化学学报 ›› 2000, Vol. 58 ›› Issue (7): 840-844. 上一篇    下一篇

研究论文

SDS/BA/H~2O体系的结构与电学特性

刘天晴;张启清;范国康;郭荣   

  1. 扬州大学理学院化学系
  • 发布日期:2000-07-15

Structure and electric properties of SDS/BA/H~2O system

Liu Tianqing;Zhang Qiqing;Fan Guokang;Guo Rong   

  • Published:2000-07-15

SDS/BA/H~2O体系电导率、反离子缔合度和电容测定表明:在O/W微乳液区域,电导率、反离子缔合度和电容值都较小;在恒定m(SDS)/m(H~2O)下,随着BA含量的增加,电导率、反离子缔合度和电容值先增加,达到一最大值后又逐渐下降。在双连续区域,为链式导电机理,电导率、反离子缔合度、电阻和电容值几乎不随水含量变化。根据加权最小二乘法回归,O/W球形胶束区域的电容值与各物理化学特性数值(κ,β,N,D,ε,χ)的关系为:C/μF=1.036×10^-^8(1-β)Z~sκD^-^1+0.03466ε~1x~1=0.09677ε~2x~2。

关键词: 十二烷基硫酸钠, 苯甲醇, 水, 缔合物, 电容, 微乳

The results of determination of the conductivity, the association degree of counter-ion and the capacitance indicate that their values are relatively small in the O/W microemulsion for SDS/BA/H~2O system. At the constant weight ratio of SDS to water, the conductivity, the association degree of counter-ion and the capacitance first increase up to the maximum and then begin to decrease with BA content increasing. In the bicontinuous region, there is a chain conductive mechanism. The conductivity, the association degree and the capacitance change scarcely with the water content. The relation of the capacitance with the properties of physical chemistry in O/W spherical microemulsion region by a least-mean square method is C/μ F=1.036×10^-^8(1-β)Z~sκD^-^1 + 0.03466ε~1x~1 = 0.09677ε~2x~2.

Key words: LAURYL SODIUM SULFATE, BENZALCOHOL, WATER, ASSOCIATES, CAPACITANCE, MICROEMUSION

中图分类号: