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化学学报
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化学学报 ›› 2011, Vol. 69 ›› Issue (23): 2827-2834.DOI: 10.6023/A1105046 上一篇    下一篇

研究论文

介孔SBA-15的形貌控制合成及负载染料后其光学性能研究

古丽米娜1,2, 陈悦3, 李晓天*,4, 姚建曦1,2   

  1. (1华北电力大学可再生能源学院 新能源与可再生能源北京市重点实验室 北京 102206)
    (2华北电力大学新能源电力系统国家重点实验室 北京 102206)
    (3中国科学院化学研究所(北京) 北京分子科学国家实验室 北京 100190)
    (4吉林大学汽车材料教育部重点实验室 长春 130012)
  • 投稿日期:2011-05-04 修回日期:2011-07-29 发布日期:2011-09-14
  • 通讯作者: 李晓天 E-mail:xiaotianli@jlu.edu.cn
  • 基金资助:

    带有纳米Fe3O4芯核的介孔TiO2包覆型光催化材料的制备与性能研究

Synthesis and Optical Performances of Different Mesoporous SBA-15 Materials Doped with Dyes

Guli Mina1,2; Chen Yue3; Li Xiaotian*,4Yao Jianxi1,2   

  1. (1 Beijing Key Laboratory of New Energy and Renewable Energy, Renewable Energy School, North China Electric Power University, Beijing 102206)
    (2 State Key Laboratory for Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206)
    (3 Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry (Beijing), Chinese Academy of Sciences, Beijing 100190)
    (4 Key Laboratory of Automobile Materials of Ministry of Education, Jilin University, Changchun 130012)
  • Received:2011-05-04 Revised:2011-07-29 Published:2011-09-14
  • Contact: Xiao-Tian LI E-mail:xiaotianli@jlu.edu.cn

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1275

被引次数

16

采用水热-组装法、溶剂挥发法等材料合成方法制备了不同形貌(粉末棒状、单块、薄膜)负载染料的介孔SBA-15复合材料, 并开展光学性质研究. 通过TEM, XRD, N2吸附-脱附表征证明所合成的各种形貌SBA-15材料均具有规则有序介孔结构, 组装染料后复合材料的形貌及结构保持完整|Uv-vis, PL表征表明染料在SBA-15孔道中呈单分散状态, 负载染料后的复合材料具有发光特性.

关键词: 介孔SBA-15, 染料, 棒状, 单块, 薄膜

Dyes have been grafted into the channels of mesoporous SBA-15 materials with different morphologies (rod-like powders, monolith and film), which were synthesized by hydrothermal and evaporate-solvent methods, respectively. The investigations of TEM (transmission electron microscopy), XRD and N2 adsorption-desorption confirmed that the different composite materials all remaining their ordered meso-structures after dye loading. Uv-vis and PL investigations show that the dye molecules are mono-dispersing in the channels of different dye containing composite materials. All the characterizations indicate that the composite materials have the potential to be used in optical sensors or solid-state dye laser.

Key words: mesoporous SBA-15, dye, rod-like, monolith, film