La 掺杂Bi2O3的制备、表征与可见光催化活性

doi:10.6023/A1112191

化学学报 ›› 2012, Vol. 70 ›› Issue (11): 1250-1256.DOI: 10.6023/A1112191 上一篇下一篇

研究论文

La 掺杂Bi₂O₃的制备、表征与可见光催化活性

杨迎春, 卢远刚, 叶芝祥, 刘盛余, 余静, 胡蕾

成都信息工程学院资源环境学院大气环境模拟与污染控制四川省高校重点实验室成都 610225

投稿日期:2011-12-21 修回日期:2012-03-01 发布日期:2012-03-20
通讯作者: 杨迎春
基金资助:
四川省教育厅重点基金(No. 07ZA012)、成都信息工程学院引进人才科研启动项目基金(No. KYTZ200920)资助项目.

Preparation, Structural Characterization and Visible-Light-Responsive Photocatalytic Performance of Lanthanum-doped Bismuth Oxide

Yang Yingchun, Lu Yuangang, Ye Zhixiang, Liu Shengyu, Yu Jing, Hu Lei

Department of Resources and Environment, Air Environmental Modeling and Pollution Controlling Key Laboratory of Sichuan Higher Education Institutes, Chengdu University of Information Technology, Chengdu 610225

Received:2011-12-21 Revised:2012-03-01 Published:2012-03-20
Supported by:
Project supported by the Scientific Research Fund of Sichuan Provincial Education Department (No. 07ZA012) and Chengdu University of Information Technology for introduced talents (No. KYTZ200920).

文章分享

摘要/Abstract

采用浸渍法制备了La 掺杂Bi₂O₃ (La-Bi₂O₃)光催化剂, 利用X 射线荧光光谱(XRF)、X 射线衍射(XRD)、扫描电子显微镜(SEM)、傅立叶变换红外光谱(FT-IR)、X 射线光电子能谱(XPS)、紫外-可见吸收光谱(UV-Vis)和光致发光谱(PL)等分析测试手段对样品的La 掺杂量、晶体结构和光谱特征等进行了表征, 并以2,4-二氯苯酚(2,4-DCP)水溶液的降解作为探针反应, 考察了样品的可见光催化性能. 结果表明, 适量的La 掺杂能有效抑制Bi₂O₃由四方相向单斜相转变, 并将光吸收范围拓展到550 nm 以上. 掺杂的La 可取代Bi₂O₃ 晶格中部分Bi, 形成Bi—O—La 键, 并生成了少量镧铋复合氧化物(La_0.176Bi_0.824O_1.5), 它们的存在能有效抑制光生电子-空穴对的复合, 从而提高光催化量子产率. 可见光照射下2,4-DCP 的光催化降解实验表明, La-Bi₂O₃具有良好的可见光催化性能, 并且当La 的掺杂量为3%(摩尔分数)时, 催化剂的可见光催化效率最高.

关键词: 氧化铋, 镧掺杂, 可见光, 光催化氧化, 2,4-二氯苯酚(2,4-DCP)

Lanthanum doped Bi₂O₃ (La-Bi₂O₃) photocatalysts were prepared by impregnation method. The doping quantity of lanthanum, crystalline phase structures and spectral properties of as-prepared photocatalysts were characterized by X-ray fluorescence (XRF), X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), ultraviolet-visible spectrophotometry (UV-Vis) and photoluminescence spectroscopy (PL). The enhanced visible-light activity was tested by the photocatalytic degradation of 2,4-dichlorophenol (2,4-DCP). Results of XRD show that appropriate amounts of lanthanum adulteration can effectively prevent the phase transformation of Bi₂O₃ from tetragonal to monoclinic. UV-Vis DRS results indicate an extension of light absorption into the visible region (higher than 550 nm). The doped lanthanum partially substitutes bismuth in the lattice of Bi₂O₃, which exists in the form of Bi—O—La chemical bond. And a new complex metal oxide compound (La_0.176Bi_0.824O_1.5) appears in the catalysts, which could inhibit the recombination between photoelectrons and holes, leading to enhanced photocatalytic quantum efficiency. Furthermore, it is found that Bi₂O₃ doped with lanthanum of 3% (in mole ratio) has the superior photocatalytic performance for 2,4-DCP.

Key words: bismuth oxide, lanthanum-doped, visible-light, photocatalytic oxidation, 2,4-dichlorophenol (2,4-DCP)

引用此文

杨迎春, 卢远刚, 叶芝祥, 刘盛余, 余静, 胡蕾. La 掺杂Bi₂O₃的制备、表征与可见光催化活性[J]. 化学学报, 2012, 70(11): 1250-1256.

Yang Yingchun, Lu Yuangang, Ye Zhixiang, Liu Shengyu, Yu Jing, Hu Lei. Preparation, Structural Characterization and Visible-Light-Responsive Photocatalytic Performance of Lanthanum-doped Bismuth Oxide[J]. Acta Chimica Sinica, 2012, 70(11): 1250-1256.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

参考文献

1 Han, S.-T.; Xi, H.-L.; Shi, R.-X.; Fu, X.-Z.; Wang, X.-X. Chin. J. Chem. Phys. 2003, 16, 339 (in Chinese). (韩世同, 习海玲, 史瑞雪, 付贤智, 王绪绪, 化学物理学报, 2003, 16, 339.)

2 Zhang, Y.-B.; Zhang, W.-Y. Rare Met. Mater. Eng. 2007, 36,

1299 (in Chinese). (张一兵, 张文彦, 稀有金属材料与工程, 2007, 36, 1299.)

3 Sheng, G.-D.; Li, J.-X.; Wang, S.-W.; Wang, X.-K. Prog. Chem. 2009, 21, 2492 (in Chinese). (盛国栋, 李家星, 王所伟, 王祥科, 化学进展, 2009, 21,2492.)

4 Li, W.; Zhou, K.-C.; Yang, H. J. Mater. Sci. Eng. 2004, 22, 154 (in Chinese). (李卫, 周科朝, 杨华, 材料科学与工程学报, 2004, 22,154.)

5 Wang, J.-Z.; Fu, X.-X.; Yang, Q.-H.; Bai, S.-L.; Sun, Y.-H. Chinese J. Appl. Chem. 2002, 19, 483 (in Chinese). (王俊珍, 付希贤, 杨秋华, 白树林, 孙艺环, 应用化学,2002, 19, 483.)

6 Zhang, L.-S.; Wang, W.-Z.; Yang J.; Chen, Z.-G.; Zhang, W.-Q.; Zhou, L.; Liu, S.-W. Appl. Catal. A: Gen. 2006, 308, 105.

7 Wu, X.-H.; Qin, W.; He, W.-D. J. Mol. Catal. A: Chem.2007, 261, 167.

8 Wu, X.-H.; Qin, W.; Li, L.; Guo, Y.; Xie, Z.-Y. Catal. Commun.2009, 10, 600.

9 Xie, J.-M.; Lü, X.-M.; Chen, M.; Zhao, G.-Q.; Song, Y.-Z.; Lu, S.-S. Dyes Pigm. 2008, 77, 43.

10 Pugazhenthiran, N.; Sathishkumar, P.; Murugesan, S.; Anandan, S. Chem. Eng. J. 2011, 168, 1227.

11 Li, L.-Z.; Yan, B. J. Alloys Compd. 2009, 476, 624.

12 Li, Y.-Y.; Wang, J.-S.; Yao, H.-C.; Dang, L.-Y.; Li, Z.-G. Catal. Commun. 2011, 12, 660.

13 Sun, J.; Liu, S.-X. J. Inorg. Mater. 2010, 25, 928 (in Chinese). (孙剑, 刘守新, 无机材料学报, 2010, 25, 928.)

14 Liu, G.-C.; Li, H.-B.; Dong, H. J. Inorg. Mater. 2011, 26, 739 (in Chinese). (刘国聪, 李海斌, 董辉, 无机材料学报, 2011, 26, 739.)

15 Li, Q.-L.; Zhao, J.-X.; Li, B.-D.; Zhang, C.-R. Acta Chim. Sinica 2010, 68, 425 (in Chinese). (李巧玲, 赵静贤, 李保东, 张存瑞, 化学学报, 2010, 68,425.)

16 Ding, S.-W.; Gao, J.; Ding, Y. Acta Chim. Sinica 2011, 69, 2959 (in Chinese). (丁士文, 高甲, 丁宇, 化学学报, 2011, 69, 2959.)

17 Zhang, X.-Q.; Xin, X.; Liu, J.-Y.; Liu, S.-Y.; Zhao, M.; Chen, Y.-Q. Chem. J. Chin. Univ. 2011, 32, 2360 (in Chinese). (张雪乔, 信欣, 刘建英, 刘盛余, 赵明, 陈耀强, 高等学校化学学报, 2011, 32, 2360.)

18 Zeng, Y.-F.; Qin, Y.-Z.; Zhou, Z. Chem. World 2011, 52, 257 (in Chinese). (曾玉凤, 覃荫造, 周振, 化学世界, 2011, 52, 257.)

19 Huang, L.; Li, L.-P.; Yan, T.-J.; Li, G.-S. Chin. J. Struct. Chem. 2009, 28, 1458.

20 Li, W. Mater. Chem. Phys. 2006, 99, 174.

21 Wang, C.-H.; Shao, C.-L.; Wang, L.-J.; Zhang, L.-N.; Li, X.-H.; Liu, Y.-C. J. Colloid Interface Sci. 2009, 333, 242.

22 Naik, B.; Martha, S.; Parida, K. M. Int. J. Hydrogen Energy2011, 36, 2794.

23 Iwamoto, S.; Iwamoto, S.; Inoue, M.; Yoshida, H.; Tanaka, T.; Kagawa, K. Chem. Mater. 2005, 17, 650.

24 Wang, E.-J.; Yang, H.-Y.; Cao, Y.-A. Acta Chim. Sinica2009, 67, 2759 (in Chinese). (王恩君, 杨辉云, 曹亚安, 化学学报, 2009, 67, 2759.)

25 Gujar, T. P.; Shinde, V. R.; Lokhande, C. D.; Mane, R. S.; Han, Sung-Hwan. Appl. Surf. Sci. 2005, 250, 161.

26 Zheng, H.-R.; Cui, Y.-J.; Zhang, J.-S.; Ding, Z.-X.; Wang, X.-C. Chin. J. Catal. 2011, 32, 100 (in Chinese). (郑华荣, 崔言娟, 张金水, 丁正新, 王心晨, 催化学报,2011, 32, 100.)

27 Long, H.-J.; Wang, E.-J.; Dong, J.-Z.; Wang, L.-L.; Cao, Y.-Q.; Yang, W.-S.; Cao, Y.-A. Acta Chim. Sinica 2009, 67, 1533 (in Chinese). (龙绘锦, 王恩君, 董江舟, 王玲玲, 曹永强, 杨文胜, 曹亚安, 化学学报, 2009, 67, 1533.)

28 Jiao, B.-Q.; Xu, Z.-P.; Sun, X.-J.; Cai, W.-M.; Wang, E.-F.; Ji, H.-Y. J. Chin. Ceram. Soc. 2011, 39, 743 (in Chinese). (焦斌权, 徐朝鹏, 孙晓君, 蔡伟民, 王恩福, 纪红月, 硅酸盐学报, 2011, 39, 743.)

29 Chen, X.-Y.; Liu, S.-X. Acta Phys.-Chim. Sin. 2007, 23, 701 (in Chinese). (陈孝云, 刘守新, 物理化学学报, 2007, 23, 701.)

30 He, W.-D.; Qin, W.; Wu, X.-H.; Din, X.-B.; Chen, L.; Jiang, Z.-H. Thin Solid Films 2007, 515, 5362.

31 Zou, W.; Hao, W.-C.; Xin, X.; Wang, T.-M. Chin. J. Inorg. Chem. 2009, 25, 1971 (in Chinese). (邹文, 郝维昌, 信心, 王天民, 无机化学学报, 2009, 25,1971.)

32 Huang, Q.-Q.; Zhang, S.-N.; Cai, C.-X.; Zhou, B. Mater. Lett. 2011, 65, 988.

33 Chen, Q.-F.; Shi, W.-M.; Jiang, D.; Xu, Y.; Wu, D.; Sun, Y.-H. Acta Chim. Sinica 2010, 68, 301 (in Chinese). (陈其凤, 史卫梅, 姜东, 徐耀, 吴东, 孙予罕, 化学学报,2010, 68, 301.)

[1]	杜思南, 赵丽曼, 张泽新, 陈国颂. 甘露糖修饰的微马达的制备及其免疫功能初探^★[J]. 化学学报, 2023, 81(7): 741-748.
[2]	李飞, 丁汇丽, 李超忠. 基于氟仿衍生的三氟甲基硼络合物参与的烯烃氢三氟甲基化反应[J]. 化学学报, 2023, 81(6): 577-581.
[3]	徐袁利, 潘辉, 杨义, 左智伟. 连续流条件下蒽-铈协同催化的苄位碳氢键选择性氧化反应^★[J]. 化学学报, 2023, 81(5): 435-440.
[4]	赵亚婷, 刘帆, 汪秋安, 夏吾炯. 可见光促进(氮杂)芳香胺与重氮乙酸乙酯的N-烷基化反应[J]. 化学学报, 2023, 81(2): 111-115.
[5]	解众舒, 薛中鑫, 许子文, 李倩, 王洪宇, 李维实. 石墨相氮化碳的共轭交联修饰及其对可见光催化产氢性能的影响[J]. 化学学报, 2022, 80(9): 1231-1237.
[6]	赵杰, 王治文, 李华清, 艾琦, 蔡培庆, 司俊杰, 姚鑫, 胡晓光, 刘祖刚. 基于苯并[b]萘并[1,2-d]噻吩的可见光驱动光环化荧光turn-on型二芳基乙烯的合成与性能研究[J]. 化学学报, 2022, 80(9): 1223-1230.
[7]	朱鹏飞, 娄晨思, 史雨翰, 王传义. Ag/AgCl/ZIF-8复合材料的制备及其对NO光催化氧化性能的研究[J]. 化学学报, 2022, 80(10): 1385-1393.
[8]	杨民, 叶柏柏, 陈健强, 吴劼. 可见光催化烷基磺酰自由基启动芳酰肼的烷基磺酰化反应[J]. 化学学报, 2022, 80(1): 11-15.
[9]	马智烨, 叶丽, 吴雨桓, 赵彤. B,N-SnO₂/TiO₂光催化剂的制备及其光催化性能研究[J]. 化学学报, 2021, 79(9): 1173-1179.
[10]	刘江, 徐敬成, Romana Pajkert, 梅海波, Gerd-Volker Röschenthaler, 韩建林. 光化学条件下(β-重氮-α,α-二氟乙基)膦酸酯与羧酸的酯化反应[J]. 化学学报, 2021, 79(6): 747-750.
[11]	刘欢, 李京哲, 李平, 张广智, 张广智, 张豪, 邱灵芳, 齐晖, 多树旺. 2D/3D ZnIn₂S₄/TiO₂复合物的原位构筑及其提高的光催化性能[J]. 化学学报, 2021, 79(10): 1293-1301.
[12]	董奎, 刘强, 吴骊珠. 放氢交叉偶联反应[J]. 化学学报, 2020, 78(4): 299-310.
[13]	李宸, 陈凤华, 叶丽, 李伟, 于晗, 赵彤. B,N共掺杂的In₂O₃/TiO₂制备与光催化产氢性能研究[J]. 化学学报, 2020, 78(12): 1448-1454.
[14]	杨俊航, 傅晓波, 卢增辉, 朱钢国. 可见光催化烯烃砜基化启动的远程醛基碳-氢键直接硫化反应[J]. 化学学报, 2019, 77(9): 901-905.
[15]	陈奕霖, 常亮, 左智伟. 可见光催化诱导的Smiles重排研究进展[J]. 化学学报, 2019, 77(9): 794-802.

La 掺杂Bi₂O₃的制备、表征与可见光催化活性

Preparation, Structural Characterization and Visible-Light-Responsive Photocatalytic Performance of Lanthanum-doped Bismuth Oxide

PDF

可视化

摘要/Abstract

引用此文

分享此文

参考文献

相关文章 15

编辑推荐

相关统计

本文评价