Study on thermodynamic properties of mixed electrolytes in mixed solvents III: System of HCl-NaCl-i-PrOH-H2O at 5 to 45℃

Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (1): 6-13. Previous Articles Next Articles

Original Articles

混合溶剂中多组分电解质溶液热力学性质的研究III: HCl-NaCl-i-PrOH-H2O体系(5-45℃)

吕殿祯;门殿元;杨家振;梁春余;王宇;范垂斌

辽宁大学化学系

发布日期:1989-01-15

Study on thermodynamic properties of mixed electrolytes in mixed solvents III: System of HCl-NaCl-i-PrOH-H2O at 5 to 45℃

LU DIANZHEN;MEN DIANYUAN;YANG JIAZHEN;LIANG CHUNYU;WANG YU;FAN CHUIBIN

Published:1989-01-15

Abstract

Emf. measurements were used to determine the properties of the HCl-NaCl-i-PrOH-H2O system containing 0.025-0.1 mol. fraction of i-PrOH, at 5-45? The activity coefficients of HCl were determine as well as relative molar enthalpies, which are linear function of the ionic strength of the solns.

Key words: MULTICOMPONENT SYSTEM, THERMODYNAMIC PROPERTIES, HYDROCHLORIC ACID, ELECTROMOTIVE FORCES, ELECTROLYTE, SODIUM CHLORIDE, SOLVENT EFFECT, ENTROPY, ENTHALPY, HYDROXIDE

CLC Number:

O645

Cite this article

LU DIANZHEN;MEN DIANYUAN;YANG JIAZHEN;LIANG CHUNYU;WANG YU;FAN CHUIBIN. Study on thermodynamic properties of mixed electrolytes in mixed solvents III: System of HCl-NaCl-i-PrOH-H2O at 5 to 45℃[J]. Acta Chimica Sinica, 1989, 47(1): 6-13.

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混合溶剂中多组分电解质溶液热力学性质的研究III: HCl-NaCl-i-PrOH-H2O体系(5-45℃)

Study on thermodynamic properties of mixed electrolytes in mixed solvents III: System of HCl-NaCl-i-PrOH-H2O at 5 to 45℃

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