Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (10): 966-972. Previous Articles     Next Articles

Original Articles

MeOH-H~2O-NaOAc体系(278.2~318.2K)的电导研究

王风云;张惟权;丁海青;邹玉芬   

  1. 南京理工大学化学系
  • 发布日期:1993-10-15

Conductance study on MeOH-H~2O-NaOAc systems in 278.2~318.2K.

WANG FENGYUN;ZHANG WEIQUAN;DING HAIQING;ZOU YUFEN   

  • Published:1993-10-15

The molar conductances of NaOAc in 10-100 wt.% aqueous MeOH at 278.2, 288.2, 298.2, 308.2 and 318.2K were determine The four groups of best fitting parameters, such as the limiting molar conductance, L0, the ions association constant, KA, and the distance parameter, R (or a), were evaluated from Fuoss-Onsager-Skinner, Pitts, Lee-Wheaton and Fuoss-1978 conductance equations, resp. A discussion about the applicability of the four conductance equations, the dependence of L0, KA, the Walden product, L0h, and the ion-solvent interactions on temperature and the wt.% of MeOH in the systems are given.

Key words: WATER, METHANOL, ELECTRIC CONDUCTANCE, MIX SOLVENT, ASSOCIATION CONSTANT

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