯基)-1-丁酮反应合成了顺式和反式-2-氨基-3-氰基-4-苯基-1-(4'-甲基苯基)-2-环戊烯-1-醇, 并用X射线衍射分析确定了这两个异构体的构型。

关键词: 锌, 晶体结构, Ｘ射线衍射分析, 苯 P, 氨基, 氰基, 醇, 异构体, 氯化钛, 环戊烯 P

The cis and trans-2-amino-3-cyano-4-phenyl-1-(4'-methylphenyl)-2cyclopentene-1-ols were synthesized by reaction of low-valent titanium reagent (TiCl4-Zn) with 4, 4-dicyano-3-phenyl-1-(4'-methylphenyl)-1-butanone. Their configurations were determined by X-ray analysis.

Key words: ZINC, CRYSTAL STRUCTURE, X-RAY DIFFRACTION ANALYSIS, BENZENE P, AMINO GROUP, CYANO GROUP, ALCOHOL, ISOMER, TITANIUM CHLORIDE, CYCLOPENTENE P

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